Process for treatment of waste gas from a cyclohexane oxidation reactor

• US 5,505,920 A
• Filed: 10/04/1994
• Issued: 04/09/1996
• Est. Priority Date: 10/04/1994
• Status: Expired due to Fees

• Current Assignee: Bayer AG, Redox Technologies, Inc. (Paper Interactive, Inc.)
• Original Assignee: Bayer AG, Redox Technologies, Inc. (Paper Interactive, Inc.)
• Inventors: Kollar, John, Borger, Gotz-Gerald, Stenger, Matthias
• Primary Examiner(s): Lewis, Michael
• Assistant Examiner(s): Harding, Amy Marie
• Application Number:
  US08/318,010
• Time in Patent Office: 553 Days
• Field of Search: 562/590, 562/600, 423/210, 423/245.1, 423/245.2, 423/245.3, 423/246, 95/230, 95/237
• US Class Current: 423/246
• CPC Class Codes: B01D 53/1487 Removing organic compounds

Abstract

The present invention relates to a process for the treatment of waste gas discharged from a cyclohexane oxidation reactor used in the manufacture of adipic acid, said waste gas containing mainly nitrogen, oxygen, carbon monoxide, carbon dioxide, acetic acid, and up to 10% by weight cyclohexane, as well as other gases or vapors, by (a) scrubbing the waste gas from the cyclohexane oxidation reactor with acetic acid in a first absorption step to reduce the amount of cyclohexane to a residual content of less than about 1% by weight, (b) scrubbing the waste gas from the first absorption step with water in a second absorption step to reduce the amount of acetic acid to a residual content of less than about 1% by weight, and (c) subjecting the scrubbed waste gas from the second absorption step to an oxidation step to oxidize carbon monoxide and other oxidizable components of the waste gas to carbon dioxide and water.

Claims

1. A process for treatment of waste gas discharged from a cyclohexane oxidation reactor from oxidizing cyclohexane to adipic acid said waste gas containing mainly nitrogen, oxygen, carbon monoxide, carbon dioxide, acetic acid, and up to 10% by weight cyclohexane, as well as other gases or vapors, comprising

(a) scrubbing the waste gas from the cyclohexane oxidation reactor with acetic acid in a first absorption step to reduce the amount of cyclohexane to a residual content of less than 1% by weight,

(b) scrubbing the waste gas discharged from the first absorption step with water in a second absorption step to reduce the amount of acetic acid to a residual content of less than 1% by weight, and

(c) subjecting the waste gas discharged from the second absorption step to an oxidation step to oxidize carbon monoxide and other oxidizable components of the waste gas to carbon dioxide and water.

2. A process according to claim 1 wherein the first absorption step (a) is carried out after the waste gas is cooled to reduce the amount of condensable vapors.

3. A process according to claim 2 wherein the waste gas is cooled to about 15°

C.

4. A process according to Claim 1 additionally comprising

(d) passing the waste gas stream discharged from oxidation step (c) at a pressure of 2 to 50 bar through a turbine to supply part of the drive power for a compressor used to introduce a gaseous oxidation agent into the cyclohexane oxidation reactor.