Infrared absorbing film improved in transparency

• US 5,256,473 A
• Filed: 09/23/1991
• Issued: 10/26/1993
• Est. Priority Date: 10/03/1990
• Status: Expired due to Fees

• Current Assignee: Sumitomo Chemical Company Limited
• Original Assignee: Sumitomo Chemical Company Limited
• Inventors: Kotani, Kozo, Negawa, Hideo
• Primary Examiner(s): Thibodeau, Paul J.
• Assistant Examiner(s): NAKARANI, DHIRAJLAL S
• Application Number:
  US07/764,195
• Time in Patent Office: 764 Days
• Field of Search: 428/331, 428/218, 428/220, 428/334, 428/516, 428/518, 428/520, 428/522, 428/523, 241/21
• US Class Current: 428/218
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: C08K 3/36 Silica
• CPC Class Codes: Y10T 428/24992 Density or compression of components
• CPC Class Codes: Y10T 428/259 Silicic material
• CPC Class Codes: Y10T 428/263 Coating layer not in excess of 5 mils thick or equivalent
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer
• CPC Class Codes: Y10T 428/3192 Next to vinyl or vinylidene chloride polymer
• CPC Class Codes: Y10T 428/31928 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31938 Polymer of monoethylenically unsaturated hydrocarbon

Abstract

Disclosed is an infrared absorbing film comprising a synthetic resin and silicon oxide, wherein the silicon oxide is used in an amount of about 2 to about 25% by weight based on the synthetic resin, and wherein the silicon oxide is produced by underwater grinding, has an average particle size of not more than 4 μm, is substantially free of particles exceeding 20 μm in average particle size, and has a specific surface area of not more than 20 m² /g.

The film may further comprise a transparent resin layer formed over at least one surface thereof.

Claims

1. An infrared absorbing transparent film comprising a synthetic resin containing silicon oxide particles in an amount of about 2 to 25% by weight based on the synthetic resin, and wherein the silicon oxide particles are produced by underwater grinding, and have an average particle size of not more than 4 μ

m and a specific surface area of not more than 20 m² /g, said film being substantially free of silicon oxide particles exceeding 20 μ

m.

2. An infrared absorbing film as claimed in claim 1 wherein the silicon oxide particles are produced by underwater grinding, and have an average particle size of not more than 3 μ

m and a specific surface area of not more than 15 m² /g, said film being substantially free of silicon oxide particles exceeding 10 μ

m.

3. An infrared absorbing film as claimed in claim 1 which has a thickness of about 20 to about 300 μ

m.

4. An infrared absorbing film as claimed in claim 1 wherein the synthetic resin is an olefin resin.

5. An infrared absorbing film as claimed in claim 1 wherein the synthetic resin is an olefin resin having a melt flow rate of about 0.1 to about 4 g/10 min.

6. An infrared absorbing film as claimed in claim 1 wherein the synthetic resin is low density polyethylene or an ethylene-α

-olefin copolymer each having a density of 0.935 g/cm³ or less.

7. An infrared absorbing film as claimed in claim 1 wherein the synthetic resin is an ethylene-vinyl acetate copolymer.

8. An infrared absorbing film as claimed in claim 1 wherein the synthetic resin is a polyvinyl chloride resin.

9. An infrared absorbing film as claimed in claim 1 which further comprises a transparent synthetic resin layer formed over at least one surface of the infrared absorbing transparent film comprising the synthetic resin and silicon oxide particles.

10. An infrared absorbing film as claimed in claim 9 wherein the transparent synthetic resin layer is composed of a synthetic resin which is the same as the synthetic resin constituting the film containing silicon oxide particles.

11. An infrared absorbing film as claimed in claim 9 wherein the synthetic resin is an olefin resin.

12. An infrared absorbing film as claimed in claim 9 wherein the synthetic resin is an olefin resin having a melt flow rate of about 0.1 to about 4 g/10 min.

13. An infrared absorbing film as claimed in claim 9 wherein the synthetic resin is low density polyethylene or an ethylene-α

-olefin copolymer each having a density of 0.935 g/cm³ or less.

14. An infrared absorbing film as claimed in claim 9 wherein the synthetic resin is an ethylene-vinyl acetate copolymer.

15. An infrared absorbing film as claimed in claim 9 wherein the synthetic resin is a polyvinyl chloride resin.

16. An infrared absorbing film as claimed in claim 9 wherein the transparent synthetic resin layer is over both surfaces of the film comprising the synthetic resin and silicon oxide particles.

17. An infrared absorbing film as claimed in claim 9 wherein the transparent resin layer has a thickness of about 5 to about 100 μ

m.

18. An infrared absorbing film as claimed in claim 1 wherein the synthetic resin is a low-density polyethylene, a medium-density polyethylene or a high density polyethylene.

19. An infrared absorbing film as claimed in claim 1 wherein the synthetic resin is a copolymer of ethylene and butene-1, 4-methylpentene, hexene-1, octene-1, acrylic acid, alkyl (meth)acrylate or propylene.

20. An infrared absorbing film as claimed in claim 1 wherein the synthetic resin is an ionomer resin or a propylenebutene-1 copolymer.

21. An infrared absorbing film as claimed in claim 1 wherein the synthetic resin is a plasticized polyvinyl chloride resin.

22. An infrared absorbing film as claimed in claim 1 wherein the synthetic further comprises a dispersing agent, a stabilizer, an ultraviolet absorber, an antistatic agent, a waterdrop formation inhibitor or a mixture thereof.