Hollow fiber membrane separation device with a housing made from a flexible material

• US 5,380,433 A
• Filed: 06/01/1993
• Issued: 01/10/1995
• Est. Priority Date: 06/01/1993
• Status: Expired due to Fees

• Current Assignee: L'Air Liquide SA
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.), L'Air Liquide SA
• Inventors: Fillet, Frederic, Leprince-Ringuet, Bruno, Mills, Wayne L., Etienne, Billy J.
• Primary Examiner(s): Dawson, Robert A.
• Assistant Examiner(s): Fortuna, Ana M.
• Application Number:
  US08/069,562
• Time in Patent Office: 588 Days
• Field of Search: 210/321.78, 210/321.79, 210/321.8, 210/321.88, 210/321.89, 210/323.2, 210/500.23, 210/500.27, 210/450, 264/249, 264/251, 156/434, 156/69, 156/294, 95/45, 96/8
• US Class Current: 210/321.79
• CPC Class Codes: B01D 2313/20 Specific housing
• CPC Class Codes: B01D 2313/206 characterised by the material
• CPC Class Codes: B01D 53/22 by diffusion manufacturing semi-permeable membranes B01D67/00; form, structure or properties of semi-permeable membranes B01D69/00; material for semi-permeable membranes B01D71/00
• CPC Class Codes: B01D 63/02 Hollow fibre modules
• CPC Class Codes: B01D 63/021 Manufacturing thereof
• CPC Class Codes: B01D 63/0233 forming the bundle
• CPC Class Codes: B01D 63/024 with a single potted end
• CPC Class Codes: B01D 63/0241 being U-shaped
• CPC Class Codes: B01D 63/032 More than two tube sheets for one bundle

Abstract

The present invention is a hollow fiber separation assembly having one or more bundles of hollow fiber membranes with a tubesheet at each end enclosed by an end cap. An impermeable housing, preferably made from a flexible polymeric material, most preferably a shrinkable tubing, contacts and encloses the bundle, extending between the end caps. The polymeric, impermeable housing contacts and compacts the array of fibers in the bundle to enhance axial flow along the outside of individual fibers, protects the fiber bundle between the end caps, and contains the permeated fluid and diverts it to a port or ports at the end(s) of the bundle. This hollow fiber separation device provides a large capacity, and is also low cost, lightweight, may be used as a stand-alone separation device, and does not have a high-pressure section which requires testing.

Claims

1. A hollow fiber separation device comprising:

(a) a bundle of hollow fiber membranes having open bores in one or more tubesheets;

(b) at least one of said tubesheet or tubesheets being enclosed by an end cap; and

(c) a flexible housing made from a polymeric shrinkable material, substantially impermeable to the fluids being treated, contacting and enclosing the bundle and extending between the ends of the bundle, said housing being sealingly in contact with the tubesheet(s) or the end cap(s) or both, at each end of the bundle.

2. The separation device of claim 1 in which the polymeric material is selected from the group of polyesters, polyamides, polypropylenes, polyolefins, polyvinylchlorides, polyurethanes, silicones, ethylene propylene dienes, fluoroelastomers or fluoroelastomers with halogen.

3. The separation device of claim 1 in which the polymeric shrinkable material contacts and consolidates the bundle.

4. The separation device of claim 1 in which the shrinkable material is a shrink-tube.

5. The separation device of claim 1 in which the device is a gas separation device and the housing is substantially impermeable to gaseous fluids.

6. The separation device of claim 1 further comprising:

(a) means for introducing a fluid mixture into the device so as to produce a permeate portion passing through the membranes and a nonpermeate portion which does not pass through the membranes;

(b) means for removing the nonpermeate portion of the fluid mixture from the device; and

(c) means for removing the permeate portion of the fluid mixture from the device.

7. The separation device of claim 1 wherein the end cap enclosing one tubesheet has a port in fluid communication with the outer surface of the fiber bundle and has a circumferential channel in fluid communication with the port and extending around the fiber bundle, and the housing is in sealing contact with the channel in said end cap.

8. The separation device of claim 1 in which the housing, tubesheet(s) and end cap(s) are in overlapping relation.

9. The separation device of claim 1 further comprising one or more tie rods fixedly connected to the end caps.

10. A process for assembling a separation device comprising:

(a) fabricating a bundle of hollow fiber membranes with one or more tubesheets;

(b) machining the tubesheets to open the ends of the hollow fiber membranes;

(c) pacing an end cap having an open end over at least one tubesheet; and

(d) placing a flexible housing made of an impermeable material over the bundle and over the open end of the end cap, said material being a polymeric shrinkable material.

11. The process of claim 10 further comprising placing a second end cap over the open end of the bundle and within the housing.

12. The process of claim 10 in which the impermeable material is caused to shrink into contact with the bundle and sealingly engage the end caps or the tubesheets.

13. The process of claim 10 wherein placing the impermeable material over the bundle consolidates the bundle to decrease the bundle circumference.

14. The process of claim 10 wherein said impermeable material is a shrink-tube.

15. The process of claim 14 wherein the shrink-tube overlaps the end caps and said shrink-tube is caused to shrink thereby sealingly engaging the end caps.