Thermo-curable and ultraviolet-curable adhesive capable of high precision bonding

• US 5,439,956 A
• Filed: 02/09/1994
• Issued: 08/08/1995
• Est. Priority Date: 07/09/1988
• Status: Expired due to Term

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Noguchi, Hiromichi
• Primary Examiner(s): Berman, Susan W.
• Application Number:
  US08/193,883
• Time in Patent Office: 545 Days
• Field of Search: 522/92, 522/96, 522/97, 522/103
• US Class Current: 522/92
• CPC Class Codes: C08L 2666/22 Macromolecular compounds not provided for in C08L2666/16 - C08L2666/20
• CPC Class Codes: C08L 75/04 Polyurethanes
• CPC Class Codes: C09J 163/10 Epoxy resins modified by unsaturated compounds

Abstract

An adhesive for use in bonding finely processed parts such as parts of ink jet recording head has a composition which essentially contains: (A) a vinylester compound of an urethanated epoxy resin; (B) a partial vinylester compound of a multi-functional epoxy resin; (C) an acrylic reactive diluent; (D) a photopolymerization initiator; and(E) an epoxy cure agent. This adhesive is curable by ultraviolet irradiation or by application of heat, and does not flow or spread into areas where bonding is not necessary, so that finely processed parts are bonded with a high degree of precision of the bonding pattern.

Claims

1. A photosensitive and heat-sensitive adhesive having a composition which comprises:

component (A) comprising a vinylester of an urethanated bisphenol A epoxy resin;

component (B) comprising a partial vinylester of a cresol novolak epoxy resin;

component (C) comprising an acrylic reactive diluent;

component (D) comprising photopolymerization initiator; and

component (E) comprising an epoxy cure agent;

wherein the composition ratio range of said component (A);

said component (B);

said component (C) is 20-60;

20-60;

10-40 by weight percent based on the total weight of said components (A), (B) and (C).

2. An adhesive according to claim 1, wherein the weight ratio between the total weight of said component (A), component (B) and component (C) and the weight of said component (D) ranges between component (A)+component (B)+component (C):

component (D)=100;

1 to 100;

10.

3. An adhesive according to claim 2, wherein the weight ratio between the weight of said component (B) and the weight of component (E) ranges between component (B):

component (E)=100;

1 to 100;

10.

4. An adhesive according to claim 1, wherein the weight ratio between the weight of said component (B) and the weight of component (E) ranges between component (B):

component (E)=100;

1 to 100;

10.

5. An adhesive according to claim 1, wherein the weight ratio between the total weight of said component (A), component (B) and component (C) and the weight of said component (D) ranges between component (A)+component (B)+component (C):

component (D)=100;

1 to 100;

10.

6. An adhesive according to claim 1, wherein the weight ratio between the weight of said component (B) and the weight of component (E) ranges between component (B):

component (E)=100;

1 to 100;

10.

7. An adhesive according to claim 1, wherein said acrylic reactive diluent is one of mono- to quadri-functional acryl monomers.

8. An adhesive according to claim 1, where said epoxy cure agent is one of a cure agent selected from the group consisting of imidazole derivatives, hydrazide, dicyandiamide, aromatic anyhydride polyphenol compound, BF₃ -amine salt, aluminum complex, and alkoxysilane.