Composition for dehalogenation and degradation of halogenated organic contaminants

• US 5,480,579 A
• Filed: 02/13/1995
• Issued: 01/02/1996
• Est. Priority Date: 09/28/1992
• Status: Expired due to Term

• Current Assignee: Adventus Intellectual Property Incorporated (FMC Corporation)
• Original Assignee: W R Grace & Company - CONN (WR Grace & Company)
• Inventors: Cairns, James E., Seech, Alan G., Marvan, Igor J.
• Primary Examiner(s): WYSE, THOMAS G
• Application Number:
  US08/387,644
• Time in Patent Office: 323 Days
• Field of Search: 252/178, 252/180, 252/181, 210/601, 210/602, 210/610, 210/611, 210/615-617, 210/631, 210/679, 210/747, 210/754, 210/757, 210/908, 210/909, 210/150, 210/151, 210/501, 210/503, 210/505, 134/39, 134/40, 134/42
• US Class Current: 252/181
• CPC Class Codes: A62D 2101/22 containing halogen
• CPC Class Codes: A62D 3/02 by biological methods, i.e. processes using enzymes or microorganisms
• CPC Class Codes: B09C 1/10 microbiologically, biologically or by using enzymes
• CPC Class Codes: B09C 1/105 using fungi or plants
• CPC Class Codes: C02F 1/705 Reduction by metals
• CPC Class Codes: C02F 2101/36 containing halogen
• CPC Class Codes: C02F 3/10 Packings; Fillings; Grids packing elements in general B01J19/30, B01J19/32
• CPC Class Codes: C02F 3/1231 Treatments of toxic sewage
• CPC Class Codes: Y02W 10/10 Biological treatment of water, waste water, or sewage
• CPC Class Codes: Y10S 210/908 Organic
• CPC Class Codes: Y10S 210/909 Aromatic compound, e.g. pcb, phenol

Abstract

A method of creating an environment which promotes dehalogenation and/or degradation of halogenated organic chemical contaminants in water, sediment, or soil by adding a combination of fibrous organic matter and certain multi-valent metal particles to the water, sediment or soil.

Claims

1. A composition useful for dehalogenating and/or degrading halogenated organic compounds in water, sediment, or soil comprising a mixture of fibrous organic matter which is capable of supporting bacterial or fungal growth and multi-valent metal particles wherein the weight ratio of metal particles:

organic matter ranges from 1;

1 to 1;

500,000 respectively.

2. A composition according to claim 1 wherein the metal particles are selected from the group consisting of iron, magnesium and mixtures thereof.

3. A composition according to claim 2 wherein the weight ratio of metal particles:

organic matter is in the range of 1;

1 to 1;

10,000 respectively.

4. A composition according to claim 1 wherein the metal is selected from the group consisting of zinc, copper, cobalt, nickel, and mixtures thereof.

5. A composition according to claim 4 wherein the weight ratio of metal particles:

organic matter is in the range 1;

10 to 1;

500,000 respectively.

6. A composition according to claim 1 wherein the size of the metal particles ranges from 0.001 mm to 5 mm.

7. A composition according to claim 1 wherein the fibrous organic matter is plant matter selected from the group consisting of agricultural crops, crop residues, bushes, trees, grass, weeds, algae and mixtures thereof.

8. A composition according to claim 1 wherein the plant matter is ground or cut into particles having a thickness ranging from 0.001 mm to 25 mm.

9. A composition according to claim 7 wherein the plant matter comprises a mixture and wherein individual components of the mixture comprise from 0.1% to 99.9% of the mixture.

10. A composition according to claim 7 wherein the plant matter is supplemented with an organic supplement selected from the group consisting of carbohydrates, organic acids, sewage sludge, potato processing waste, spent distiller grains and spent coffee grounds or with a nitrogenous material selected from the group consisting of amines, nitrate, and mixtures thereof.

11. A composition according to claim 10 wherein the organic supplement is present in an amount which ranges from 0.1 to 49% of the total organic mixture.