Method of restoring a tooth

• US 5,547,379 A
• Filed: 10/06/1994
• Issued: 08/20/1996
• Est. Priority Date: 10/06/1994
• Status: Expired due to Term

• Current Assignee: ABCO Research LLC
• Original Assignee: Robert W. Hasel
• Inventors: Hasel, Robert W.
• Primary Examiner(s): Swiatek, Robert P.
• Application Number:
  US08/319,456
• Time in Patent Office: 684 Days
• Field of Search: 433/212.1, 433/217.1, 433/226, 433/228.1
• US Class Current: 433/212.1
• CPC Class Codes: A61C 5/00 Filling or capping teeth
• CPC Class Codes: A61C 5/62 Applicators, e.g. syringes or guns
• CPC Class Codes: A61K 6/887 Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: A61K 6/893 Polyurethanes
• CPC Class Codes: C08L 33/00 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 75/16 having terminal carbon-to-carbon unsaturated bonds

Abstract

A method of restoring a tooth. The method comprises the steps of dispensing a curable composition from an applicator and curing the curable composition. The applicator has a needle with a lumen. The composition is injected into a hollow on the tooth to achieve a desired shape. The composition includes curable liquid resin portion and an inorganic filler portion. The curable liquid resin portion has a polymerizable binder resin.

Claims

1. A method of restoring a tooth, comprising:

(a) dispensing a curable composition from an applicator having a needle with a lumen into a hollow on the tooth to achieve a desired shape, the composition comprising;

(i) curable liquid resin portion having a polymerizable binder resin; and

(ii) inorganic filler portion comprising about 30% to about 70% by weight of the inorganic filler portion of fumed silica, and wherein the weight ratio of the curable liquid resin portion to the inorganic filler portion is less than 7;

3; and

(b) curing the curable composition.

2. The method according to claim 1 wherein the polymerizable binder resin is 2,2-bis[4(2-hydroxy-3-methacryloxypropoxy)phenyl]propane.

3. The method according to claim 1 wherein the inorganic filer portion contains a filler selected from the group consisting of silica, barium aluminum silicate, quartz, and silanated products thereof.

4. The method according to claim 1 wherein the curable composition further comprises an initiator of polymerization and is visible light-curable.

5. The method according to claim 1 wherein the curable composition is thixotropic.

6. The method according to claim 1 wherein the dispensed curable composition forms a cured restorative structure of desired shape and smoothness upon curing.

7. The method according to claim 1 wherein the applicator is a syringe and the needle is a syringe needle.

8. The method according to claim 1 further comprising a step of repeating the dispensing and curing steps to achieve a cured restorative structure of a desired shape on the tooth.

9. The method according to claim 1 further comprising a step of preparing the tooth to receive the curable composition by coating the hollow with a bond having a polymerizable binder resin and a polymerizable diluent monomer less viscous than the polymerizable binder resin.

10. The method according to claim 1 wherein the weight ratio of the curable liquid resin portion to the inorganic filler portion is 3:

10 to 1;

1.

11. The method according to claim 1 wherein the weight ratio of the curable liquid resin portion to the inorganic filler portion is 2:

5 to 3;

5.

12. The method according to claim 1 wherein the curable liquid resin portion has a viscosity at 25°

C. of from 500 to 5000 cps and wherein when a bead of the curable composition is deposited on a flat surface of a cured specimen of the curable composition the bead will not run.

13. The method according to claim 1 wherein the curable liquid resin portion comprises a polymerizable binder resin and a polymerizable diluent monomer less viscous than the polymerizable binder resin.

14. The method according to claim 13 wherein the diluent monomer is 2-hydroxyethylmethacrylate.

15. The method according to claim 13 wherein the diluent monomer is triethylene glycol dimethacrylate.

16. The method according to claim 13 wherein the weight ratio of polymerizable binder resin to polymerizable diluent monomer is from 3:

1 to 1;

2.

17. The method according to claim 13 wherein the weight ratio of polymerizable binder resin to polymerizable diluent monomer is from 3:

2 to 2;

3.

18. A method of restoring a tooth having a decayed portion, comprising:

(a) removing the decayed portion and adjacent healthy portion of the tooth to form a hollow on the tooth wherein the volume of the healthy portion removed is 0.5 to 3 times the size of the decayed portion;

(b) coating the surface in the hollow with a curable bond and curing the bond;

(c) dispensing a curable composition from an applicator having a needle with a lumen into the hollow to achieve a desired shape, the composition comprising;

(i) curable liquid resin portion having polymerizable binder resin and polymerizable diluent monomer less viscous then the polymerizable binder resin; and

(ii) inorganic filler portion comprising about 30% to about 70% by weight of the inorganic filler portion of fumed silica, and wherein the weight ratio of the curable liquid resin portion to the inorganic filler portion is less than 7;

3;

(d) curing the curable composition; and

(e) repeating steps (c) and (d) until a cured structure of desired shape and smoothness is obtained.

19. The method according to claim 18 wherein the hollow has walls generally divergently directing outward from the interior of the hollow.

20. The method according to claim 18 wherein in at least one of the dispensing steps, the curable composition is laid as a layer of less than 2 mm thick in the hollow before curing.

21. The method according to claim 18 wherein steps (c) and (d) are repeated at least 3 times.

22. A method of restoring a tooth, comprising:

(a) dispensing a curable composition from an applicator having a needle with a lumen in the form of one of a layer and a drop into a hollow on the tooth, the composition comprising;

(i) curable liquid resin portion having polymerizable binder resin; and

(ii) inorganic filler portion comprising about 30% to about 70% by weight of the inorganic filler portion of fumed silica, and wherein the weight ratio of the curable liquid resin portion to the inorganic filler portion is less than 7;

3;

(b) curing the curable composition, wherein the curable composition shrinks during curing;

(c) dispensing the curable composition from the needle on the cured composition to further fill the hollow and to compensate for the shrinkage to achieve a desired shape;

(d) curing the curable composition; and

(e) repeating steps (c) and (d) until a cured structure of desired shape is formed.

23. A method of restoring a tooth having a decayed portion;

comprising;

(a) removing the decayed portion and adjacent healthy portion of the tooth to form a hollow on the tooth wherein the volume of the healthy portion removed is 0.5 to 3 times the size of the decayed portion;

(b) coating the surface in the hollow with a curable bond and curing the bond;

(c) dispensing a curable, thixotropic composition from a syringe with a needle having a lumen into the hollow to result in a desired shape of the curable composition, the composition comprising;

(i) curable liquid resin portion having polymerizable binder resin including 2,2-bis [4(2-hydroxy-3-methacryloxypropoxy)phenyl]propane and a diluent monomer selected from the group consisting of 2-hydroxyethylmethacrylate and triethylene glycol dimethacrylate, the weight ratio of polymerizable binder resin to polymerizable diluent monomer is from 3;

1 to 1;

2; and

(ii) inorganic filler portion comprising about 30% to about 70% by weight of the inorganic filler fumed silica;

wherein the viscosity of the curable liquid resin portion at 25°

C. is 1000 to 6000 cps and the weight ratio of curable liquid resin portion to inorganic filler portion is 2;

5 to 3;

5;

(d) curing the curable composition with visible light, wherein the curable composition shrinks during curing;

(e) dispensing the curable composition from the needle on the cured composition to further fill the hollow and to compensate for the shrinkage to achieve a desired shape;

(f) curing the curable composition; and

(g) repeating steps (e) and (f) until a cured structure of desired shape is formed;

wherein the cured structure has desired smoothness without polishing.

24. A curable, thixotropic composition injectable through a hypodermic needle for filling a hollow in the restoration of a tooth, comprising:

(a) a curable liquid resin portion having a polymerizable binder resin; and

(b) an inorganic filler portion comprising about 30% to about 70% by weight of the inorganic filler of fumed silica, and wherein the weight ratio of the curable liquid resin portion to the inorganic filler portion is less than 7;

3.