Sensor utilizing thermoelectric material and method for manufacture thereof

• US 5,507,879 A
• Filed: 06/08/1993
• Issued: 04/16/1996
• Est. Priority Date: 06/09/1992
• Status: Expired due to Fees

• Current Assignee: Matsushita Electric Industrial Company Limited (Panasonic Holdings Corporation)
• Original Assignee: Matsushita Electric Industrial Company Limited (Panasonic Holdings Corporation)
• Inventors: Nakagiri, Yasushi, Gyoten, Hisaaki, Yamamoto, Yoshiaki
• Primary Examiner(s): Walsh, Donald P.
• Assistant Examiner(s): CARROLL, CHRISMAN DION
• Application Number:
  US08/072,940
• Time in Patent Office: 1,043 Days
• Field of Search: 136/201, 136/224, 136/236.1, 136/238, 136/239, 136/240, 419/2, 419/66, 428/550
• US Class Current: 136/224
• CPC Class Codes: G01N 25/32 using thermoelectric elements
• CPC Class Codes: G01N 27/002 by investigating the work function voltage
• CPC Class Codes: H10N 10/01 Manufacture or treatment
• CPC Class Codes: H10N 10/17 characterised by the structure or configuration of the cell or thermocouple forming the device
• CPC Class Codes: H10N 10/852 comprising tellurium, selenium or sulfur
• CPC Class Codes: H10N 10/855 comprising compounds containing boron, carbon, oxygen or nitrogen
• CPC Class Codes: Y10T 428/12042 Porous component

Abstract

In a fine structure of a thermoelectric material, fine particles of a material exhibiting Seebeck effect are electrically linked in a loosely contacted state with one another without fusing, having spaces formed at clearances among the fine particles. A method of manufacturing the thermoelectric material comprises a step of compacting fine particles made of a material exhibiting Seebeck effect through a cold pressing. Also, disclosed is a sensor for quantitatively sensing a substance, which comprises a pellet of a powder thermoelectric material, where a temperature difference is generated between two points inside the piece of thermoelectric material. The sensor further includes thermocouples connected to a heater plate (6) and a cooling plate, and a controller which is electrically connected in the loop circuit of the thermocouples for detecting thermoelectric current corresponding to the temperature difference, thereby to control the heating of the heater plate.

Claims

1. A sensor for measuring gas pressure comprising:

a pellet of powder thermoelectric material having a fine structure in which fine particles of one compound exhibiting a Seebeck effect are made by a cold pressing are electrically linked in a state of loose contact with one another without fusing so as to exhibit said effect, having spaces formed at clearances between the fine particles;

means for generating a temperature difference between two points inside said pellet of the thermoelectric material; and

means for sensing a thermal electromotive force generated between the two points inside said pellet as a function of pressure.

2. The sensor is claimed in claim 1, wherein said thermoelectric material has a composition of Fe₀.985 Mn₀.015 Si₂, which is shaped in a rectangular plate.

3. The sensor as claimed in claim 2, wherein said temperature differences generating means includes a heater plate attached to one end of said thermoelectric plate for heating and a cooling plate attached to the other end of said thermoelectric plate for discharging heat.

4. The sensor as claimed in claim 2, wherein said temperature difference generating means further includes control means for controlling the temperature difference between the two points to be kept constant.

5. The sensor as claimed in claim 2, wherein said temperature difference generating means further includes thermocouples connected to the heater plate and the cooling plate, and wherein said control means is electrically connected in the loop circuit of said thermocouples for detecting thermoelectric current corresponding to the temperature difference, thereby to control the heating of the heater plate.

6. The sensor as claimed in claim 2, wherein said thermal electromotive force sensing means further includes first and second electrodes made of silver paste, which are respectively provided in the end portions of said thermoelectric plate, said first electrode being located in a position corresponding to the heater plate while said second electrode being located in position corresponding to the cooling plate.

7. The sensor as claimed in claim 6, wherein said thermal electromotive force sensing means further includes a voltmeter which is electrically connected across said first and second electrodes via silver lead wires for measuring a voltage due to the thermal electromotive force in accordance with the temperature difference.

8. A sensor for measuring gas pressure and density of a specific substance comprising:

a pellet of powder thermoelectric material having a fine structure in which fine particles of one compound exhibiting a Seebeck effect are made by a cold pressing and are electrically linked in a state of loose contact with one another without fusing so as to exhibit said effect, having spaces formed at clearances between the fine particles;

means for generating a temperature difference between two points inside said pellet of the thermoelectric material; and

means for sensing a thermal electromotive force generated between the two points inside said pellet;

and wherein said fine particles of the thermoelectric material are coated with a material having a specificity of adsorption of the specific substance.

9. The sensor as claimed in claim 8, wherein said material having a specificity of adsorption is a formaldehyde dehydrogenase enzyme mixed into polyacrylamide sol.

10. The sensor as claimed in claim 8, wherein said material having a specificity of absorption is formed in a film-like state mainly on the surface of the particles of thermoelectric material.

11. A method of manufacturing a sensor for quantitatively detecting a specific substance in an atmospheric gas comprising the steps of:

a. producing a powder thermoelectric material having a composition of Fe₀.985 Mn₀.015 Si₂ by a method comprising;

i. compacting fine particles made of one compound exhibiting a Seebeck effect, said compacting consisting essentially of a cold pressing to produce a thermoelectric material composed of fine particles loosely contacting each other so as to exhibit said effect, with spaces formed at clearances between the particles, and before said cold pressing, the steps of melting specified amounts of raw materials of Fe, Mn and Si, each having a purity of not less than 99.9% in an arc furnace and then crushing;

ii. repeating the cycle of melting/crushing;

iii. analyzing the composition of the resultant material; and

iv. then adjusting the ratio of the raw materials to derive a composition of Fe₀.985 Mn₀.015 Si₂ ; and

b. processing the resultant powder thermoelectric material into granules each having a size of 5 to 10 μ

m in diameter;

c. mixing formaldehyde dehydrogenase enzyme serving as a material having a specificity of adsorption into polyacrylamide sol and mixing the resultant mixture with the powder thermoelectric material of Fe₀.985 Mn₀.015 Si₂, thereby to obtain a slurry;

d. atomizing the mixed slurry in a dried Ar gas atmosphere thereby to gelatinize the polyacrylamide sol, dispersing excessive solvent by evaporation; and

e. dispersing the obtained powder material in an organic solvent to be formed on a glass substrate through printing.

12. The method of manufacturing a sensor as claimed in claim 11, wherein, in the step of gelatinizing the polyacrylamide sol, a thin-film like polyacrylamide gel including enzyme is formed on the surface of the Fe₀.985 Mn₀.015 Si₂ particles, having the film thickness adjusted to 0.5-5.0 μ

m.