Electrophotographic photosensitive member with overlayer and electrophotographic apparatus employing same

• US 5,455,135 A
• Filed: 12/16/1993
• Issued: 10/03/1995
• Est. Priority Date: 12/18/1992
• Status: Expired due to Term

• Current Assignee: Canon Ayutthaya Limited (Canon Inc.)
• Original Assignee: Canon Ayutthaya Limited (Canon Inc.)
• Inventors: Sekiya, Michiyo, Nakamura, Kazushige, Amamiya, Shoji, Tsuji, Haruyuki, Maruyama, Akio, Nagahara, Shin, Yamagami, Masaaki
• Primary Examiner(s): MARTIN, ROLAND E
• Application Number:
  US08/167,049
• Time in Patent Office: 656 Days
• Field of Search: 430/58, 430/66, 430/67, 355/211, 358/300, 358/302
• US Class Current: 430/59.6
• CPC Class Codes: G03G 5/14704 comprising inorganic material
• CPC Class Codes: G03G 5/14786 Macromolecular compounds characterised by specific side-chain substituents or end groups
• CPC Class Codes: G03G 5/14791 Macromolecular compounds characterised by their structure, e.g. block polymers, reticulated polymers, or by their chemical properties, e.g. by molecular weight or acidity

Abstract

An electrophotographic photosensitive member includes an electroconductive substrate, a photosensitive layer disposed on the electroconductive substrate, and a protective layer disposed on the photosensitive layer, the protective layer containing a resin formed by polymerization of compounds each having two or more ion polymerizable functional groups, and electroconductive particles.

Claims

1. An electrophotographic photosensitive member comprising:

an electroconductive substrate;

a photosensitive layer disposed on said electroconductive substrate; and

a protective layer disposed on said photosensitive layer,

said protective layer containing a resin formed by ionic polymerization of compounds each having two or more ionic polymerizable functional groups, and electroconductive particles.

2. An electrophotographic photosensitive member according to claim 1, wherein said resin has a crosslinked structure.

3. An electrophotographic photosensitive member according to claim 1, wherein said compound has three or more ionic polymerizable functional groups.

4. An electrophotographic photosensitive member according to claim 1, wherein said protective layer is formed by hardening a mixture containing the compounds and the electroconductive particles.

5. An electrophotographic photosensitive member according to claim 1, wherein said ionic polymerizable functional group is selected from the group consisting of epoxy materials, vinyl ethers, electron donative vinyl materials, ring ethers, thiirane ring materials and ring polyorganosiloxane.

6. An electrophotographic photosensitive member according to claim 4, wherein the mixture is hardened by irradiation with light in the presence of a photopolymerization initiator.

7. An electrophotographic photosensitive member according to claim 6, wherein said photopolymerization initiator is selected from the group consisting of aromatic diazonium salt, aromatic halonium salt, photosensitive aromatic onium salt of group IVa element and photosensitive aromatic onium salt of group Va element.

8. An electrophotographic photosensitive member according to claim 6, wherein said light is ultraviolet radiation.

9. An electrophotographic photosensitive member according to claim 1, wherein said electroconductive particles are selected from the group consisting of metal particles, metal oxide particles and carbon black.

10. An electrophotographic photosensitive member according to claim 9, wherein said electroconductive particles are metal oxide particles.

11. An electrophotographic photosensitive member according to claim 1, wherein said electroconductive particles have an average primary particle size of 0.1 μ

m or less.

12. An electrophotographic photosensitive member according to claim 11, wherein said electroconductive particles have an average primary particle size of 0.05 μ

m or less.

13. An electrophotographic photosensitive member according to claim 1, wherein said protective layer contains a coupling material.

14. An electrophotographic photosensitive member according to claim 13, wherein said coupling material contains a fluorine atom.

15. An electrophotographic photosensitive member according to claim 1, wherein said photosensitive layer has a charge generating layer and a charge transporting layer.

16. An electrophotographic photosensitive member according to claim 1, wherein an undercoating layer is disposed between said electroconductive substrate and said photosensitive layer.

17. An electrophotographic photosensitive apparatus, comprising:

an electrophotographic photosensitive member;

means for forming an electrostatic latent image on said photosensitive member;

means for developing the formed electrostatic latent image; and

means for transferring a developed image to a transfer medium,

said electrophotographic photosensitive member comprising an electroconductive substrate, a photosensitive layer disposed on said electroconductive substrate, and a protective layer disposed on said photosensitive layer,

said protective layer containing a resin formed by ionic polymerization of compounds each having two or more ionic polymerizable functional groups, and electroconductive particles.

18. A device unit comprising:

an electrophotographic photosensitive member and at least one means selected from a group consisting of charging means, developing means and cleaning means,

said electrophotographic photosensitive member comprising an electroconductive substrate, a photosensitive layer disposed on said electroconductive substrate and a protective layer disposed on said photosensitive layer,

said protective layer containing a resin formed by ionic polymerization of compounds each having two or more ionic polymerizable functional groups, and electroconductive particles,

said unit integrally supporting said electrophotographic photosensitive member and at least one means selected from the group consisting of said charging means, said developing means and said cleaning means, and

said unit being made attachable/detachable to and from an apparatus body.