Preparing laminated thermoplastics stabilized with bisbenzophenones

• US 5,306,456 A
• Filed: 03/10/1993
• Issued: 04/26/1994
• Est. Priority Date: 03/10/1993
• Status: Expired due to Fees

• Current Assignee: CIBA Specialty Chemicals
• Original Assignee: Ciba-Geigy Corporation (Novartis Ag)
• Inventors: Botkin, James H., Suhadolnik, Joseph, Hendricks, Carmen
• Primary Examiner(s): Thurlow, Jeffery
• Application Number:
  US08/029,211
• Time in Patent Office: 412 Days
• Field of Search: 264/171, 264/211, 425/131.1, 425/133.5, 425/462, 428/412
• US Class Current: 264/173.16
• CPC Class Codes: C08K 5/132 Phenols containing keto groups , e.g. benzophenones
• CPC Class Codes: C08L 69/00 Compositions of polycarbonates; Compositions of derivatives of polycarbonates
• CPC Class Codes: Y10T 428/24967 Absolute thicknesses specified
• CPC Class Codes: Y10T 428/31507 Of polycarbonate

Abstract

Thermoplastic articles, preferably of polycarbonate, are advantageously stabilized by selected bisbenzophenone UV absorbers concentrated in the outer surface or coating layers of the article prepared by coextrusion techniques.

Claims

1. A process for stabilizing a multi-layered, thermoplastic article, prepared by coextrusion, which process comprises coextruding a thermoplastic resin or mixture of thermoplastic resins to give a multi-layered thermoplastic article having an outer UV absorbing thermoplastic layer 0.1 to 10 mil (0.00254 to 0.254 mm) thick, which said outer UV absorbing layer contains 0.1 to 20% by weight of a bisbenzophenone UV absorber of the formula ##STR4## wherein X is a straight or branched chain alkylene of 1 to 16 carbon atoms, o-, m- or p-xylylene or an oxa-alkanediyl of the formula --CH₂ CH₂ [OCH₂ CH₂ ]_n --, --CH₂ CH(CH₃)[OCH₂ CH(CH₃)]_n -- or --CH₂ CH₂ CH₂ CH₂ [OCH₂ CH₂ CH₂ CH₂ ]_n -- where n is 1-4,

Y is hydrogen, straight or branched chain alkyl of 1-18 carbon atoms, and

Z is hydrogen, chloro, straight or branched chain alkyl of 1 to 18 carbon atoms or alkoxy of 1 to 18 carbon atoms.

2. A process according to claim 1 wherein X is alkylene of 2 to 10 carbon atoms.

3. A process according to claim 1 wherein Y is hydrogen or tert-butyl.

4. A process according to claim 1 wherein Z is hydrogen, chloro, tert-butyl or methoxy.

5. A process according to claim 1 wherein X is alkylene of 3 to 10 carbon atoms and Y and Z are both hydrogen.

6. A process according to claim 1 wherein the thermoplastic layer is 0.1 to 5 mil (0.00254 to 0.127 mm) thick.

7. A process according to claim 1 wherein said layer contains 2% to 15% by weight of the bisbenzophenone.

8. A process according to claim 7 wherein said layer contains 5% to 10% by weight of the bisbenzophenone.

9. A process according to claim 1 wherein the thermoplastic article and the coating layer are of the same thermoplastic resin or different thermoplastic resins.

10. A process according to claim 9 wherein the thermoplastic resin is selected from the group consisting of aromatic polycarbonates, polyesters, polyester carbonates, polyphenylene oxide, polyvinyl chloride, polypropylene, polyethylene, polyacrylates, polymethacrylates and copolymers and blends which are styrene and acrylonitrile on polybutadiene and styrene and maleic anhydride.

11. A process according to claim 10 wherein the thermoplastic resin is a polycarbonate based on a dihydric phenol selected from the group consisting of 2,2-bis-(4-hydroxyphenyl)propane (bisphenol A);

2,4-bis-(4-hydroxyphenyl)-2-methylbutane;

1,1-bis-(4-hydroxyphenyl)cyclohexane;

2,2-bis-(3-chloro-4-hydroxyphenyl)propane;

4,4'"'"'-sulfonyldiphenol; and

1,1-bis-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane.

12. A process according to claim 11 wherein the thermoplastic resin for both the article and the coating layer is a polycarbonate based on bisphenol A.