Semiconductor device-encapsulating epoxy resin composition

• US 5,567,749 A
• Filed: 10/25/1994
• Issued: 10/22/1996
• Est. Priority Date: 02/26/1991
• Status: Expired due to Fees

• Current Assignee: Toray Industries Incorporated
• Original Assignee: Toray Industries Incorporated
• Inventors: Tanaka, Masayuki, Sawamura, Yasushi, Teshiba, Toshihiro
• Primary Examiner(s): KRASS, FREDERICK F
• Application Number:
  US08/328,617
• Time in Patent Office: 728 Days
• Field of Search: 523/443, 523/466, 523/457, 523/458, 523/459, 525/481, 525/485, 525/486, 525/487, 525/482, 528/104
• US Class Current: 523/443
• CPC Class Codes: C08G 59/245 aromatic
• CPC Class Codes: C08G 59/621 Phenols
• CPC Class Codes: H01L 23/293 Organic, e.g. plastic
• CPC Class Codes: H01L 2924/00 Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
• CPC Class Codes: H01L 2924/0002 Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00

Abstract

A semiconductor-encapsulating composition comprised of (i) an epoxy resin preferably containing a bifunctional biphenyl-skeletal epoxy resin and/or a bifunctional naphthalene-skeletal epoxy resin, (ii) a curing agent containing 4,4'"'"'-dihydroxybiphenyl, and (iii) 70 to 95% by weight, based on the total epoxy resin composition, of a filler.

Claims

1. A semiconductor-encapsulating epoxy resin composition comprising (i) an epoxy resin, (ii) a curing agent comprising a mixture of 4,4'"'"'-dihydroxybiphenyl and a tri- or higher polyphenol, and (iii) 75 to 95% by weight, based on the total weight of said epoxy resin composition, of a filler;

said epoxy resin including at least one bifunctional epoxy resin selected from the group consisting of bifunctional epoxy resins having a biphenyl radical represented by the following formula (I);

##STR5## wherein each of R¹ through R⁸ independently represents a hydrogen atom, a halogen atom or an alkyl group having 1 to 4 carbon atoms, and bifunctional epoxy resins having a naphthalene radical represented by the following formula (II);

##STR6## wherein two of R¹¹ through R¹⁸ represent a 2,3-epoxypropoxy group and the others independently represent a hydrogen atom, a halogen atom or an alkyl group having 1 to 4 carbon atoms.

2. An epoxy resin composition according to claim 1, wherein the amount of the bifunctional epoxy resin or resins selected from the bifunctional biphenyl-radical epoxy resins and the bifunctional naphthalene-radical epoxy resins, is at least 50% by weight based on the weight of the epoxy resin (i).

3. An epoxy resin composition according to claim 1, wherein the curing agent comprises, based on the weight of the curing agent, 5 to 90% by weight of said 4,4'"'"'-dihydroxybiphenyl and 10 to 95% by weight of said tri- or higher polyphenol.

4. An epoxy resin composition according to claim 1, wherein the amount of the epoxy resin (i) is 3 to 25% by weight based on the total weight of the epoxy resin composition.

5. An epoxy resin composition according to claim 1, wherein the amount of the curing agent is such that the chemical equivalent ratio of the curing agent to the epoxy resin (i) is in the range of 0.5 to 1.5.

6. A semiconductor-encapsulating epoxy resin composition comprising (i) an epoxy resin, (ii) a curing agent comprising a mixture of 4,4'"'"'-dihydroxybiphenyl and another polyfunctional compound selected from the group consisting of a phenol-novolak resin, a cresol-novolak resin, and phenolic compounds represented by the following formula (III):

##STR7## wherein R represents a hydrogen atom, an aryl group having 6 to 7 carbon atoms or an alkyl group having 1 to 4 carbon atoms, and (iii) 75 to 95% by weight, based on the total weight of said epoxy resin composition, of a filler;

said epoxy resin including at least one bifunctional epoxy resin selected from the group consisting of bifunctional epoxy resins having a biphenyl radical represented by the following formula (I);

##STR8## wherein each of R¹ through R⁸ independently represents a hydrogen atom, a halogen atom or an alkyl group having 1 to 4 carbon atoms, and bifunctional epoxy resins having a naphthalene radical represented by the following formula (II);

##STR9## wherein two of R¹¹ through R¹⁸ represent a 2,3-epoxypropoxy group and the others independently represent a hydrogen atom, a halogen atom or an alkyl group having 1 to 4 carbon atoms.