Antiperspirant stick containing a macroporous polymer

• US 5,281,413 A
• Filed: 10/05/1990
• Issued: 01/25/1994
• Est. Priority Date: 10/05/1990
• Status: Expired due to Term

• Current Assignee: Amcol Health & Beauty Solutions, Incorporated (Minerals Technologies Incorporated)
• Original Assignee: Dow, Inc.
• Inventors: Abrutyn, Eric S., Gressani, Tina M.
• Primary Examiner(s): Michl, Paul R.
• Assistant Examiner(s): Spear, James M.
• Application Number:
  US07/593,848
• Time in Patent Office: 1,208 Days
• Field of Search: 424/DIG. 5, 424/484, 424/66, 424/68
• US Class Current: 424/68
• CPC Class Codes: A61K 2800/56 Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms
• CPC Class Codes: A61K 8/0229 Sticks
• CPC Class Codes: A61K 8/26 Aluminium; Compounds thereof
• CPC Class Codes: A61K 8/28 Zirconium; Compounds thereof
• CPC Class Codes: A61K 8/585 Organosilicon compounds
• CPC Class Codes: A61K 8/8152 Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
• CPC Class Codes: A61Q 15/00 Anti-perspirants or body deodorants deodorisation of air A61L9/00
• CPC Class Codes: Y10S 424/05 Stick

Abstract

An antiperspirant stick product containing as components at least one material such as astringent antiperspirant compounds, a volatile silicone, a waxy material, emollients, perfumes, coloring agents, and other ingredients normally used in making stick products. The improvement is directed to incorporating into the stick product as one component a macroporous highly crosslinked polymer. The macroporous polymer is free of "in situ" entrapped active ingredients.

Claims

1. In an antiperspirant stick product containing as components thereof at least one material selected from the group consisting of astringent antiperspirant compounds, a volatile silicone, a wax, emollients, perfumes, coloring agents, and antiperspirant solid stick additives normally used in making stick products, the improvement comprising incorporating into the stick product as a component thereof a macroporous crosslinked polymer, the macroporous polymer being free of in situ entrapped active ingredients.

2. The product of claim 1 wherein the polymer is hydrophobic and is formed of at least one polyunsaturated monomer.

3. The product of claim 2 wherein the polyunsaturated monomer is selected from the group consisting of ethylene glycol dimethacrylate and tetraethylene glycol dimethacrylate.

4. The product of claim 1 wherein the polymer is hydrophobic and is formed of at least one monounsaturated monomer and at least one polyunsaturated monomer.

5. The product of claim 4 wherein the monounsaturated monomer is selected from the group consisting of lauryl methacrylate and 2-ethylhexyl methacrylate, and the polyunsaturated monomer is selected from the group consisting of ethylene glycol dimethacrylate and tetraethylene glycol dimethacrylate.

6. The product of claim 1 in which the macroporous polymer is in the form of particles in the shape of a bead.

7. The product of claim 6 in which the particles have an average diameter of about ten microns to about one hundred-fifty microns.

8. The product of claim 1 in which the macroporous polymer is in the form of a powder, the powder being a combined system of polymer particles, the system of powder particles including unit particles of less than about one micron in average diameter, agglomerates of fused unit particles of sizes in the range of about twenty to eighty microns in average diameter, and aggregates of clusters of fused agglomerates of sizes in the range of about two-hundred to about twelve-hundred microns in average diameter.

9. The product of claim 8 in which the polymer is a polymethacrylate.

10. The product of claim 1 in which the stick includes about ten to about fifty weight percent of an astringent antiperspirant compound, about ten to about sixty-five weight percent of a volatile silicone, about twelve to about fifteen weight percent of wax, and about four to about five weight percent of the macroporous polymer.

11. The product of claim 10 in which the stick includes 10-30 weight percent of astringent antiperspirant compound, and fifty to sixty-five weight percent of volatile silicone.

12. The product of claim 1 in which the astringent is aluminum chlorohydrate.

13. The product of claim 1 in which the astringent is aluminum zirconium chlorohydroxyglycine.