High resolution low noise optical polarimeter
First Claim
1. A polarimeter comprising in combination:
- first and second means for emitting respective first and second amplitude modulated linearly polarized beams of monochromatic light having a polarization axis, said first amplitude modulated linearly polarized beam of monochromatic light with said polarization axis non-collinear with said polarization axis of said second amplitude modulated linearly polarized beam of monochromatic light, said amplitude modulation including imposition of a sinusoid on both said beams, said first amplitude modulated linearly polarized beam of monochromatic light modulated with said imposed sinusoid out of phase from said imposed sinusoid on said second amplitude modulated linearly polarized beam of monochromatic light;
an optical path including a transparent, optically active sample of known length in said optical path;
means for combining said first and second amplitude modulated linearly polarized beams of monochromatic light and emitting said combined beam into said optical path;
means for separating said combined beam into two orthoganal polarization components in said optical path;
first and second photoelectric detectors for detecting said two orthoganal polarization components and emitting respective signals proportional to said components;
means for subtracting said respective signals from said first and second photoelectric detectors for removing common mode noise and obtaining a received amplitude modulated sinusoid; and
,means for comparing phase of said received amplitude modulated sinusoid with phase of said imposed sinusoids on respective first and second amplitude modulated linearly polarized beams of monochromatic light obtaining a phase difference proportional to polarization rotation within said sample.
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Abstract
Two linearly polarized beams of monochromatic laser light are amplitude modulated with low frequency sinusoids. The first laser is modulated with a sinusoid 90° out of phase from the second laser. The two beams of laser light have their polarization axis fixed and separated by 45°. These two beams are then collimated and combined into one composite beam using simple optics. This composite beam is then allowed to pass through an optically active substance of a calibrated path length. The laser radiation exiting the sample is passed through a optical notch pass filter, reducing any signal that may be present from any polarized ambient light by passing only light of the laser'"'"'s frequency. The composite beam then passes into a beam splitting polarizing cube. This cube has the function of separating the beam into two orthogonal polarization components. The two beams of light exiting the cube are focused onto silicon photoelectric detectors. The cube is oriented such that one of the cube'"'"'s transmission axis is aligned to coincide with the polarization axis of one of the lasers. The current from the detectors is converted into a voltage. The resulting detector voltages are then AC coupled to remove any DC component of the voltage, leaving only signal. These voltages are then subtracted using an instrumentation grade operational amplifier. The subtracted signal is phase shifted in direct proportion to solution concentration. Setting the ratio of laser signal amplitudes greater than unity can further amplify this phase shift to produce high instrument sensitivity.
46 Citations
22 Claims
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1. A polarimeter comprising in combination:
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first and second means for emitting respective first and second amplitude modulated linearly polarized beams of monochromatic light having a polarization axis, said first amplitude modulated linearly polarized beam of monochromatic light with said polarization axis non-collinear with said polarization axis of said second amplitude modulated linearly polarized beam of monochromatic light, said amplitude modulation including imposition of a sinusoid on both said beams, said first amplitude modulated linearly polarized beam of monochromatic light modulated with said imposed sinusoid out of phase from said imposed sinusoid on said second amplitude modulated linearly polarized beam of monochromatic light; an optical path including a transparent, optically active sample of known length in said optical path; means for combining said first and second amplitude modulated linearly polarized beams of monochromatic light and emitting said combined beam into said optical path; means for separating said combined beam into two orthoganal polarization components in said optical path; first and second photoelectric detectors for detecting said two orthoganal polarization components and emitting respective signals proportional to said components; means for subtracting said respective signals from said first and second photoelectric detectors for removing common mode noise and obtaining a received amplitude modulated sinusoid; and
,means for comparing phase of said received amplitude modulated sinusoid with phase of said imposed sinusoids on respective first and second amplitude modulated linearly polarized beams of monochromatic light obtaining a phase difference proportional to polarization rotation within said sample. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11)
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12. A process for polarimetry comprising the steps of:
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emitting respective first and second amplitude modulated linearly polarized beams of monochromatic light having a polarization axis, said first amplitude modulated linearly polarized beam of monochromatic light having said polarization axis non-collinear with said polarization axis of said second amplitude modulated linearly polarized beam of monochromatic light, said amplitude modulation including imposition of a sinusoid on both said beams;
said first amplitude modulated linearly polarized beam of monochromatic light modulated with said imposed sinusoid out of phase from said imposed sinusoid on said second amplitude modulated linearly polarized beam of monochromatic light;combining said first and second amplitude modulated linearly polarized beams of monochromatic light; emitting said combined beam into an optical path including a transparent optically active sample of known length in said optical path; placing means for separating said combined beam into two orthoganal polarization components in said optical path; providing first and second photoelectric detectors for detecting said two orthoganal polarization components and emitting a signal proportional to said components; subtracting said signals from said first and second photoelectric detectors for removing common mode noise and obtaining a received amplitude modulated sinusoid; and
,comparing phase of said received amplitude modulated sinusoid with phase of said imposed sinusoids on said respective first and second amplitude modulated linearly polarized beams of monochromatic light obtaining a phase difference proportional to polarization rotation within said sample. - View Dependent Claims (13, 14, 15, 16, 17, 18, 19, 20, 21, 22)
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Specification