Electrochemical deionization

• US 5,584,981 A
• Filed: 04/24/1995
• Issued: 12/17/1996
• Est. Priority Date: 05/06/1994
• Status: Expired due to Fees

• Current Assignee: Accenture PLC
• Original Assignee: United Kingdom Atomic Energy Authority
• Inventors: Jones, Christopher P., Neville, Mark D., Hill, Michael R. H., Turner, Andrew D.
• Primary Examiner(s): Phasge, Arun S.
• Application Number:
  US08/426,978
• Time in Patent Office: 603 Days
• Field of Search: 204/182.4, 204/182.5, 204/301, 204/536, 204/551, 204/632, 204/647
• US Class Current: 204/536
• CPC Class Codes: B01D 2311/2626 Absorption or adsorption
• CPC Class Codes: B01D 61/48 having one or more compartments filled with ion-exchange material , e.g. electrodeionisation
• CPC Class Codes: B01D 61/485 Specific features relating to the ion-exchange material
• CPC Class Codes: B01J 47/08 subjected to a direct electric current
• CPC Class Codes: C02F 1/42 by ion-exchange ion-exchange in general B01J
• CPC Class Codes: C02F 1/4604 for desalination of seawater or brackish water
• CPC Class Codes: C02F 1/4691 Capacitive deionisation
• CPC Class Codes: C02F 1/4695 electrodeionisation
• CPC Class Codes: C02F 1/62 Heavy metal compounds
• CPC Class Codes: C02F 2001/46133 characterised by the material
• CPC Class Codes: C02F 2001/46138 Electrodes comprising a substrate and a coating
• CPC Class Codes: C02F 2101/103 Arsenic compounds
• CPC Class Codes: C02F 2101/163 Nitrates
• CPC Class Codes: C02F 2103/40 from the manufacture or use of photosensitive materials
• CPC Class Codes: C02F 2201/46115 Electrolytic cell with membranes or diaphragms
• CPC Class Codes: C23F 2201/02 Concrete, e.g. reinforced

Abstract

An electrochemical cell (50) for deionizsation utilizes electrochemical ion-exchange to remove ions from a feed solution. Under the influence of an electric field, ions are adsorbed into, are scored within and pass through a permeable layer (54, 64) of particulate ion-absorbing material and binder, the sheet being several millimeters thick. Water from the feed solution also permeates through the layer (54, 64), so a concentrated solution of the ions emerges from the rear (58) of the layer. The cell does not require separate sources of feed and eluant solutions and can be operated substantially continuously. In a modified cell (70) the flow path for the feed solution passes through a highly porous ion exchanger structure (77), which may be located between two such microporous layers (54, 64). Absorption in such a cell may be effective in the absence of an electric field, elution requiring the periodic application of the electric field.

Claims

1. An electrochemical cell for use in electrochemical deionisation which comprises a water-permeable layer of particulate ion absorbing material, a liquid compartment for a liquid undergoing treatment arranged so the liquid comes into contact with at least part of the layer, electrodes to apply an electric field across at least part of the layer, so that ions move through the layer to emerge into an eluate zone, the layer being at least 1 mm thick in the direction of the electric field, and the particulate material being bound together by a binder so as to be coherent at least in the direction of the electric field, and means to ensure separation of the liquid undergoing treatment from the eluate zone.

2. A cell as claimed in claim 1 wherein the liquid compartment is bounded by two such separation means which separate the liquid undergoing treatment from respective eluate zones.

3. A cell as claimed in claim 2 wherein each separation means comprises a respective said layer, each said layer having a front surface exposed to the liquid compartment and a rear surface exposed to the respective eluate zone.

4. A cell as claimed in claim 2 wherein the layer is highly permeable to the liquid, and wherein each separation means comprises a barrier layer of particulate ion absorbing material bound into a water-permeable coherent structure by a binder and at least 1 mm thick.

5. A cell as claimed in claim 4 wherein the layer occupies the width of the liquid compartment.

6. A cell as claimed in claim 2 wherein each layer is highly permeable to the liquid, and wherein each separation means comprises an electrodialysis membrane.

7. A cell as claimed in claims 6 wherein the layer occupies the width of the liquid compartment.

8. A cell as claimed in claim 1 wherein the separation means comprises a said layer, the said layer having a front surface exposed to the liquid compartment and a rear surface exposed to the eluate zone.

9. A cell as claimed in claim 1 wherein the layer is highly permeable to the liquid, and wherein the separation means comprises a barrier layer of particulate ion absorbing material bound into a water-permeable coherent structure by a binder and at least 1 mm thick.

10. A cell as claimed in claim 1 wherein the layer is highly permeable to the liquid, and wherein the separation means comprises an electrodialysis membrane.

11. A cell as claimed in claim 1 wherein the layer comprises a plurality of macroporous foam blocks incorporating particulate ion absorbing material.

12. A cell as claimed in claim 11 wherein some of the foam blocks incorporate an anion absorbing material and the other foam blocks incorporate a cation absorbing material.

13. A cell as claimed in claim 1 wherein the layer comprises a high porosity fibrous structure, the fibres incorporating particulate ion absorbing material.

14. A method for the removal of ions from an aqueous liquid which comprises establishing an electrochemical cell by causing the aqueous liquid, as cell electrolyte, to be present in the liquid compartment of a cell as claimed in claim 1, and applying a d.c. voltage between the electrodes such that ions are adsorbed into the layer, are stored within the layer, are transported through the layer as a result of the electric field, and are subsequently eluted from the layer, being transported into the eluate zone.

15. A method as claimed in claim 14 wherein the separation means is water-permeable, and wherein water from the electrolyte passes through the separation means along with the transported ions, into the eluate zone, so producing in the eluate zone an eluate solution.

16. A method as claimed in claim 15 wherein an eluate zone of the cell contains an ion exchange material suitable for absorbing the ions, and wherein

(a) in a first stage the aqueous liquid is caused to flow through the said eluate zone of the cell, with no d.c. voltage and so no electric field applied, and

(b) then in a second stage an aqueous liquid is supplied to the liquid compartment and the d.c. voltage is applied, the eluate solution so produced in the eluate zone being such as to cause desorption of the ions absorbed on the ion exchange material.

17. A method as claimed in claim 14 wherein the layer is highly permeable to the liquid and occupies the width of the liquid compartment, the aqueous liquid is caused to flow through the liquid compartment, and wherein

(a) in a first stage no d.c. voltage and so no electric field applied, and

(b) then in a second stage the d.c. voltage is applied so ions absorbed in the layer are transported into the eluate zone.