Neutral, low emissivity coated glass articles and method for making

• US 5,395,698 A
• Filed: 06/04/1993
• Issued: 03/07/1995
• Est. Priority Date: 06/04/1993
• Status: Expired due to Term

• Current Assignee: Vitro Flat Glass LLC (Compagnie De Saint-Gobain)
• Original Assignee: PPG Industries Incorporated (Nouryon BV)
• Inventors: Stewart-Davis, Royann L., Neuman, George A.
• Primary Examiner(s): Robinson, Ellis P.
• Assistant Examiner(s): Speer, Timothy M.
• Application Number:
  US08/072,792
• Time in Patent Office: 641 Days
• Field of Search: 428/428, 428/432, 428/446, 428/448, 428/697, 428/699, 428/701, 428/702, 428/336, 428/212, 428/216, 359/359, 359/580, 359/586
• US Class Current: 428/428
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: G02B 1/10 Optical coatings produced by application to, or surface treatment of, optical elements G02B1/08 takes precedence
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/265 1 mil or less

Abstract

A coated article and method of producing it are disclosed wherein the iridescence caused by the difference between the refractive index of a transparent substrate and the refractive index of a metal oxide coating is reduced by means of two intermediate layers, the first of which, closest to the substrate, has a refractive index higher than the refractive index of the substrate but lower than the refractive index of the second, and the second has a refractive index higher than the refractive index of the first but lower than the refractive index of the metal oxide coating. The thicknesses of the two intermediate layers for optimizing a neutral appearance are determined by the thickness and refractive index of the metal oxide coating.

Claims

1. A neutral, low emissivity coated article comprising:

a. transparent substrate having a refractive index in the range of about 1.5 to 1.6;

b. a first transparent coating layer having a refractive index in the range of about 1.66 to 1.73 and a thickness in the range of about 400 to 600 Angstroms;

c. a second transparent coating layer having a refractive index in the range of about 1.76 to 1.83 and a thickness in the range of about 350 to 550 Angstroms; and

d. a metal oxide coating layer having a refractive index of at least 1.86 and a thickness sufficient to lower the emissivity of the coated substrate below the emissivity of the uncoated substrate.

2. An article according to claim 1, wherein the metal oxide coating layer is tin oxide.

3. An article according to claim 2, wherein the tin oxide is doped with fluorine to reduce the emissivity of the coated article.

4. An article according to claim 3, wherein the thickness of the tin oxide coating is at least 1600 Angstroms.

5. An article according to claim 4, wherein the thickness of the tin oxide coating is in the range of about 2600 to 3600 Angstroms.

6. An article according to claim 5, wherein the thickness of the tin oxide is in the range of 3000 to 3400 Angstroms.

7. An article according to claim 1, wherein the first transparent coating layer has a refractive index in the range of about 1.68 to 1.72.

8. An article according to claim 7, wherein the first transparent coating layer has a thickness in the range of about 450 to 550 Angstroms.

9. An article according to claim 1, wherein the second coating layer has a refractive index in the range of about 1.78 to 1.82.

10. An article according to claim 9, wherein the second coating layer has a thickness in the range of about 400 to 500 Angstroms.

11. An article according to claim 1, wherein the first transparent coating layer comprises a mixture of silicon oxide and tin oxide.

12. An article according to claim 1, wherein the second transparent coating layer comprises a mixture of silicon oxide and tin oxide.

13. An article according to claim 1, wherein the first and second transparent coating layers comprise a mixture of silicon oxide and tin oxide.

14. An article according to claim 13, wherein the metal oxide coating layer is tin oxide.