Exhaust gas purification apparatus for an internal combustion engine

• US 5,402,641 A
• Filed: 07/20/1993
• Issued: 04/04/1995
• Est. Priority Date: 07/24/1992
• Status: Expired due to Term

• Current Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Original Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Inventors: Murakami, Fumitada, Asanuma, Takamitsu, Iguchi, Satoshi, Tanaka, Toshiaki, Takeshima, Shinichi, Katoh, Kenji, Goto, Masato, Kihara, Tetsuro
• Primary Examiner(s): Hart, Douglas
• Application Number:
  US08/094,799
• Time in Patent Office: 623 Days
• Field of Search: 60/277, 60/285, 60/297, 60/301
• US Class Current: 60/285
• CPC Class Codes: B01D 2255/2042 Barium
• CPC Class Codes: B01D 2255/20761 Copper
• CPC Class Codes: B01D 53/0454 Controlling adsorption controlling temperature swing adsorption B01D53/0462, controlling pressure swing adsorption B01D53/047
• CPC Class Codes: B01D 53/8696 Controlling the catalytic process
• CPC Class Codes: B01D 53/9422 for removing nitrogen oxides by NOx storage or reduction by cyclic switching between lean and rich exhaust gases (LNT, NSC, NSR)
• CPC Class Codes: B01D 53/9481 Catalyst preceded by an adsorption device without catalytic function for temporary storage of contaminants, e.g. during cold start
• CPC Class Codes: B01D 53/9495 Controlling the catalytic process
• CPC Class Codes: F01N 13/009 having two or more separate purifying devices arranged in series
• CPC Class Codes: F01N 2240/18 an adsorber or absorber
• CPC Class Codes: F01N 2250/12 absorption or adsorption, and catalytic conversion
• CPC Class Codes: F01N 2390/02 using electric components only
• CPC Class Codes: F01N 2430/06 by varying fuel-air ratio, e.g. by enriching fuel-air mixture
• CPC Class Codes: F01N 2570/04 Sulfur or sulfur oxides
• CPC Class Codes: F01N 3/0842 Nitrogen oxides
• CPC Class Codes: F01N 3/20 specially adapted for catalytic conversion F01N3/22 takes precedence; Methods of operation or control of catalytic converters
• CPC Class Codes: F02D 2200/0606 Fuel temperature
• CPC Class Codes: F02D 41/028 Desulfurisation of NOx traps or adsorbent
• CPC Class Codes: F02D 41/1446 the characteristics being exhaust temperatures
• CPC Class Codes: F02D 41/1475 Regulating the air fuel ratio at a value other than stoichiometry
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

An NOx absorbent is installed in an exhaust conduit of an internal combustion engine capable of fuel combustion at lean air-fuel ratios. An oxygen concentration is repeatedly or continuously decreased by, for example, switching the air-fuel from the lean air-fuel ratio to a stoichiometric or rich air fuel ratio when the exhaust gas temperature is higher than 550° C. or when NOx absorbent temperature is higher than 500° C. As a result, the SOx absorbed in the NOx absorbent during lean air-fuel ratio, low temperature operation is released from the NOx absorbent, and the SOx-poisoned NOx absorbent is recovered.

Claims

1. An exhaust gas purification apparatus for an internal combustion engine comprising:

an internal combustion engine capable of fuel combustion at lean air-fuel ratios and an exhaust conduit connected to the engine;

an NOx absorbent installed in the exhaust conduit and including at least one element selected from the group consisting of alkaline earth, rare-earth, alkaline metals, and oxides of alkaline earth, rare-earth, and alkaline metals, the NOx absorbent absorbing NOx included in exhaust gas having excess oxygen therein and releasing the NOx which the NOx absorbent has absorbed when an oxygen concentration of the exhaust gas decreases;

operating condition detecting means for detecting an operating condition of the engine;

operating condition determining means for determining whether the exhaust gas includes excess oxygen and for determining whether one of an exhaust gas temperature and an NOx absorbent temperature is high; and

exhaust gas oxygen concentration control means for decreasing the oxygen concentration of the exhaust gas flowing into the NOx absorbent when the operating condition determining means determines that the exhaust gas includes excess oxygen and that one of an exhaust gas temperature and an NOx absorbent temperature is high.

2. An apparatus according to claim 1, further comprising a three-way catalyst installed in the exhaust conduit downstream of the NOx absorbent.

3. An apparatus according to claim 1, wherein the NOx absorbent comprises a Ba-Cu-O base absorbent.

4. An apparatus according to claim 1, wherein the operating condition detecting means includes an engine speed sensor and an engine load sensor.

5. An apparatus according to claim 1, wherein the operating condition determining means determines that the exhaust gas or NOx absorbent temperature is high when the exhaust gas temperature is higher than 550°

C. or the NOx absorbent temperature is higher than 500°

C.

6. An apparatus according to claim 1, wherein the exhaust gas oxygen concentration control means includes means for repeatedly decreasing the exhaust gas oxygen concentration by controlling fuel injection so that the oxygen concentration of the exhaust gas is repeatedly decreased.

7. An apparatus according to claim 6, wherein the means for repeatedly decreasing the exhaust gas oxygen concentration includes means for controlling the fuel injection so that a sequence of a lean air-fuel ratio operation conducted for a first time period, followed by a rich air-fuel ratio operation conducted for a second time period, is repeated.

8. An apparatus according to claim 7, wherein the first time period is about two minutes and the second time period is about three seconds.

9. An apparatus according to claim 1, wherein the exhaust gas oxygen concentration control means includes means for continuously decreasing exhaust gas oxygen concentration in order to decrease the exhaust gas oxygen concentration and maintain the decreased oxygen concentration for a predetermined time period.

10. An apparatus according to claim 1, wherein the exhaust gas oxygen concentration control means includes a fuel cutting ceasing means for ceasing fuel cutting when the exhaust gas includes excess oxygen and one of the exhaust gas temperature and the NOx absorbent temperature is high.

11. An apparatus according to claim 10, wherein the condition where fuel cutting is to be conducted is a deceleration condition.

12. An apparatus according to claim 1, wherein the operating condition determining means includes means for determining whether one of a current exhaust gas temperature and an NOx absorbent temperature is within a predetermined temperature range, and wherein the exhaust gas oxygen concentration control means decreases the oxygen concentration only when one of the current exhaust gas temperature and the NOx absorbent temperature is within the predetermined temperature range.

13. An apparatus according to claim 12, wherein the predetermined temperature range is a range of 550°

C.-750°

C. in exhaust gas temperature and a range of 500°

C.-700°

C. in NOx absorbent temperature.

14. An apparatus according to claim 1, wherein the operating condition determining means includes means for determining whether one of a current exhaust gas temperature and an NOx absorbent temperature is within a predetermined temperature range, and wherein the exhaust gas oxygen concentration control means includes means for delaying an objective ignition timing when one of the current exhaust gas temperature and the NOx absorbent temperature is within the predetermined temperature range.

15. An apparatus according to claim 14, wherein the predetermined temperature range is a range of 550°

C.-750°

C. in exhaust gas temperature and a range of 500°

C.-700°

C. in NOx absorbent temperature.

16. An apparatus according to claim 1, wherein the operating condition detecting means includes a vehicle speed sensor and wherein the operating condition determining means includes means for determining whether or not an exhaust gas or NOx absorbent temperature is high by determining whether a current vehicle speed detected by the vehicle speed sensor is at least as great as a predetermined speed.

17. An apparatus according to claim 1, wherein the predetermined speed is about 100 Km/h.

18. An apparatus according to claim 1, wherein the exhaust gas oxygen concentration control means includes means for modifying a reference temperature for switching an engine operation from a lean air-fuel operation to a rich air-fuel operation so that the higher the temperatures that the NOx absorbent has experienced, the higher the reference temperature is.

19. An apparatus according to claim 1, wherein the exhaust gas oxygen concentration control means includes means for decreasing the exhaust gas oxygen concentration to allow an NOx absorbent temperature to rise when the NOx absorbent temperature exceeds a predetermined temperature, storing a highest temperature that the NOx absorbent experiences, and ceasing the operation of decreasing the exhaust gas oxygen concentration when the NOx absorbent temperature decreases to a temperature lower than the stored highest temperature by a predetermined temperature decrement.

20. An apparatus according to claim 19, wherein the predetermined temperature is about 500°

C. and the predetermined temperature decrement is about 50°

C.

21. An apparatus according to claim 1, wherein the exhaust gas oxygen concentration control means includes means for ceasing an engine operation at lean air-fuel ratios and for stopping the ceasing of the lean air-fuel ratio operation independently of an NOx absorbent temperature when a predetermined time period has elapsed since the lean air-fuel operation has ceased.

22. An apparatus according to claim 21, wherein the predetermined time period is about ten minutes.

23. An apparatus according to claim 1, wherein the operating condition detecting means includes means for detecting an inlet gas temperature of the NOx absorbent and means for detecting an outlet gas temperature of the NOx absorbent, and wherein the exhaust gas oxygen concentration control means includes means for decreasing the exhaust gas oxygen concentration when the outlet gas temperature of the NOx absorbent exceeds a first predetermined temperature, and wherein the exhaust gas oxygen concentration decreasing operation is stopped when the inlet gas temperature of the NOx absorbent decreases to a temperature below a second predetermined temperature, wherein the second predetermined temperature is lower than the first predetermined temperature.

24. An apparatus according to claim 23, wherein the means for detecting an outlet gas temperature of the NOx absorbent comprises a temperature sensor installed downstream of the NOx absorbent.

25. An apparatus according to claim 23, wherein the first predetermined temperature is about 500°

C. and the second predetermined temperature is about 400°

C.