Biodegradable moldable products and films comprising blends of starch esters and polyesters

• US 5,462,983 A
• Filed: 07/27/1993
• Issued: 10/31/1995
• Est. Priority Date: 07/27/1993
• Status: Expired due to Term

• Current Assignee: Starpol, Inc.
• Original Assignee: Evercorn Inc.
• Inventors: Bloembergen, Steven, Narayan, Ramani
• Primary Examiner(s): Short, Patricia A.
• Application Number:
  US08/097,563
• Time in Patent Office: 826 Days
• Field of Search: 523/128, 524/51, 524/599
• US Class Current: 524/51
• CPC Class Codes: C08L 2201/06 Biodegradable
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/26 Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00
• CPC Class Codes: C08L 3/06 Esters
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence
• CPC Class Codes: C08L 67/04 Polyesters derived from hydroxycarboxylic acids, e.g. lactones C08L67/06 takes precedence

Abstract

Biodegradable moldable products and films prepared from a compatible blend containing a biodegradable, hydrophobic, starch ester and a biodegradable polyester, and optionally a biodegradable and miscible plasticizer and/or a compatible filler.

Claims

1. A biodegradable moldable product or film product prepared from a compatible blend comprising a biodegradable, hydrophobic, water repellant, amorphous, starch ester having a degree of substitution of about 1.0 to about 2.5 DS and a biodegradable polyester selected from the class consisting of poly (ε

-caprolactone) (PCL), poly(lactic acid) or polylactide (PLA), poly(glycolic acid) or polyglycolide (PGA), bacterial and synthetic poly(β

-hydroxybutyrate-co-β

-hydroxyvalerate) (PHB/V) and poly(β

-hydroxyalkanoates) (PHA).

2. A product as set forth in claim 1 wherein said starch ester has an amylose content of equal to or greater than 50%.

3. A product as set forth in claim 2 wherein said starch ester has an amylose content of equal or greater than 70%.

4. A product as set forth in claim 1 wherein said starch ester has a degree of substitution of 1.2 to 1.7 DS.

5. A product as set forth in claim 1 wherein said starch ester an ester of starch wherein said starch is selected from the group consisting of cornstarch, potato starch, tapioca starch, rice starch, wheat starch, and cassava starch.

6. A product as set forth in claim 1 further including a solvent-type low molecular weight plasticizer.

7. A product as set forth in claim 6 wherein the plasticizer is selected from the group consisting of dipropyl-, dibutyl-, dihexyl-, diheptyl-, dioctyl-, dimethyl- and diethylsuccinate and related esters, glycerol triacetate glycerol mono- and diacetate, glycerol mono-, di and tripropionate, glycerol tributanoate glycerol mono- and dibutaoate, glycerol mono-, di- and tristearate, glycerol esters, lactic acid esters, citric acid esters, adipic acid esters, stearic acid esters, oleic acid esters, ricinoleic acid esters, fatty acid esters, erucic acid esters, soybean oil, and caster oil.

8. A moldable composition comprising a compatible thermoplastic blend of a biodegradable, predominantly amorphous, hydrophobic, water repellant, starch ester having a degree of substitution (DS) of about 1.0 to about 2.5 DS and a biodegradable polyester is selected from the group consisting of poly(ε

-caprolactone) (PCL), poly(lactic acid) or polylactide (PLA), poly(glycolic acid) or polyglycolide (PGA), bacterial and synthetic poly(β

-hydroxybutyrate-co-β

-hydroxyvalerate) (PHB/V), poly(β

-hydroxyalkanoates) (PHA), and aliphatic biodegradable polyesters.

9. A composition of claim 8 in which the starch ester has an amylose content greater than 50% by weight.

10. A composition of claim 8 which contains a filler.

11. A molded product formed by heating a composition of claim 8 so that it is thermoplastic and then shaping it into a product.

12. A method of forming a film which comprises dissolving a composition of claim 8 in a solvent and casting the solution on a solid substrate, removing the solvent, and then removing the film which remains from the solid substrate.

13. A method of forming a product which comprises heating a composition of claim 8 until it is thermoplastic and shaping it into a product.