Broad band pass filter including metal layers and dielectric layers of alternating refractive index

• US 5,337,191 A
• Filed: 04/13/1993
• Issued: 08/09/1994
• Est. Priority Date: 04/13/1993
• Status: Expired due to Fees

• Current Assignee: Photran Corporation
• Original Assignee: Photran Corporation
• Inventors: Austin, R. Russel
• Primary Examiner(s): LaRoche, Eugene R.
• Assistant Examiner(s): Nguyen, Tan
• Application Number:
  US08/046,232
• Time in Patent Office: 483 Days
• Field of Search: 359/359, 359/360, 359/585, 359/586, 359/589, 359/580, 359/885
• US Class Current: 359/885
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3615 Coatings of the type glass/metal/other inorganic layers, at least one layer being non-metallic
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3649 made of metals other than silver
• CPC Class Codes: C03C 2217/734 comprising an alternation of high and low refractive indexes
• CPC Class Codes: G02B 5/282 reflecting for infrared and transparent for visible light, e.g. heat reflectors, laser protection

Abstract

A visible light transmitting, near-infrared reflecting filter for a substrate, comprises a central group of layers (26) including two metal layers (32 and 36) separated by a spacer-layer (34) and bounded by admittance-matching layers (32 and 38). The spacer-layer has an optical thickness of less than one-half wavelength of visible light and the admittance-matching layers have an optical thickness of less than one-quarter wavelength of visible light. On each side of the central group is a group of layers (24 and 28) for boosting near infrared reflectivity of the filter, and for providing low reflection and high transmission for visible light. Each of these near-infrared-reflection-boosting groups including a high refractive index layer (40 and 42) and at least one low refractive index layer (46 and 48). The high index layer has an optical thickness of about one-quarter wavelength at a near-infrared wavelength, and the low refractive index layer has a refractive index of less than one-quarter wavelength at the near-infrared wavelength.

Claims

1. An optical interference filter for a substrate, comprising:

ten layers, said layers designated the first through the tenth in consecutive numerical order beginning with the layer furthest from the substrate;

said first layer of a material having a low refractive index and having an optical thickness of about one-eighth wavelength at a first wavelength in the near-infrared spectral region;

said second and tenth layers of a material having a high refractive index and having an optical thickness of about one-quarter wavelength at said first wavelength;

said third and ninth layers of a material having a low refractive index and having an optical thickness between one-quarter and one eighth wavelength at said first wavelength;

said fourth and eighth layers of a material having a high refractive index and having an optical thickness of less than one-quarter wavelength at a second wavelength in the visible spectrum;

said fifth and seventh layers being metal layers and having a thickness between about 12.5 and 30.0 nanometers;

said sixth layer of a material having a high refractive index and having an optical thickness less than one-half wavelength at said second wavelength;

said first wavelength being between about 800 and 1250 nanometers and said second wavelength being between about 480 and 560 nanometers; and

said high refractive index being between about 1.65 and 2.65 at a wavelength of about 520 nm and said low refractive index being between about 1.35 and 1.65 at a wavelength of about 520 nm.

2. The filter of claim 1 wherein said fifth and seventh layers include silver.

3. The filter of claim 1, wherein said low refractive index material includes a material selected from the group consisting of magnesium fluoride, thorium fluoride, and silicon dioxide, said high refractive index material includes a material selected from the group consisting of zinc sulfide, titanium dioxide, tantalum oxide, niobium oxide, zinc oxide, tin oxide, indium oxide, and indium tin oxide, and said fifth and seventh layers include a metal selected from the group consisting of aluminum, copper, gold, rhodium, and silver.

4. The filter of claim 1 further including an eleventh layer of a material having said low refractive index and having an optical thickness of about one-eighth wavelength at said first wavelength.

5. The filter of claim 1 wherein at least one of said first second third fourth sixth, eighth ninth and tenth layers is formed from two or more sub-layers having a different refractive index.

6. The filter of claim 1, wherein between one of said fifth and seventh layers and a layer adjacent thereto is an auxiliary-layer having a thickness less than about 10 nm, said auxiliary-layer being defined as one or more of the group consisting of adhesion-promoting-layer, glue-layer, barrier-layer, primer-layer, protective-layer, and nucleation-layer.

7. The filter of claim 1 further including an eleventh layer said eleventh layer including a material selected from the group consisting of titanium nitride, zirconium nitride, hafnium nitride, vanadium nitride, niobium nitride, tantalum nitride, and chromium nitride.

8. The filter of claim 7 wherein said eleventh layer has a thickness between about 2 and 40 nanometers.

9. The filter of claim 8 wherein said eleventh layer includes titanium nitride.

10. The filter of claim 9 wherein said eleventh layer has a thickness between about 2 and 40 nanometers.

11. The filter of claim 1 further including an eleventh layer, said eleventh layer including a material selected from the group consisting of chromium, cobalt, iron, molybdenum, neodymium, niobium, nickel, palladium, platinum, tantalum, titanium, tungsten, vanadium, and zirconium.

12. An optical interference filter for a substrate, comprising:

twelve layers, said layers designated the first through the twelfth in consecutive numerical order beginning with the layer furthest from the substrate;

said first layer of a material having a low refractive index and having an optical thickness of about one-eighth wavelength at a first wavelength in the near-infrared spectral region;

said second and twelfth layers of a material having a high refractive index and having an optical thickness of about one-quarter wavelength at said first wavelength;

said third and eleventh layers of a material having a low refractive index and having an optical thickness between one-quarter and one-eighth wavelength at said first wavelength;

said fourth and tenth layers of a material having a high refractive index and having an optical thickness of less than one-quarter wavelength at a second wavelength in the visible spectrum;

said fifth, seventh and ninth layers being metal layers and having a thickness between about 12.5 and 30.0 nanometers;

said sixth and eighth layers of a material having a high refractive index and having an optical thickness less than one-half wavelength at said second wavelength;

said first wavelength being between about 800 and 1250 nanometers and said second wavelength being between about 480 and 560 nanometers; and

said high refractive index being between about 1.65 and 2.65 at a wavelength of about 520 nm and said low refractive index being between about 1.35 and 1.65 at a wavelength of about 520 nm.

13. The filter of claim 12 wherein said metal layers are silver layers.

14. The filter of claim 13, wherein said low refractive index material is thorium fluoride, said high refractive index material is zinc sulphide, and said fifth, seventh, and ninth layers include gold.

15. The filter of claim 13, wherein said low refractive index material is thorium fluoride, said high refractive index material is zinc sulphide, and said fifth, seventh, and ninth layers include silver.

16. The filter of claim 12, wherein said low refractive index material includes a material selected from the group consisting of magnesium fluoride, thorium fluoride, and silicon dioxide, said high refractive index material includes a material selected from the group consisting of zinc sulfide, titanium dioxide, tantalum oxide, niobium oxide, zinc oxide, tin oxide, indium oxide, and indium tin oxide, and said fifth, seventh, and ninth layers include a metal selected from the group consisting of aluminum, copper, gold, rhodium, and silver.