Ink ribbon

• US 5,569,531 A
• Filed: 10/05/1994
• Issued: 10/29/1996
• Est. Priority Date: 10/05/1993
• Status: Expired due to Fees

• Current Assignee: Hitachi Maxell Limited (Hitachi, Ltd.)
• Original Assignee: Hitachi Maxell Limited (Hitachi, Ltd.)
• Inventors: Yamamoto, Yoshinori, Ohiwa, Tsunemi
• Primary Examiner(s): Schwartz, Pamela R.
• Application Number:
  US08/318,117
• Time in Patent Office: 755 Days
• Field of Search: 428/195, 428/207, 428/690, 428/323, 428/206, 428/336, 106/21 R
• US Class Current: 428/323
• CPC Class Codes: B41M 3/144 using fluorescent, luminescent or iridescent effects
• CPC Class Codes: B41M 5/385 characterised by the transferable dyes or pigments infrared absorbing dyes B41M5/465
• CPC Class Codes: B41M 5/392 Additives, other than colour forming substances, dyes or pigments, e.g. sensitisers, transfer promoting agents
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
• CPC Class Codes: Y10T 428/24893 including particulate material
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/265 1 mil or less

Abstract

An ink ribbon comprising a base film and an ink layer having a thickness of from 1 to 10 μm and containing a particle form infrared ray-emitting fluorescent substance having excellent light emitting characteristics.

Claims

1. A ribbon comprising a base film and an infrared ray emitting layer having a thickness of from 1 to 10 μ

m, said infrared ray emitting layer containing infrared ray-emitting fluorescent particles having a size of at least 0.1 μ

m to less than 1 μ

m.

2. The ribbon according to claim 1, wherein said infrared ray-emitting fluorescent particles satisfy the formula:

space="preserve" listing-type="equation">A.sub.1-x-y Nd.sub.x Yb.sub.y PO.sub.4

wherein A is at least one element selected from the group consisting of Al, Bi, B, In, Ga, Sc, Gd, Ce, Y, Lu and La, x is a number of 0 to 0.9, and y is a number of 0 to 0.9, provided that a sum of x and y is larger than 0 and not larger than 1.

3. The ink ribbon according to claim 1, wherein said infrared ray-emitting fluorescent particles satisfy the formula:

space="preserve" listing-type="equation">A.sub.2-p-q Nd.sub.p Yb.sub.q Ca.sub.5 (MoO.sub.4).sub.8

wherein A is at least one element selected from the group consisting of Al, Bi, B, In, Ga, Sc, Gd, Ce, Y, Lu and La, p is a number from 0 to 2, and q is a number from 0 to 2, provided that the sum of p and q is larger than 0 and not larger than 2, whereby said ink layer has light emitting characteristics.

4. The ribbon according to claim 1, wherein said ink layer further contains a dispersant selected from the group consisting of alkylamines and phosphate salts and mixtures thereof.

5. The ribbon of claim 4, wherein the dispersant is present in an amount of from 0.1 to 5% by weight, based on the weight of the infrared ray-emitting fluorescent particles.

6. The ribbon according to claim 1, wherein said infrared ray emitting layer further contains a colorant.

7. The ribbon of claim 1, wherein the infrared ray-emitting fluorescent particles are present in an amount of 60 to 85% by weight, based on the weight of the infrared ray emitting layer.