Method for producing blow molded multilayer plastic articles

• US 5,540,878 A
• Filed: 09/27/1994
• Issued: 07/30/1996
• Est. Priority Date: 12/26/1989
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Schrenk, Walter J., Shastri, Ranganath K., Ayres, Ralph E., Roehrs, Herbert C.
• Primary Examiner(s): Timm, Catherine
• Application Number:
  US08/313,669
• Time in Patent Office: 672 Days
• Field of Search: 264/73, 264/75, 264/241, 264/245, 264/297.2, 264/328.8, 264/328.12, 264/513, 264/255, 264/512, 425/130, 425/132, 425/133.1, 425/133.5, 425/523, 425/533, 425/588
• US Class Current: 264/513
• CPC Class Codes: B29C 2043/3433 using dispensing heads, e.g. extruders, placed over or apart from the moulds
• CPC Class Codes: B29C 2043/3618 plurality of counteracting elements
• CPC Class Codes: B29C 2949/0811 Wall thickness
• CPC Class Codes: B29C 43/16 Forging
• CPC Class Codes: B29C 43/203 Making multilayered articles
• CPC Class Codes: B29C 43/361 with pressing members independently movable of the parts for opening or closing the mould, e.g. movable pistons transfer moulding B29C45/02; injection-compression moulding B29C45/561
• CPC Class Codes: B29C 45/16 Making multilayered or multicoloured articles B29C45/0062 takes precedence; feeding colouring materials into the injection unit B29C45/1816
• CPC Class Codes: B29C 48/0017 combined with blow-moulding or thermoforming
• CPC Class Codes: B29C 48/07 Flat, e.g. panels
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/09 Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
• CPC Class Codes: B29C 48/12 Articles with an irregular circumference when viewed in cross-section, e.g. window profiles
• CPC Class Codes: B29C 48/18 the components being layers
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/22 with means connecting the layers, e.g. tie layers or undercuts
• CPC Class Codes: B29C 48/255 Flow control means, e.g. valves flow dividers B29C48/695
• CPC Class Codes: B29C 48/335 Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles
• CPC Class Codes: B29C 48/71 for layer multiplication extrusion of multi-component articles B29C48/16
• CPC Class Codes: B29C 49/22 using multilayered preforms or parisons
• CPC Class Codes: B29C 51/14 using multilayered preforms or sheets
• CPC Class Codes: B29C 69/001 : a shaping technique combined with cutting, e.g. in parts or slices combined with rearranging and joining the cut parts for reinforced material B29C70/545; B29C49/4278, B29C51/268 take precedence
• CPC Class Codes: B29C 69/02 : of moulding techniques only
• CPC Class Codes: B29K 2105/26 : Scrap or recycled material
• CPC Class Codes: B29K 2995/0067 : non-permeable
• CPC Class Codes: B29L 2031/565 : for containers
• CPC Class Codes: B32B 37/153 : at least one layer is extruded and immediately laminated while in semi-molten state

Abstract

A blow molded multilayer plastic article having a large number of layers is formed. First and second diverse thermoplastic streams are extruded into a coextrusion feedblock. In the feedblock the streams are divided into multiple streams and arranged into a first composite stream having a substantially uniform distribution of the layers. The first stream is fed into an interfacial surface generator in which the stream is manipulated to form a second composite stream having even more layers of substantially uniform thickness. This second stream is then formed into a preform such as by injection molding and this preform is blow molded. The second composite stream and preform are formed so that the layers of first and second materials lie generally parallel to a critical surface and possess substantial uniformity when blow molded.

Claims

1. A method of making a blow molded multilayer plastic article, comprising the steps of:

providing first and second streams of first and second diverse thermoplastic resinous materials;

forming via a coextrusion feedblock device said streams into a plurality of layers of substantially uniform thickness;

arranging via said coextrusion feedblock device said layers in a first composite stream such that said composite stream has a substantially uniform distribution of said layers;

manipulating via an interfacial surface generator said first composite stream to form a second composite stream having an increased number of layers of substantially uniform thickness; and

blow molding said second composite stream into a desired configuration having at least one critical surface such that a plurality of said layers of said first and second materials of said second composite stream lie generally parallel to said surface, and further such that at least about 90 percent of said layers of said first and second materials adjacent said critical surface are discrete and substantially continuous.

2. A method as set forth in claim 1, wherein said step of molding said second composite stream comprises the steps of providing a single piston, engaging said second composite stream with only said single piston, and forcing said second composite stream into a mold cavity via said single piston.

3. A method as set forth in claim 1, wherein said step of forming via a coextrusion feedblock device said streams into a plurality of layers of substantially uniform thickness comprises the step of forming each of said streams into three or more layers of substantially uniform thickness.

4. A method as defined in claim 1, further comprising the step of injecting said second composite stream into a mold cavity and said blow molding step comprises the step of blow molding said injected second composite stream into said desired configuration.

5. A method of making a blow molded multilayer plastic article, comprising the steps of:

providing first and second streams of first and second diverse thermoplastic resinous materials;

forming via a coextrusion feedblock device said streams into a plurality of layers of substantially uniform thickness,

arranging via said coextrusion feedblock device said layers in a first composite stream such that said composite stream has a substantially uniform distribution of said layers;

manipulating via an interfacial surface generator said first composite stream to form a second composite stream having an increased number of layers of substantially uniform thickness; and

blow molding said second composite stream into a desired configuration having at least one critical surface such that a plurality of said layers of said first and second materials of said second composite stream lie generally parallel to said surface and said second composite stream in said desired configuration possesses a substantial uniformity of composition with respect to at least said layers of said first and second materials adjacent said critical surface.

6. A method as defined in claim 5, further comprising the step of injecting said second composite stream into a mold cavity and said blow molding step comprises the step of blow molding said injected second composite stream into said desired configuration.

7. A method of making a blow molded multilayer plastic article, comprising the steps of:

providing first and second streams of first and second diverse thermoplastic resinous materials;

providing a stream of a third material;

forming via a coextrusion feedblock device each of said streams into a plurality layers of substantially uniform thickness;

arranging via said coextrusion feedblock device said layers in a selected layer order in a first composite stream such that said composite stream has a substantially uniform distribution of said layers;

manipulating via an interfacial surface generator said first composite stream to form a second composite stream having an increased number of layers of substantially uniform thickness, and

blow molding said second composite stream into a desired configuration having at least one critical surface such that a plurality of said layers of said first, second and third materials of said second composite stream lie generally parallel to said surface and at least about 90 percent of said layers of said first, second and third materials adjacent said critical surface are discrete and substantially continuous.

8. A method as defined in claim 7, further comprising the step of injecting said second composite stream into a mold cavity and said blow molding step comprises the step of blow molding said injected second composite stream into said desired configuration.

9. A method of making a blow molded multilayer plastic article, comprising the steps of:

providing first and second streams of first and second diverse thermoplastic resinous materials;

forming via a coextrusion feedblock device said streams into more than one layer of substantially uniform thickness;

arranging via said coextrusion feedblock device said layers in a first composite stream such that said composite stream has a substantially uniform distribution of said layers;

manipulating via an interfacial surface generator said first composite stream to form a second composite stream having an increased number of layers of substantially uniform thickness; and

blow molding said second composite stream into a desired configuration having at least one critical surface such that a plurality of said layers of said first and second materials of said second composite stream lie generally parallel to said surface, and further such that at least about 90 percent of said layers of said first and second materials adjacent said critical surface are discrete and substantially continuous.