Battery tester with stacked thermochromic elements

• US 5,491,420 A
• Filed: 03/01/1993
• Issued: 02/13/1996
• Est. Priority Date: 03/01/1993
• Status: Expired due to Term

• Current Assignee: Gillette Company (The Procter & Gamble Company)
• Original Assignee: Duracell Incorporated (Berkshire Hathaway Incorporated)
• Inventors: Parker, Robert
• Primary Examiner(s): Regan, Maura K.
• Application Number:
  US08/024,423
• Time in Patent Office: 1,079 Days
• Field of Search: 324/435, 324/104, 324/105, 324/426-429, 345/106, 340/636, 359/51, 359/98
• US Class Current: 324/435
• CPC Class Codes: G01D 7/005 Indication of measured value by colour change
• CPC Class Codes: G01R 31/364 Battery terminal connectors with integrated measuring arrangements
• CPC Class Codes: G01R 31/3835 involving only voltage measurements
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 6/505 Cells combined with indicating means for external visualization of the condition, e.g. by change of colour or of light intensity
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A thermochromic apparatus for testing dc voltage sources, particularly small, low voltage disposable batteries, employs a very thin resistive heater layer deposited onto a flexible dielectric substrate. A series of thermochromic elements are "stacked" (mounted on top of one another) at a single thermochromic site proximate the resistive heater. During testing current from the battery flows through the resistive layer heats the substrate, causing a series of thermochromic elements mounted on the substrate to undergo visual "temperature events" (such as color changes) at progressively higher temperatures. The thermochromics may be stacked in a series of discrete films, each film containing a dye for one temperature event. Alternatively, the thermochromics may be contained in microcapsules in a common film.

Claims

1. A thermochromic apparatus for testing an electrical battery source having a anode terminal and a cathode terminal, comprising:

a dielectric substrate having a single test site thereon;

conductive means on the substrate for conducting a test current from the battery source during testing;

anode contact means for electrical connection of said conductive means to the anode terminal of the battery source and

cathode contact means for electrical connection of said conductive means to the cathode terminal of the battery source;

a resistive heater means formed by a segment of the conductive means proximate the single test site for generating heat in response to the test current therethrough which raises the temperature of the single test site from an initial temperature to a higher temperature determined by the resistive heater means and the test status of the battery source, the segment of the conductive means forming the resistive heater means having a constant width for producing a substantially constant temperature throughout the entire test site (the test temperature);

at least two thermochromic layers stacked on said substrate at said test site, a first thermochromic layer over a second thermochromic layer, said thermochromic layers being stacked at the test site so that the second thermochromic layer is closer to the test site on the substrate than is the first thermochromic layer, whereby during battery testing the first thermochromic layer is closer to the viewer than the second thermochromic layer,

said first thermochromic layer being of a first color which is generally opaque at said initial temperature, and clear at a test temperature (T1) which is greater than the initial temperature thereby revealing the color of the second thermochromic layer to indicate that the battery source is at least partially operable;

said second thermochromic layer being of a second color which is generally opaque at said initial temperature and T1, and clear at a test temperature (T2) which is greater than T1 thereby revealing the color of a layer of material therebelow to indicate that the battery source is stronger than if only the first thermochromic layer had cleared.

2. The apparatus of claim 1, wherein the first color is darker than the second color, and the second color is darker than the single test site.

3. The apparatus of claim 1, wherein the single test site on the substrate is defined by a thermally passive visual characteristic of the underlying substrate.

4. The apparatus of claim 3, wherein the thermally passive visual characteristic is an underlying color.

5. The apparatus of claim 4, wherein the color of the thermally passive visual characteristic of the substrate underlying the single test site is visually distinguishable from the surrounding substrate.

6. The apparatus of claim 3, wherein the thermally passive visual characteristic of the single test site includes a symbol.

7. The apparatus of claim 1, wherein the area of the first thermochromic layer means and the area of the second thermochromic are smaller than the area of the single test site.

8. The apparatus of claim 1, wherein the area of the first thermochromic layer means and the area of the second thermochromic are larger than the area of the single test site.

9. The apparatus of claim 1, wherein the first thermochromic layer means is a first discrete film containing a first thermochromic dye positioned at the single test site, and the second thermochromic is second discrete film containing a second thermochromic dye positioned between the first discrete film the substrate underlying and the single test site.

10. The apparatus of claim 9, further comprising a third discrete film containing a third thermochromic dye positioned between the second discrete film and the substrate underlying the single test site, and of a third color which is generally opaque at Tam and T1 and T2, and clears at a third temperature T3 which is greater than T2,

the first thermochromic dye optically responsive to the heat generated by the test current as the test temperature approaches T1 for clearing from the opaque to reveal the second color thereunder indicating the first test status of the battery source,

the second thermochromic dye optically responsive to the heat generated by the test current as the test temperature approaches T2 for clearing from the opaque to reveal the third color thereunder indicating the second test status of the battery source, and

the third thermochromic dye optically responsive to the heat generated by the test current as the test temperature approaches T3 for clearing from the opaque to reveal the portion of the substrate means underlying the single test site indicating a third test status of the battery source.

11. The apparatus of claim 10, wherein the first color is darker than the second color, and the second color is darker than the third color, and the third color is darker than the single test site.

12. The apparatus of claim 1, wherein the first and second thermochromic layers are first and second thermochromic dyes mixed together in a common film positioned at the single test site.

13. The apparatus of claim 12, wherein at least one of the thermochromic dyes is contained in a plurality of microcapsules.

14. The apparatus of claim 12, wherein the first thermochromic dye is contained in a first plurality of microcapsules, and the second thermochromic dye is contained in a second plurality of microcapsules.

15. The apparatus of claim 12, further comprising a third thermochromic dye contained in the common film of a third color which is generally opaque at Tam and T1 and T2, and clears at a third temperature T3 which is greater than T2, the third thermochromic dye optically responsive to the test current as the test temperature approaches T3 for clearing from the opaque to reveal the portion of the substrate underlying the single test site indicating a third test status of the battery source.

16. The apparatus of claim 15, wherein the first thermochromic dye is contained in a first plurality of microcapsules, the second thermochromic dye is contained in a second plurality of microcapsules, and the third thermochromic dye is contained in a third plurality of microcapsules.

17. The apparatus of claim 1, wherein the first thermochromic layer means is a first discrete film positioned at the single test site containing a first thermochromic dye and a second thermochromic dye mixed together within the first discrete film, and the second thermochromic is second discrete film positioned between the first discrete film and the substrate underlying the single test site containing a third thermochromic dye.

18. The apparatus of claim 17, wherein:

the first thermochromic dye is of the first color which is generally opaque at said initial temperature, and clears at the first temperature T1 which is greater than Tam,

the second thermochromic dye is of the second color which is generally opaque at said initial temperature and T1, and clears at the second temperature T2 which is greater than T1,

the third thermochromic dye is of a third color which is generally opaque at Tam, and clears at a third temperature T3 which is greater than T2,

the first thermochromic dye optically responsive to the heat generated by the test current as the test temperature approaches T1 for clearing from the opaque to reveal the second color indicating the first test status of the battery source,

the second thermochromic dye optically responsive to the heat generated by the test current as the test temperature approaches T2 for clearing from the opaque to reveal the third color thereunder indicating the second test status of the battery source, and

the third thermochromic dye optically responsive to the heat generated by the test current as the test temperature approaches T3 for clearing from the opaque to reveal the portion of the substrate underlying the single test site indicating a third test status of the battery source.

19. The apparatus of claim 1, wherein the first thermochromic layer means is a first discrete film positioned at the single test site containing a first thermochromic dye, and the second thermochromic is second discrete film positioned between the first discrete film and the substrate means underlying the single test site and containing a second thermochromic dye and a third thermochromic dye mixed together within the second discrete film.

20. The apparatus of claim 19, wherein:

the first thermochromic dye is of the first color which is generally opaque at said initial temperature, and clears at the first temperature T1 which is greater than Tam,

the second thermochromic dye is of the second color which is generally opaque at said initial temperature and T1, and clears at the second temperature T2 which is greater than T1,

the third thermochromic dye is of a third color which is generally opaque at said initial temperature, and clears at a third temperature T3 which is greater than T2,

the first thermochromic dye optically responsive to the heat generated by the test current as the test temperature approaches T1 for clearing from the opaque to reveal the second color thereunder indicating the first test status of the battery source,

the second thermochromic dye optically responsive to the heat generated by the test current as the test temperature approaches T2 for clearing from the opaque to reveal the third color indicating the second test status of the battery source, and

the third thermochromic dye optically responsive to the heat generated by the test current as the test temperature approaches T3 for clearing from the opaque to reveal the portion of the substrate means underlying the single test site indicating a third test status of the battery source.

21. The apparatus of claim 1, wherein the resistive heater means has a uniform width and a uniform thickness and a uniform sheet resistivity which produce a uniform heat watt density and a uniform test temperature within the resistive heater means.

22. The apparatus of claim 21, wherein the watt density of the resistive heater means is determined by the voltage relationship:

space="preserve" listing-type="equation">W=V.sup.2 /rL.sup.2

where

W is the heat watt density within the resistive heater means,

V is the voltage across the resistive heater means during testing,

r is the sheet resistivity within the resistive heater means, and

L is the length of the heat generating current path through the resistive heater means.

23. The apparatus of claim 22, wherein the voltage "V" varies from about 0.8 volt to about 1.6 volts.

24. The apparatus of claim 22, wherein the sheet resistivity "r" of the resistive heater means is from about 0.1 ohms per square to about 1.0 ohms per square.

25. The apparatus of claim 21, wherein resistive heater means is formed by a segment of the conductive means having a reduced thickness for producing an enhanced Teq therein which is higher than the Teq within the remainder of the conductive means.

26. The apparatus of claim 21, wherein the resistive heater means is coextensive with the conductive means and extends uniformly over the entire substrate means.

27. The apparatus of claim 1, wherein the conductive means is a thin electrically conductive layer formed on the substrate by evaporation deposition.

28. The apparatus of claim 1, wherein the conductive means is a thin electrically conductive layer formed on the substrate by vapor deposition.

29. The apparatus of claim 1, wherein the conductive means is a thin electrically conductive layer formed on the substrate means by sputter deposition.

30. The apparatus of claim 1, wherein the conductive means is a thin electrically conductive layer formed by at least one material selected from the group of materials consisting of Cu, Al, Ag, Au, Ni, stainless steel, and C.

31. The apparatus of claim 1, wherein the conductive means is a thin electrically conductive layer formed of Cu.

32. The apparatus of claim 1, wherein the conductive means is a compound electrically conductive layer comprising:

a highly conductive primary layer deposited on the substrate member; and

a hard secondary layer deposited over the primary layer.

33. The apparatus of claim 32, wherein the primary layer is Cu and the secondary layer is stainless steel.

34. The apparatus of claim 1, wherein the substrate is elongated and flexible forming an elongated conductive means with the anode contact means at one end thereof and the cathode contact means at the other end thereof, for extending between the anode terminal and the cathode terminal of the battery source.