Electrically conductive polyimide film containing gold (III) ions, composition, and process of making

• US 5,575,955 A
• Filed: 07/22/1994
• Issued: 11/19/1996
• Est. Priority Date: 07/22/1994
• Status: Expired due to Fees

• Current Assignee: The Government of The US As Represented By The Secretary of The Navy, The United States of America As Represented By The Secretary of Agriculture
• Original Assignee: United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration
• Inventors: Stoakley, Diane M., St. Clair, Anne K., Caplan, Maggie L.
• Primary Examiner(s): McGinty, Douglas J.
• Application Number:
  US08/281,804
• Time in Patent Office: 851 Days
• Field of Search: 252/514, 252/519, 427/125, 427/126.5, 106/403
• US Class Current: 252/514
• CPC Class Codes: C08G 73/1039 comprising halogen-containing substituents
• CPC Class Codes: C08L 79/08 Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys

Abstract

An electrically conductive, thermooxidatively stable poltimide, especially a film thereof, is prepared from an intimate admixture of a particular polyimide and gold (III) ions, in an amount sufficient to provide between 17 and 21 percent by weight of gold (III) ions, based on the weight of electrically conductive, thermooxidatively stable polyimide. The particular polyimide is prepared from a polyamic acid which has been synthesized from a dianhydride/diamine combination selected from the group consisting of 3,3'"'"',4,4'"'"'-benzophenonetetracarboxylic dianhydride and 2,2-bis[4-(4 -aminophenoxy)phenyl]hexafluoropropane; 3,3'"'"',4,4'"'"'-benzophenonetetracarboxylic dianhydride and 4,4'"'"'-oxydianiline; 2,2'"'"'-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride and 4,4'"'"'-oxydianiline; and 3,3'"'"'4,4'"'"'-benzophenonetetracarboxylic dianhydride and 2,2-bis(3-aminophenyl)hexafluoropropane.

Claims

1. An electrically conductive, thermooxidatively stable polyimide comprising an intimate admixture of the following components:

a polyimide synthesized from a dianhydride/diamine combination selected from the group consisting of 3,3'"'"',4,4'"'"'-benzophenonetetracarboxylic dianhydride and 2,2-bis[4-(4-aminophenoxy)phenyl]hexafluoropropane;

2,2'"'"'-bis 3,4-dicarboxyphenyl)hexafluoropropane dianhydride and 4,4'"'"'oxydianiline; and

3,3'"'"',4,4'"'"'-benzophenonetetracarboxylic dianhydride and 2,2-bis(3-aminophenyl)hexafluoropropane; and

gold (III) ions in an amount sufficient to provide between about 17 and 21 percent by weight of gold (III) ions, based on the weight of the electrically conductive, thermooxidatively stable polyimide.

2. A film prepared by a processor of applying the electrically conductive, thermooxidatively stable polyimide of claim 1 to a substrate.

3. The electrically conductive, thermooxidatively stable polyimide of claim 1, wherein tetrachloroauric (III) acid is employed to provide the gold (III) ions.

4. The film of claim 2, wherein tetrachloroauric (III) acid is employed to provide the gold (III) ions.

5. A process for preparing an electrically conducting, thermooxidatively stable polyimide film, which process comprises:

preparing a solution of a polyamic acid in a polar organic solvent by reacting in a polar organic solvent a dianhydride/diamine combination selected from the group consisting of;

3,3'"'"',4,4'"'"'-benzophenonetetracarboxylic dianhydride and 2,2-bis[4-(4-aminophenoxy)phenyl]hexafluoropropane;

2,2'"'"'-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride and 4,4'"'"'-oxydianiline; and

3,3'"'"', 4,4'"'"'-benzophenonetetracarboxylic dianhydride and 2,2-bis(3-aminophenyl)hexafluoropropane;

adding to the solution of the polyamic acid in the polar organic solvent gold (III) ions in an amount sufficient to provide between about 17 and 21 percent by weight of gold (III) ions, based on the weight of the electrically conducting, thermooxidatively stable polyimide film;

fabricating a film layer of the solution of the polyamic acid in the polar organic solvent containing gold (III) ions on a surface of a substrate;

imidizing the film layer and recovering a gold (III) ion-containing polyimide film from the substrate.

6. The process of claim 5, wherein tetrachloroauric (III) acid is employed to provide the gold (III) ions.

7. The process of claim 6, wherein the tetrachloroauric (III) acid is freed of moisture before it is added to the solution of the polyamic acid in the polar organic solvent.

8. The process of claim 7, wherein the tetrachloroauric (III) acid which has been freed of moisture is added to the solution of the polyamic acid in the polar organic solvent in an inert gas atmosphere.

9. The process of claim 8, wherein the polar organic solvent is selected from the group consisting of amide-type solvents and ether-type solvents.

10. The process of claim 9, wherein the film layer of the solution of the polyamic acid in the polar organic solvent containing gold (III) ions is fabricated by casting onto a plate in an enclosed, dust-free, low-humidity.

11. The process of claim 10, wherein the film layer is imidized thermally to form a gold (III) ion-containing polyimide film.

12. The process of claim 11, wherein the film layer is heated to a temperature of about 300°

C.