Method and system for remediation of groundwater contamination

• US 5,286,141 A
• Filed: 02/12/1993
• Issued: 02/15/1994
• Est. Priority Date: 02/12/1993
• Status: Expired due to Term

• Current Assignee: ManTech Environmental Corp. (Mantech International Corporation)
• Original Assignee: Ronald J. Vigneri
• Inventors: Vigneri, Ronald J.
• Primary Examiner(s): CORBIN, DAVID
• Application Number:
  US08/017,478
• Time in Patent Office: 368 Days
• Field of Search: 405/52, 405/128, 405/129, 405/258, 405/263, 166/268, 166/300, 166/310, 210/747
• US Class Current: 210/747.8
• CPC Class Codes: B01F 2101/305 Treatment of water, waste water or sewage
• CPC Class Codes: B01F 23/451 by injecting one liquid into another
• CPC Class Codes: B01F 35/2132 Concentration, pH, pOH, p(ION) or oxygen-demand B01F35/2133 takes precedence
• CPC Class Codes: B01F 35/82 by adding a material to be mixed to a mixture in response to a detected feature, e.g. density, radioactivity, consumed power or colour
• CPC Class Codes: B09C 1/002 involving in-situ ground water treatment
• CPC Class Codes: B09C 1/08 chemically
• CPC Class Codes: B09C 2101/00 In situ
• CPC Class Codes: C02F 1/722 Oxidation by peroxides
• CPC Class Codes: C02F 2103/06 Contaminated groundwater or leachate
• CPC Class Codes: E02D 31/00 Protective arrangements for foundations or foundation structures protective casings for piles E02D5/60; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution spillage retaining means for tanks B65D90/24
• CPC Class Codes: E21B 43/00 Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells applicable only to water E03B; obtaining oil-bearing deposits or soluble or meltable materials by mining techniques E21C41/00; pumps F04

Abstract

A method for remediating a hydrocarbon-contaminated region of a subterranean body of groundwater to destroy or reduce the initial concentration levels of hydrocarbon contaminants. A plurality of mutually spaced wells are provided intersecting the groundwater region, and the existence of acceptable continuity and well interflow paths for the said region is determined by generating a test flow of a solution of hydrogen peroxide from one of the wells and monitoring pH changes at each other of the wells as a function of time to detect a pH drop of at least 0.2. Subsequent to detecting the pH drop, a treating flow of the hydrogen peroxide solution is provided from one or more of the wells. A system to enable the foregoing is also disclosed.

Claims

1. A method for remediating a hydrocarbon-contaminated region of a subterranean body of groundwater to destroy or reduce the initial concentration levels of hydrocarbon contaminants, comprising the steps of:

(a) providing a plurality of mutually spaced wells intersecting said groundwater region;

(b) determining the existence of acceptable continuity and well interflow paths for the said region by generating a test flow of a solution of hydrogen peroxide from one of said wells and monitoring pH changes at each other of said wells as a function of time to detect a pH drop of at least 0.2; and

(c) subsequent to detecting said pH drop, providing a treating flow of said hydrogen peroxide solution from one or more of said wells.

2. A method in accordance with claim 1, wherein the treating flow is periodically stopped and the hydrocarbon contaminant levels measured at each said well, until the said initial contaminant concentration levels drop below predetermined acceptable values.

3. A method in accordance with claim 2, wherein said treating flow is at the rate of 1 to 6 gallons of hydrogen peroxide per minute per well, expressed on the basis of a 35% by weight solution of hydrogen peroxide.

4. A method is accordance with claim 3, wherein the treating flow is provided under a pressure not more than the hydrostatic head relative to surface at the point of treating flow discharge from said well.

5. A method in accordance with claim 4, wherein the treating flow is provided under a pressure of from 6 to 40 psig.

6. A method in accordance with claim 4, wherein the total said treating flow of hydrogen peroxide solution is 1 to 5% by weight of the effective volume of contaminated water which is treated, expressed on the basis of a 35% solution of hydrogen peroxide.

7. A method in accordance with claim 1, wherein the total volume in the test flow is 0.5 to 1.0% by weight of the effective volume of contaminated water, expressed on the basis of a 35% solution of hydrogen peroxide, and is injected at the rate of 0.3 to 1 gallon/minute and at a pressure which is not more than the hydrostatic head relative to surface at the point of treating flow discharge from said well.

8. A method in accordance with claim 1, including at least 3 said wells, which are spaced about the periphery of said groundwater region.

9. A method in accordance with claim 8, wherein said test flow is injected at one said well and the said pH change monitored at said other wells.

10. A method in accordance with claim 1, further including in step (b), monitoring temperature changes at one or more other of said wells to detect a temperature rise of at least 2°

F. as a confirmatory indicator of said acceptable continuity and well interflow paths.

11. A method for remediating a hydrocarbon-contaminated region of a subterranean body of groundwater to destroy or reduce the initial concentration levels of hydrocarbon contaminants, comprising the steps of:

(a) providing a plurality of mutually spaced wells intersecting said groundwater region;

(b) providing a treating flow of a hydrogen peroxide solution from one or more of said wells; and

(c) periodically stopping the treating flow and determining the hydrocarbon contaminant levels measured at each said well, until the said initial contaminant concentration levels drop below predetermined acceptable values.

12. A method in accordance with claim 11, wherein said treating flow is at the rate of 1 to 6 gallons of hydrogen peroxide per minute per well, expressed on the basis of a 35% by weight solution of hydrogen peroxide.

13. A method in accordance with claim 12, wherein the treating flow is provided under a pressure of from 6 to 40 psig, but not more than the hydrostatic head relative to surface at the point of treating flow discharge from said well.

14. A method in accordance with claim 13, wherein the total said treating flow of hydrogen peroxide solution is 1 to 5% by weight of the effective volume of contaminated water which is treated, expressed on the basis of a 35% solution of hydrogen peroxide.

15. A method in accordance with claim 11, wherein said treating solution includes from about 10 to 35% by weight hydrogen peroxide.

16. A method in accordance with claim 15, wherein prior to step (b) a treating flow is injected from said one or more wells into said region of groundwater, which includes at least one catalytically effective amount of an initiation catalyst for the redox reaction between said hydrogen peroxide and the hydrocarbon contaminant sought to be reacted.

17. A method in accordance with claim 15, wherein said treating solution further includes a reaction surface enhancing reagent.

18. A method for remediating a hydrocarbon-contaminated subterranean static plume of groundwater to destroy or reduce the initial concentration levels of hydrocarbon contaminants, comprising the steps of:

(a) providing a plurality of mutually spaced wells intersecting said static plume groundwater;

(b) measuring the change in water depth at each of said wells following atmospheric precipitation, to determine by common depth changes the likelihood of said plume;

(c) confirming the existence of the static plume by generating a test flow of a solution of hydrogen peroxide from one of said wells and monitoring the absence of pH changes at each other of said wells as a function of time; and

(d) providing a treating flow of said hydrogen peroxide solution from each of said wells at a rate of from 1 to 6 gallons per minute to establish a radial sweep about each said well, the total volume of treating solution being from 1 to 5% by weight of the effective volume of contaminated water, expressed on the basis of a 35% solution of hydrogen peroxide.

19. A method in accordance with claim 18, wherein the treating flow is periodically stopped and the hydrocarbon contaminant levels measured at each said well, until the said initial contaminant concentration levels drop below predetermined acceptable values.

20. A method in accordance with claim 18, wherein the treating flow is provided under a pressure not more than the hydrostatic head relative to surface at the point of treating flow discharge from said well.

21. A method in accordance with claim 20, wherein the treating flow is provided under a pressure of from 6 to 40 psig.

22. A system for remediating a hydrocarbon-contaminated region of a subterranean body of groundwater to destroy or reduce the initial concentration levels of hydrocarbon contaminants, comprising:

(a) a plurality of mutually spaced wells disposed to intersect said groundwater region;

(b) means for generating a test flow of a solution of hydrogen peroxide from one of said wells;

(c) means for monitoring pH changes at each other of said wells as a function of time to detect a pH drop of at least 0.2, whereby to establish the existence of acceptable continuity and well interflow paths for the said region; and

(d) means for providing, subsequent to detecting said pH drop, a treating flow of said hydrogen peroxide solution from one or more of said wells.