Optically variable multilayer film and optically variable pigment obtained therefrom

• US 5,437,931 A
• Filed: 10/20/1993
• Issued: 08/01/1995
• Est. Priority Date: 10/20/1993
• Status: Expired due to Term

• Current Assignee: Industrial Technology Research Institute
• Original Assignee: Industrial Technology Research Institute
• Inventors: Lee, Chii-Hua, Chuang, Gi-Horng, Tsai, Rung-Ywan, Ho, Fang-Chuan, Wei, Chaur-Tsang
• Primary Examiner(s): Ryan, Patrick J.
• Assistant Examiner(s): Krynski, William A.
• Application Number:
  US08/139,524
• Time in Patent Office: 650 Days
• Field of Search: 106/22, 106/415, 428/403, 428/328, 428/329, 428/330, 428/331, 428/404, 428/412, 428/480, 428/913, 428/916, 428/446, 428/448, 428/450, 428/195, 428/209
• US Class Current: 428/446
• CPC Class Codes: C23C 14/0005 Separation of the coating from the substrate
• CPC Class Codes: C23C 14/0015 characterized by the colour of the layer
• CPC Class Codes: C23C 14/10 Glass or silica
• CPC Class Codes: C23C 14/18 on other inorganic substrates
• CPC Class Codes: G02B 5/287 comprising at least one layer of organic material
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
• CPC Class Codes: Y10T 428/24917 including metal layer

Abstract

An optically variable pigment being formed from optically variable flakes. The optically variable multilayer is vacuum deposited onto a flexible polyester substrate having being provided with a release layer. An optically variable stack is formed from an opaque metallic reflective layer and two sub-unit film stacks D'"'"'MD symmetrically stacked on the opposite surfaces of the metallic reflective layer. D is adjacent to the reflective layer and is a color-presenting layer and D'"'"' is an outer layer of the stack which is used to protect the multilayer film to obtain better color-presenting. M is a semitransparent metallic layer, e.g. chromium.

Claims

1. An optically variable multilayer film, comprising:

(1) a metallic reflective layer M'"'"';

(2) two sub-unit multilayer stacks symmetrically mounted onto opposite surfaces of the metallic reflective layer M'"'"';

each of the stacks having a structure of D'"'"'MD, wherein D'"'"' and D are a protective layer and a color-presenting layer, respectively, and both are composed of low refractive index, high hardness, chemically stable silicon dioxide;

said protective layer D'"'"' further has an optical thickness which is 1/2 of the wavelength of the desired reflected light; and

M is a semi-transparent metallic layer;

said optically variable multilayer film being deposited on a flexible substrate S with a release layer R made of a neutral detergent, soluble in water or a solvent, deposited between said optically variable multilayer film and said flexible substrate S so as to form a structure of S-R-D'"'"'-M-D-M'"'"'-D-M-D'"'"'.

2. An optically variable multilayer film as set forth in claim 1, wherein each of said sub-unit multilayer stacks has a structure of D'"'"'MDMD.

3. An optically variable multilayer film as set forth in claim 1, being released from said substrate S by solving said release layer R in water or solvent and being flaked and mixed with resin or varnish to form an optically variable paint or ink.

4. An optically variable multilayer film as set forth in claim 1, wherein said color-presenting layer D has an optical thickness which is an integer times the half wavelength of the desired reflected light.

5. An optically variable multilayer film as set forth in claim 1, wherein each of said protective layer D'"'"' and said color-presenting layer D have a refractive index smaller than 1.7.