Production of chlorofluorocarbon-free, urethane-containing moldings having a cellular core and a compacted peripheral zone

• US 5,254,597 A
• Filed: 11/24/1992
• Issued: 10/19/1993
• Est. Priority Date: 11/30/1991
• Status: Expired due to Fees

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Mueller, Ulrich, Horn, Peter, Hoelderich, Wolfgang, Tintelnot, Dieter, Schuster, Ludwig, Taddey, Rudolf
• Primary Examiner(s): Foelak, Morton
• Application Number:
  US07/981,025
• Time in Patent Office: 329 Days
• Field of Search: 521/51, 521/99, 521/901, 521/174, 521/172, 521/176, 521/173, 264/45.4, 264/DIG. 15
• US Class Current: 521/51
• CPC Class Codes: C08G 18/12 using two or more compounds having active hydrogen in the first polymerisation step
• CPC Class Codes: C08G 18/302 Water
• CPC Class Codes: C08G 18/4072 Mixtures of compounds of group C08G18/63 with other macromolecular compounds
• CPC Class Codes: C08G 18/4812 Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
• CPC Class Codes: C08G 18/4841 containing oxyethylene end groups
• CPC Class Codes: C08G 18/632 onto polyethers
• CPC Class Codes: C08G 18/6674 with compounds of group C08G18/3203
• CPC Class Codes: C08G 2110/0008 flexible
• CPC Class Codes: C08G 2110/0016 semi-rigid
• CPC Class Codes: C08G 2110/0025 rigid
• CPC Class Codes: C08G 2110/0033 having integral skins
• CPC Class Codes: C08G 2110/0066 ≥ 150kg/m3
• CPC Class Codes: C08G 2110/0083 prepared using water as the sole blowing agent
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 9/34 Chemical features in the manufacture of articles consisting of a foamed macromolecular core and a macromolecular surface layer having a higher density than the core
• CPC Class Codes: C08K 3/04 Carbon
• CPC Class Codes: C08L 75/04 Polyurethanes
• CPC Class Codes: Y10S 264/15 Aging of foamed resin products
• CPC Class Codes: Y10S 521/901 Cellular polymer containing a carbodiimide structure

Abstract

A process for the production of chlorofluorocarbon-free, urethane- or urethane- and urea-containing, soft-elastic, semirigid or rigid moldings having a cellular core and a compacted peripheral zone and an essentially pore-free, smooth surface involves reacting

a) an organic and/or modified organic polyisocyanate with

b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and, if desired,

c) a low-molecular-weight chain extender and/or cross-linking agent,

in the presence of

d) a blowing agent,

e) a catalyst,

f) at least one microporous activated charcoal and/or microporous carbon molecular sieve which preferably has a mean pore diameter with a frequency of occurrence of more than 40% in the range from 0.3 to 3 nm, a pore volume of from 0.20 to 1.4 ml/g and a BET surface area of from 500 to 2500 m² /g, and, if desired, further additives and

g) assistants,

in a closed mold with compaction.

Claims

1. A process for the production of chlorofluoro-carbon-free, urethane- or urethane- and urea-containing moldings having a cellular core and a compacted peripheral zone, by reacting

a) an organic and/or modified organic polyisocyanate with

b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and, if optionally,

c) a low-molecular-weight chain extender and/or crosslinking agent, in the presence of

d) a blowing agent,

e) a catalyst,

f) additives and, if optionally,

g) assistants,

in a closed mold with compaction, wherein one of the additives (f) is microporous activated charcoal, microporous carbon molecular sieve or a mixture thereof.

2. A process as claimed in claim 1, wherein the microporous activated charcoal or microporous carbon molecular sieve has a mean pore diameter with a frequency of occurrence of more than 40% in the range from 0.3 to 3 nm.

3. A process as claimed in claim 1, wherein the microporous activated charcoal or microporous carbon molecular sieve has a pore volume in the range from 0.20 to 1.4 ml/g.

4. A process as claimed in claim 1, wherein the microporous activated charcoal or microporous carbon molecular sieve has a BET surface area in the range from 500 to 2500 m² /g.

5. A process as claimed in claim 1, wherein the microporous activated charcoal or microporous carbon molecular sieve or the mixture of activated charcoal and carbon molecular sieve is used in an amount of from 0.5 to 50% by weight, based on the weight of starting components (b) or (b) and (c).

6. A process as claimed in claim 1, wherein the additive (f) is used in the form of a concentrate comprising at least one microporous activated charcoal or at least one microporous carbon molecular sieve or a mixture thereof, and at least one relatively high-molecular-weight compound containing two reactive hydrogen atoms.

7. A process as claimed in claim 1, wherein the additive (f) is used in the form of a concentrate comprising at least one microporous activated charcoal or at least one microporous carbon molecular sieve or a mixture thereof, and at least one ethylenediamine-initiated polyoxypropylene-polyol having a hydroxyl number of from 35 to 100.

8. A process as claimed in claim 1, wherein the microporous activated charcoal or microporous carbon molecular sieve has a water content of from 3 to 20% by weight, based on the total weight.

9. A process as claimed in claim 1, wherein the additive (f) used is microporous activated charcoal, microporous carbon molecular sieve or a mixture thereof in combination with microporous, crystalline molecular sieve or amorphous, microporous silica gel, or a mixture thereof.

10. A process as claimed in claim 1, wherein the additive (f) used is a mixture of microporous activated charcoal or microporous carbon molecular sieve, amorphous, microporous silica gel and zeolite.

11. A process as claimed in claim 1, wherein the microporous activated charcoal or microporous carbon molecular sieve has type I isothermicity.

12. A process as claimed in claim 1, wherein the blowing agent (d) used is water or a physical blowing agent, with the exception of chlorofluorocarbons, or a mixture of water and a physical blowing agent.

13. A process as claimed in claim 1, wherein the chlorofluorocarbon-free, urethane-containing moldings are soft-elastic, semirigid or rigid.

14. A process as claimed in claim 1, wherein the chlorofluorocarbon-free, urethane-containing moldings are produced by RIM or the low-pressure process.

15. A process as claimed in claim 1 for coating metal containers, preferably metal barrels for beverages.

16. A process for the production of moldings for the inside or outside of vehicles.