Process for reforming at low severities with high-activity, high-yield, tin modified platinum-iridium catalysts

• US 5,269,907 A
• Filed: 03/06/1992
• Issued: 12/14/1993
• Est. Priority Date: 12/14/1990
• Status: Expired due to Fees

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Swan, George A. III, Boyle, Joseph P., Baird, William C.
• Primary Examiner(s): Myers, Helane
• Application Number:
  US07/847,541
• Time in Patent Office: 648 Days
• Field of Search: 208/65, 208/138, 208/139, 208/63
• US Class Current: 208/65
• CPC Class Codes: B01J 23/626 with tin
• CPC Class Codes: C10G 35/09 Bimetallic catalysts in which at least one of the metals is a platinum group metal
• CPC Class Codes: C10G 59/02 plural serial stages only

Abstract

A process for reforming a naphtha feed at low severities with tin modified platinum-iridium catalysts. In particular, both high selectivity, and high activity are manifested by such catalysts in reforming a naphtha feed at low severities in the lead reactor, or reactors, of a series of reactors; i.e., within the dehydrogenation and ring isomerization zone, or zones, of a reforming unit. The lead reactors of the series are charged with a tin-containing platinum-iridium catalyst, and the naphtha feed reformed to produce a low RON clear C₅ + liquid reformate. The low octane product of the lead reactors may be transferred to a mogas pool, into blending components, or all or some part of the product further reformed. Preferably, the product is further reformed in a tail reactor, and preferably the tail reactor is charged with a non-tin containing platinum, or platinum-iridium catalyst.

Claims

1. A process for improving the octane quality of a naphtha comprising a mixture of paraffins, aromatics and naphthenes, which comprises reforming said naphtha feed over a tin modified platinum-iridium catalyst at reforming conditions sufficient to produce predominantly dehydrogenation and ring isomerization reactions, with minimum paraffin dehydrocyclization, and produce a reformate of RON clear octane ranging from about 80 to about 95, said catalyst comprising from about 0.1 percent to about 0.7 percent platinum, from about 0.1 percent to about 0.7 percent iridium, and from about 0.02 percent to about 0.4 percent tin, wherein each of said metals is composited with and uniformly dispersed throughout an inorganic oxide support.

2. The process of claim 1 wherein the catalyst composite contains from about 0.1 percent to about 0.5 percent platinum, from about 0.1 percent to about 0.5 percent iridium, and from about 0.05 to about 0.3 percent tin.

3. The process of claim 1 wherein the catalyst composite contains from about 0.1 percent to about 3 percent halogen, and containing up to about 0.05-0.15 percent sulfur.

4. The process of claim 1 wherein the inorganic oxide support component of the catalyst is alumina.

5. In a process of improving the octane quality of a naphtha comprised of a mixture of paraffins, aromatics and naphthenes in a reforming unit comprised of a plurality of serially connected reactors inclusive of one or more lead reactors and a tail reactor, each of which contains a platinum catalyst, the naphtha flowing in sequence from one reactor of the series to another and contacting the catalyst in the presence of hydrogen, the improvement comprising, providing the lead reactor, or reactors, of the series with a catalyst comprised of from about 0.1 percent to about 0.7 percent platinum, from about 0.1 percent to about 0.7 percent iridium, and from about 0.02 percent to about 0.4 percent tin, based on the total weight of the catalyst, wherein each of said metals is composited with and uniformly dispersed throughout an inorganic oxide support and reforming said naphtha feed over said catalyst at reforming conditions in said one or more lead reactors sufficient to produce predominantly dehydrogenation and ring isomerization reactions, with minimum paraffin dehydrocyclization, and produce a reformate of RON clear ranging from about 80 to about 95.

6. The process of claim 6 wherein the catalyst in the lead reactor, or reactors, contains from about 0.1 percent to about 0.5 percent platinum, from about 0.1 percent to about 0.5 percent iridium, and from about 0.05 to about 0.3 percent tin.

7. The process of claim 6 wherein the catalyst in the tail reactor contains from about 0.1 to about 0.7 percent platinum, and from about 0.1 percent to about 0.7 percent iridium.

9. The process of claim 6 wherein the catalyst contains from about 0.1 percent to about 3 percent halogen, and containing up to about 0.05-0.15 percent.

10. The process of claim 6 wherein the reforming conditions employed in the lead reactor, or reactors, of the series are defined as follows:

space="preserve" listing-type="tabular">______________________________________ Pressure, psig about 150 to 500 Reactor Temperature, °

F. about 800 to 950 Gas Rate, SCF/B about 2,000 to 6,000 Feed Rate, W/Hr/W about 5 to 15. ______________________________________

11. The process of claim 6 wherein the reforming conditions employed in the tail reactor of the series are defined as follows:

space="preserve" listing-type="tabular">______________________________________ Pressure, psig about 100 to 700 Reactor Temperature, °

F. about 800 to 1000 Gas Rate, SCF/B about 2,000 to 10,000 Feed Rate, W/Hr/W about 1 to 10. ______________________________________

12. The process of claim 6 wherein the reforming conditions employed in the tail reactor of the series are defined as follows:

space="preserve" listing-type="tabular">______________________________________ Pressure, psig about 150 to 500 Reactor Temperature, °

F. about 850 to 975 Gas Rate, SCF/B about 2,000 to 6,000 Feed Rate, W/Hr/W about 2 to 8. ______________________________________

8. The process of claim 8 wherein the catalyst in the tail reactor contains from about 0.1 percent to about 0.5 percent platinum, and from about 0.1 percent to about 0.5 percent iridium.