Birefringent interference polarizer

• US 5,612,820 A
• Filed: 05/30/1995
• Issued: 03/18/1997
• Est. Priority Date: 06/20/1989
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Wheatley, John A., Chang, Victor S., Schrenk, Walter J.
• Primary Examiner(s): Shafer, Ricky D.
• Application Number:
  US08/452,832
• Time in Patent Office: 658 Days
• Field of Search: 359/488, 359/489, 359/490, 359/491, 359/493, 359/494, 359/498, 359/500, 425/131.1, 425/133.5, 427/163.1, 156/229, 156/244.11, 264/1.31, 264/1.34, 264/1.7
• US Class Current: 359/489.12
• CPC Class Codes: B32B 2307/418 Refractive
• CPC Class Codes: B32B 2307/516 mono-axially
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: B32B 2369/00 Polycarbonates
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/20 using fillers, pigments, thixotroping agents
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: B32B 33/00 Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
• CPC Class Codes: B32B 7/023 Optical properties
• CPC Class Codes: G02B 1/04 made of organic materials, e.g. plastics G02B1/08 takes precedence
• CPC Class Codes: G02B 1/08 made of polarising materials
• CPC Class Codes: G02B 5/0841 comprising organic materials, e.g. polymers
• CPC Class Codes: G02B 5/0883 with a refractive index gradient rugate filters G02B5/289
• CPC Class Codes: G02B 5/26 Reflecting filters G02B5/28 takes precedence
• CPC Class Codes: G02B 5/305 including organic materials, e.g. polymeric layers
• CPC Class Codes: G02F 1/133545 Dielectric stack polarisers
• CPC Class Codes: Y10S 359/90 Methods

Abstract

A birefringent interference polarizer which may be fabricated from readily available materials using established coextrusion techniques is provided. The polarizer has a level of light absorption near zero and can be fabricated to polarize and reflect light of specific wavelengths while transmitting light of other wavelengths. The polarizer includes multiple alternating oriented layers of at least first and second polymeric materials having respective nonzero stress optical coefficients which are sufficiently different to produce a refractive index mismatch between the first and second polymeric materials in a first plane which is different from the refractive index mismatch between the first and second polymeric materials in a second plane normal to the first plane. The refractive index mismatch in the first plane is preferably at least 0.03.

Claims

1. A birefringent interference polarizer comprising multiple alternating oriented layers of at least first and second polymeric materials having respective nonzero stress optical coefficients which are sufficiently different to produce a refractive index mismatch between said first and second polymeric materials in a first plane which is different from the refractive index mismatch between said first and second polymeric materials in a second plane normal to said first plane, wherein said layers increase in thickness to produce a layer thickness gradient.

2. The birefringent interference polarizer of claim 1 in which said first and second polymeric materials have substantially equal refractive indices when unoriented.

3. The birefringent interference polarizer of claim 1 in which said oriented first and second polymeric materials have substantially equal refractive indices in one of said planes.

4. The birefringent interference polarizer of claim 1 in which said first and second polymeric materials are uniaxially oriented.

5. The birefringent interference polarizer of claim 1 in which said first polymeric material has a positive stress optical coefficient and said second polymeric material has a negative stress optical coefficient.

6. The birefringent interference polarizer of claim 1 in which said refractive index mismatch in said first plane is at least 0.03.

7. The birefringent interference polarizer of claim 1 in which the optical thickness of each layer is from about 0.09 micrometers to about 0.70 micrometers.

8. The birefringent interference polarizer of claim 1 in which said layers increase in thickness monotonically to produce said layer thickness gradient.

9. The birefringent interference polarizer of claim 1 in which said first polymeric material is selected from the group consisting of polycarbonates and polyethylene terephthalates.

10. The birefringent interference polarizer of claim 1 in which said second polymeric material is selected from the group consisting of polystyrene, copolymers of styrene and acrylonitrile, copolymers of styrene and methyl methacrylate, and polyethylene naphthalate.

11. The birefringent interference polarizer of claim 1 in which said second polymeric material is a syndiotactic polystyrene.

12. The birefringent interference polarizer of claim 1 in which said polarizer reflects and polarizes a portion of the light incident on its surface while transmitting the remainder of said incident light.

13. The birefringent interference polarizer of claim 1 in which said polarizer reflects and polarizes substantially all light incident in said first plane while transmitting and polarizing substantially all light incident in said second plane.

14. The birefringent interference polarizer of claim 1 in which said first and second polymeric materials comprise copolymers or miscible blends of polymers to adjust the respective refractive indices, stress optical coefficients, and glass transition temperatures of said polymeric materials.

15. The birefringent interference polarizer of claim 1 in which a coloring agent is incorporated into at least one layer of said birefringent polarizer.

16. The birefringent interference polarizer of claim 15 in which said coloring agent is selected from the group consisting of pigments and dyes.

17. A tunable birefringent inteference polarizer comprising multiple alternating layers of first and second elastomeric materials having respective nonzero stress optical coefficients which are sufficiently different to produce a refractive index mismatch between said first and second elastomeric materials in a first plane which is different from the refractive index mismatch between said first and second elastomeric materials in a second plane normal to said first plane, said layers increasing in thickness to produce a layer thickness gradient, and said polarizer variably polarizing wavelengths of light dependent upon the degree of elongation of said elastomers.