Apparatus and method for separation of helium and neon

• US 5,626,035 A
• Filed: 07/24/1995
• Issued: 05/06/1997
• Est. Priority Date: 07/24/1995
• Status: Expired due to Term

• Current Assignee: Russian-American Technology Alliance, Inc.
• Original Assignee: Russian-American Technology Alliance, Inc.
• Inventors: Pozvonkov, Felix
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US08/506,218
• Time in Patent Office: 652 Days
• Field of Search: 62/637, 62/639, 62/923
• US Class Current: 62/637
• CPC Class Codes: F25J 2205/20 using solidification of components
• CPC Class Codes: F25J 2215/30 Helium
• CPC Class Codes: F25J 2215/32 Neon
• CPC Class Codes: F25J 2270/904 by liquid or gaseous cryogen in an open loop
• CPC Class Codes: F25J 3/0685 separation of noble gases from air F25J3/04642; in general C01B23/00
• CPC Class Codes: F25J 3/069 of helium
• CPC Class Codes: F25J 3/08 Separating gaseous impurities from gases or gaseous mixtures or from liquefied gases or liquefied gaseous mixturescold traps B01D8/00
• CPC Class Codes: Y10S 62/923 Inert gas

Abstract

An apparatus and method for the cryogenic purification of gaseous mixtures is provided. The apparatus comprises a heat-insulated hermetically sealed vessel which contains liquid hydrogen. Immersed within the liquid hydrogen are a number of serially connected cartridges which contain chips of a thermally conductive mixture. A mixture of neon and helium is input into the apparatus. The neon freezes, while the helium passes through the apparatus in a gaseous state. The resulting neon is allowed to thaw into a liquid or gaseous form and is highly pure.

Claims

1. An apparatus for the separation of a mixture of materials which are gaseous at room temperature to produce a purified material, said apparatus comprising:

(a) a hollow, sealed, insulated cryostat;

(b) a plurality of serially connected cartridges which are disposed inside the cryostat;

wherein the cartridges have a hollow interior cavity and include at least first, second and third openings, where the first and second openings are located in a top surface of the cartridge and the third opening is located in a bottom surface of the cartridge;

(c) input means for introducing the mixture into the apparatus, said input means introducing the mixture into the hollow interior cavity of a first cartridge;

(d) collection means for collecting the purified material, wherein the collection means are connected to the third opening means located on the bottom surface of each of the cartridges;

(e) inlet means for introducing a cryogenic coolant into the cryostat container, said inlet means introducing the cryogenic coolant to a space inside the cryostat container which is outside the cartridges;

(f) connection means for transferring the mixture between adjacent cartridges, wherein the connection means is connected to the second opening in the top surface of one cartridge and connected to the first opening of an adjacent cartridge; and

where the connection means passes through the first opening into the hollow interior cavity of the adjacent cartridge to introduce the mixture into the hollow cavity of the cartridge;

(g) output means for transferring the gaseous mixture from a final cartridge to the exterior of the cryostat.

2. The apparatus of claim 1, wherein the hollow interior cavity of the cartridge is filled with chips of a thermally conductive material.

3. The apparatus of claim 2, wherein the chips are made from a material selected from copper and aluminum.

4. The apparatus of claim 1, wherein the cartridge is in the shape of a cylinder.

5. The apparatus of claim 1, wherein the cartridge has at least one fourth opening in the top surface and at least one corresponding fifth opening in the bottom surface of said cartridge and wherein the fourth opening is connected to the fifth opening in the bottom surface by a hollow tube.

6. The apparatus of claim 5, wherein the cartridge has multiple fourth and fifth openings connected by multiple tubes.

7. The apparatus of claim 1, wherein the insulated cryostat container contains seven serially connected cartridges.

8. The apparatus of claim 1, wherein the cryostat contains additional sets of serially connected cartridges arranged in parallel to the first set of cartridges.

9. A method for the purification of a mixture of materials which are gaseous at room temperature to produce a purified material, comprising:

(a) introducing a gaseous mixture into an apparatus as claimed in claim 1 and passing the gaseous mixture through the serially arranged cartridges while the cartridges are submerged in a cryogenic liquid coolant, until the cartridges are full of a single material which has condensed and solidified;

(b) stopping the introduction of the gaseous mixture into the apparatus;

(c) removing the cryogenic liquid coolant from the cryostat container;

(d) introducing a heating gas into the cryostat container; and

(e) collecting the purified material.

10. The method of claim 9, wherein the gaseous mixture is a mixture of helium gas and neon gas.

11. The method of claim 10, wherein the cryogenic liquid coolant is selected from liquid hydrogen and liquid neon.

12. The method of claim 11, wherein the cryogenic liquid coolant is liquid hydrogen.

13. The method of claim 12, wherein the gaseous mixture is a mixture of helium gas and natural gas.

14. The method of claim 13, wherein the cryogenic liquid coolant is liquid nitrogen.

15. The method of claim 9, wherein the purified material is collected as a gas.

16. The method of claim 9, wherein the purified material is collected as a liquid.