Spatially modified elastic laminates

• US 5,344,691 A
• Filed: 03/30/1990
• Issued: 09/06/1994
• Est. Priority Date: 03/30/1990
• Status: Expired due to Term

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Hanschen, Thomas P., Krueger, Dennis L., Karp, Gregory P.
• Primary Examiner(s): Bell, James J.
• Application Number:
  US07/502,330
• Time in Patent Office: 1,621 Days
• Field of Search: 428/152, 428/156, 428/161, 428/162, 428/163, 428/167, 428/910, 428/179, 428/343, 428/354, 428/411.1, 604/385.2, 604/390
• US Class Current: 428/152
• CPC Class Codes: B29C 55/023 using multilayered plates or sheets
• CPC Class Codes: B29C 61/0616 layered or partially layered preforms, e.g. preforms with layers of adhesive or sealing compositions B29C61/0625 and B29C61/065 take precedence
• CPC Class Codes: B32B 2310/14 Corona, ionisation, electrical discharge, plasma treatment
• CPC Class Codes: B32B 2405/00 Adhesive articles, e.g. adhesive tapes labels B32B2519/00
• CPC Class Codes: B32B 2437/00 Clothing anti-ballistic clothing B32B2571/02
• CPC Class Codes: B32B 25/08 of synthetic resin
• CPC Class Codes: B32B 2555/02 Diapers or napkins
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: B32B 38/0008 Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation heat treatment B32B38/0036
• CPC Class Codes: Y10S 428/91 Product with molecular orientation
• CPC Class Codes: Y10T 428/24446 Wrinkled, creased, crinkled or creped
• CPC Class Codes: Y10T 428/24669 Aligned or parallel nonplanarities
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]

Abstract

Microtextured elastomeric laminates comprising at least one elastomeric layer and at least one thin skin layer is preferably prepared by coextrusion of the layers followed by stretching the laminate past the elastic limit of the skin layers in predetermined regions of the laminate and then allowing the laminate to recover in these regions.

Claims

1. A multi-layer film laminate comprising at least one nonelastomeric skin film layer and at least one core film layer, the at least one skin film layer and the at least one core film layer together forming at least one preferential activation zone where the film laminate will preferentially elongate when stretched, wherein said at least one core film layer is substantially elastomeric, each of said core and skin layers being substantially coextensive and having relatively constant average thicknesses over both the at least one preferential activation zone and an at least one adjacent non-preferential activation zone such that, for a given skin or core layer, the skin or core layer thickness in one zone will be substantially the same as the same skin or core layer thickness in all zones, said at least one skin film layer and/or at least one core film layer are provided such that when the multi-layer laminate is stretched said at least one preferential activation zone will preferentially elongate and can recover in said preferential activation zone to become an elastic zone, of said multi-layer film laminate, and adjacent multi-layer non-preferential activation zones will not preferentially elongate to provide substantially inelastic zones.

2. The elastomeric film laminate of claim 1 wherein said at least one preferential activation zone has lower relative modulus regions over at least 20% of its extents on average in the direction transverse to the stretch direction.

3. The elastomeric film laminate of claim 2 wherein said at least one preferential activation zone has lower modulus regions over at least 50% of its extents on average in the direction transverse to the stretch direction.

4. The elastomeric film laminate of claim 3 wherein non-preferentially activated zones comprise a second zone having lower modulus regions at least 20% less over its extents, on average, transverse to the stretch direction, compared to the comparable extents of said at least one preferential activation zone.

5. The elastomeric film laminate of claim 2 wherein said laminate when stretched will preferentially elongate the low modulus regions in said preferential activation zone past the inelastic deformation limit of at least one skin layer which layer will form a microtextured surface upon recovery of the laminate.

6. The elastomeric film laminate of claim 1 wherein the laminate in said preferential activation zone will recover from its stretched length by 15% or more after at least 1 second.

7. The elastomeric film laminate of claim 6 wherein the laminate will recover from its stretched length by 15% after at least 5 seconds.

8. The elastomeric film laminate of claim 7 wherein the laminate will recover from its stretched length by 15% after at least 20 seconds.

9. The elastomeric film laminate of claim 8 wherein the laminate will recover from its stretched length by less than 15% after 20 seconds and when then exposed to an activation temperature above 26.7°

C. will recover by at least 50% of the total recovery.

10. The elastomeric film laminate of claim 1 wherein the recovery can be initiated mechanically.

11. The elastomeric film laminate of claim 1 wherein the laminate recovers by at least 15% after 1 second.

12. The elastomeric film laminate of claim 2 wherein non-preferentially activated zones contain a relatively high modulus region that has been subjected to an annealing process.

13. The elastomeric film laminate of claim 2 wherein said relatively low modulus regions have been subjected to a plasticization treatment.

14. The elastomeric film laminate of claim 2 wherein non-preferentially activated zones contain at least one relatively high modulus region that has been subjected to a crosslinking treatment.

15. The elastomeric film laminate of claim 4 wherein, in at least one layer, a higher modulus polymer composition, than the polymer composition of said layer in at least one low modulus region, is used in said second zone.

16. The elastomeric film laminate of claim 15 wherein said higher modulus polymer composition comprises higher modulus polymer than polymer in said lower modulus polymer composition.

17. The elastomeric film laminate of claim 15 wherein said higher modulus polymer composition and said lower polymer composition are predominately comprised of substantially identical polymers, either or both of which further comprising a modulus modifying additive.

18. The elastomeric film laminate of claim 15 wherein said high modulus polymer composition is a nonelastomer, and said low modulus polymer composition is an elastomeric composition in which at least one layer comprises a core layer.

19. The elastomeric film laminate of claim 1 wherein at least one of said core layers is an inner layer and at least one skin layer is an outer layer.

20. The elastomeric film laminate of claim 16 comprising at least two skin layers.

21. An elastic adhesive tape comprising the elastomeric film laminate of claim 1 wherein an area outside at least one preferential activation zone further comprises an adhesive layer.

22. The elastic adhesive tape of claim 21 wherein two non-preferential activation zones are adjacent to either side of a preferential activation zone wherein adhesive layers on said non-preferential activation zones are on the same face of the laminate, which elastic tape is of a size suitable for use as an adhesive closure tab.

23. The elastic tape of claim 22 comprising a diaper closure tab.

24. The elastic tape of claim 21 wherein said preferential activation zone further comprises a low adhesive backsize on at least one face thereof.

25. The elastomeric film laminate of claim 1 wherein said at least one preferential activation zone is comprised of at least one preferential stress region.

26. The elastomeric film laminate of claim 25 wherein said at least one preferential activation zone has preferential stress regions over at least 20% of the laminate extents, on average, in the direction transverse to the stretch direction.

27. The elastomeric film laminate of claim 26 wherein at least one non-preferential activation zone comprise a second zone having preferential stress regions at least 20% less over its extents, on average, transverse to the stretch direction as compared to the corresponding extents of said at least one preferential activation zone.

28. The elastomeric film laminate of claim 25 wherein said preferential stress region is formed by scoring, ablating, corona treating or removal of material from at least one layer of said region.

34. The elastomeric film laminate of claim 25 wherein said at least one preferential stress region has been corona ablated.

35. The elastomeric film laminate of claim 25 wherein said at least one preferential stress region has microcracks created by corona treatment.

49. The elastomeric film laminate of claim 1 wherein the activated zone width decreases by less than 20% when restretched to the extent of permanent deformation of at least one previously deformed skin layer.

50. The elastomeric film laminate of claim 1 wherein the surface area formed on the microtextured skin layer is at least 50% greater than an untextured surface.

51. The elastomeric film laminate of claim 1 wherein the laminate is a film formed of substantially coextensive layers having relatively constant average thicknesses across the width of the laminate.

52. The elastomeric film laminate of claim 1 wherein the core and skin layers remain in substantially continuous contact in the activated zones following stretching and recovery.

53. The elastomeric film laminate of claim 1 wherein the skin and core layers remain in substantially intermittent contact in the activated zones following stretching and activation.

54. The film laminate of claim 1 wherein the laminate is capable of recovering instantaneously, over time or upon the application of heat depending on the degree of stretch past the deformation limit of at least one skin layer in the activation zones.

55. The elastomeric film laminate of claim 1 wherein the at least partially elastomeric core comprises an A-B-A block copolymer.

56. The elastomeric film laminate of claim 55 wherein the ABA block copolymer comprises a styrene-isoprene-styrene, styrene-butadiene-styrene or styrene-ethylene butylene-styrene block copolymer.

29. A multi-layer film laminate comprising at least one nonelastomeric skin film layer and at least one core film layer, the at least one skin layer and the at least one core layer forming preferential activation regions and non-preferential activation regions for a given skin or core layer, the skin or core layer thickness in one region will be substantially the same as the same skin or core layer thickness in all regions, wherein said at least one core layer is substantially elastomeric in said preferential activation regions, and said at least one skin layer and/or said at least one core layer are provided such that when the multi-layer laminate is stretched, said preferential activation regions can elongate and recover in the elongated regions to an elastic state.

30. The elastomeric film laminate of claim 29 wherein said preferential activation regions define zones of preferential activation on the laminate.

31. The elastomeric film laminate of claim 30 wherein at least some of said preferential and non-preferential activation regions form a pattern which when stretched and recovered will form a patterned surface macrotexture with at least one microstructured skin layer in said preferential activation regions.

32. The elastomeric film laminate of claim 31 wherein both said preferential and non-preferential activation regions in said pattern stretch and are recovered.

33. The elastomeric film laminate of claim 32 wherein both said preferential and non-preferential activation regions in said pattern form microstructured skin layer regions.

36. The elastomeric film laminate of claim 29 wherein said preferential activation regions have been corona ablated.

37. The elastomeric film laminate of claim 29 wherein said preferential activation regions have microcracks formed by corona treatment.

38. An article having a film laminate with elastic regions comprising a film laminate having elasticized preferential activation zones and nonelasticized non-preferential activation zones which laminate is comprised of at least one nonelastomeric skin film layer and at least one at least partially elastomeric core film layer such that, for a given skin or core layer, the skin or core layer thickness in one zone will be substantially the same as the same skin or core layer thickness in all zones.

39. The article of claim 38 wherein said article is a garment further comprising an engagement surface to which the elastomeric laminate is attached.

40. The article of claim 39 wherein said laminate is attached to said engagement surface at said nonelasticized zones.

41. The article of claim 39 comprising a diaper.

42. The article of claim 41 wherein said laminate comprises a diaper closure tab comprising a central elasticized zone and two nonelasticized outer zones at least one of which is adhesive coated on at least one face thereof.

43. The article of claim 41 wherein said laminate comprises an elasticizing element at a leg or waist engaging area and is attached to said engaging surface at said nonelasticized zones.

44. The article of claim 43 wherein said elastic laminate is attached to said engaging surface with adhesive, which adhesive was applied as a hot melt thereby defining annealed nonelasticized zones.

45. The article of claim 38 wherein said nonelasticized and elasticized zones extend continuously across substantially entire extents of said laminate.

46. The article of claim 38 comprising nonelasticized and elasticized regions which form a pattern with single extents intersecting multiple elasticized and nonelasticized regions within a single overall activated elasticized zone.

47. The article of claim 38 wherein said elasticized zones are comprised predominately of relatively low modulus regions and said nonelasticized zones are comprised predominately of relatively high modulus regions.

48. The article of claim 38 wherein said elasticized zones are comprised predominately of regions treated to create preferential stress concentration.