Silver halide light-sensitive material comprising polymerizable layer provided on aluminum support

• US 5,393,651 A
• Filed: 07/08/1994
• Issued: 02/28/1995
• Est. Priority Date: 07/12/1993
• Status: Expired due to Term

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Hoshi, Satoshi
• Primary Examiner(s): Brammer, Jack P.
• Application Number:
  US08/271,916
• Time in Patent Office: 235 Days
• Field of Search: 430/275, 430/278, 430/523, 430/526
• US Class Current: 430/526
• CPC Class Codes: B41N 3/03 Chemical or electrical pretreatment
• CPC Class Codes: G03F 7/0285 Silver salts, e.g. a latent silver salt image

Abstract

A silver halide light-sensitive material is disclosed. The light-sensitive material comprises an aluminum support, an anodic oxide layer and a light-sensitive polymerizable layer in the order. The light-sensitive polymerizable layer contains silver halide, a reducing agent and an ethylenically unsaturated polymerizable compound or a cross-linkable polymer. According to the present invention, an intervening layer is further provided between the anodic oxide layer and the light-sensitive polymerizable layer. The intervening layer contains a compound having a metal cation or a metal oxide anion. The metal cation or the metal oxide anion has a standard electrode potential of 0 V or more.

Claims

1. A silver halide light-sensitive material which comprises an aluminum support, an anodic oxide layer and a light-sensitive polymerizable layer in that order, said light-sensitive polymerizable layer containing silver halide, a reducing agent and an ethylenically unsaturated polymerizable compound or a cross-linkable polymer, wherein an intervening layer is further provided between the anodic oxide layer and the light-sensitive polymerizable layer, said intervening layer containing a compound having a metal cation or a metal oxide anion, and said metal cation or said metal oxide anion having a standard electrode potential of 0 V or more.

2. The silver halide light-sensitive material as claimed in claim 1, wherein the aluminum support is made of an aluminum plate having a metal purity of not less than 90 wt. %.

3. The silver halide light-sensitive material as claimed in claim 1, wherein the aluminum support has a thickness in the range of 0.1 to 0.5 mm.

4. The silver halide light-sensitive material as claimed in claim 1, wherein the aluminum support has a rough surface, on which the anodic oxide layer is provided.

5. The silver halide light-sensitive material as claimed in claim 1, wherein the anodic oxide layer is provided in an amount of not less than 1.0 g/m².

6. The silver halide light-sensitive material as claimed in claim 1, wherein the metal cation or the metal oxide anion is Cu²⁺, Cu⁺, Pd²⁺, Ag⁺, Pt²⁺, Pt⁴⁺, Au³⁺, Hg⁺, Hg²⁺, MnO₄^-, Cr₂ O₇^2-, Co³⁺, Rh³⁺, FeO₄^2- or ReO₄^-.

7. The silver halide light-sensitive material as claimed in claim 1, wherein the compound having the metal cation or the metal oxide anion is copper(II) nitrate, palladium(II) nitrate, silver nitrate, mercury(II) nitrate, copper(II) sulfate, palladium(II) sulfate, silver sulfate, mercury(I) sulfate, mercury(II) sulfate, copper(I) chloride, copper(II) chloride, palladium(II) chloride, silver chloride, silver bromide, silver iodide, potassium tetrachloroplatinate(II), potassium chloroplatinate(IV), chloroplatinic(IV) acid, chloroauric(III) acid, sodium chloroaurate(III), potassium cyanoaurate(III), silver nitrate, palladium acetate, silver carbonate, silver chlorate, silver chromate, silver 4-cyclohexylbutyric acid, silver 2,3-dibromopropionate, silver iodate, silver lactate, silver nitrite, silver perchlorate, silver tetrafluoroborate, silver thiocyanate, silver p-toluenesulfonate, silver vanadate, iron(VI) oxide hydrate, perrhenic acid, rhodium(III) chloride or cobalt(III) hydroxide.

8. The silver halide light-sensitive material as claimed in claim 1, wherein the metal cation or the metal oxide anion has a standard electrode potential in the range of 0.3 to 1.0 V.

9. The silver halide light-sensitive material as claimed in claim 1, wherein the intervening layer contains the compound having the metal cation or the metal oxide anion in an amount of 0.0001 to 20 wt. % based on an amount of a coating solution of the intervening layer.

10. The silver halide light-sensitive material as claimed in claim 1, wherein the intervening layer further contains a hydrophilic polymer as a binder.

11. The silver halide light-sensitive material as claimed in claim 1, wherein the intervening layer further contains a binder in an amount of 0.1 to 30 wt. % based on an amount of a coating solution of the intervening layer.

12. The silver halide light-sensitive material as claimed in claim 1, wherein the intervening layer has a dry coating amount in the range of 0.1 to 100 mg/m².

13. The silver halide light-sensitive material as claimed in claim 1, wherein the light-sensitive polymerizable layer comprises a light-sensitive layer containing silver halide and a polymerizable layer containing the ethylenically unsaturated polymerizable compound or the cross-linkable polymer.

14. The silver halide light-sensitive material as claimed in claim 1, wherein the light-sensitive material further comprises an image formation accelerating layer containing a base precursor.