Cell tester device employing a cathodically depositable metal ion electrolyte solution

• US 5,672,440 A
• Filed: 05/31/1995
• Issued: 09/30/1997
• Est. Priority Date: 01/31/1991
• Status: Expired due to Term

• Current Assignee: Eveready Battery Company Incorporated (Energizer Holdings, Inc.)
• Original Assignee: Eveready Battery Company Incorporated (Energizer Holdings, Inc.)
• Inventors: Bailey, John C.
• Primary Examiner(s): Kalafut, Stephen J.
• Application Number:
  US08/455,951
• Time in Patent Office: 853 Days
• Field of Search: 429/92, 429/93, 361/505, 361/526
• US Class Current: 429/93
• CPC Class Codes: G01R 13/403 using passive display devices, e.g. liquid crystal display or Kerr effect display devices
• CPC Class Codes: G02F 1/1525 characterised by a particular ion transporting layer, e.g. electrolyte
• CPC Class Codes: G02F 1/153 Constructional details
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 10/488 Cells or batteries combined with indicating means for external visualization of the condition, e.g. by change of colour or of light density
• CPC Class Codes: H01M 6/505 Cells combined with indicating means for external visualization of the condition, e.g. by change of colour or of light intensity
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A cell tester device for use on an electrochemical cell which comprises an electrolyte containing a cathodically reducible metal ion that changes its visible appearance when it is reduced upon application of a power source.

Claims

1. A cell tester device for an electrochemical cell having a first terminal and a second terminal of opposite polarity;

said device comprising a first electrically conductive electrode adapted to contact the first terminal of the cell;

an electrically conductive layer spaced apart from said electrode and adapted to contact the second terminal of the cell; and

an immobilized metal ion electrolyte disposed between and in contact with the electrode and the conductive layer, said electrolyte comprising a solution of at least one salt of at least one metal which can be cathodically deposited from the solution of one of its simple or complex ions at least at the interface of the electrode and the electrolyte and the deposited metal ion having a different color than the electrolyte so that when the electrode makes contact with the first terminal of the cell and the conductive layer makes contact with the second terminal of the cell, the metal ion in the electrolyte will be reduced to provide a deposit at said interface that has a different visual appearance than the electrolyte that can be used to indicate the condition of the cell and which different visual appearance is observable to the user.

2. The cell tester device of claim 1 wherein the immobilized metal is an aqueous metal ion gelled electrolyte and said salt is a water-soluble salt.

3. The cell tester device of claim 2 wherein the working electrode has pores on its surface and a portion of the gel electrolyte is deposited into the pores.

4. The cell tester device of claim 2 wherein the first electrically conductive electrode is transparent or translucent and comprises indiumtin oxide.

5. The cell tester device of claim 2 wherein the aqueous metal ion gel electrolyte contains a polymer resin.

6. The cell tester device of claim 7 wherein the polymer resin is selected from the group consisting of hydroxyethyl cellulose, hydroxypropyl cellulose, polyethylene oxide, polypropylene oxide and polyvinyl alcohol.

7. The cell tester device of claim 2 wherein the salt of the metal is selected from the group consisting of bismuth, zinc, copper, silver, lead and mixtures thereof.

8. The cell tester device of claim 2 wherein the salt of the metal is bismuth or zinc.

9. The cell tester device of claim 2 wherein the conductive layer is selected from the group consisting of carbon, silver, nickel, titanium and conductive polymers.

12. The cell tester device of claim 2 wherein the first electrically conductive electrode is disposed above the conductive layer and the aqueous metal ion gel electrolyte is secured between the electrode and the conductive layer by an adhesive placed around the periphery of the gel electrolyte and secured to the working electrode and the conductive layer.

16. The cell tester device of claim 2 wherein an electrically nonconductive layer is deposited over the conductive layer and said electrically nonconductive layer is adapted to be secured to a housing of an electrochemical cell.

17. The cell tester device of claim 1 wherein the first electrode is from 0.1 to 250 microns thick the conductive layer is from 0.1 to 250 microns thick and the ionically conductive electrolyte is from 1 to 250 microns thick.

18. The cell tester device of claim 3 wherein the aqueous metal ion gel electrolyte contains a salt of a metal selected from the group consisting of BiCl₃, ZnCl₂, AgCl and PbCl₂.

19. The cell tester device of claim 18 wherein the salt of the metal is BiCl3.

10. A cell tester device for an electrochemical cell having a first terminal and a second terminal of opposite polarity;

said device comprising a first electrically conductive electrode adapted to contact the first terminal of the cell;

an electrically conductive layer spaced apart from said electrode and adapted to contact the second terminal of the cell; and

an immobilized metal ion electrolyte disposed between and in contact with the electrode and the conductive layer, said electrolyte comprising a solution of at least one salt of at least one metal which can be cathodically deposited from the solution of one of its simple or complex ions at least at the interface of the electrode and the electrolyte and the deposited metal ion having a different color than the electrolyte so that when the electrode makes contact with the first terminal of the cell and the conductive layer makes contact with the second terminal of the cell, the metal ion in the electrolyte will be reduced to provide a deposit at said interface that has a different visual appearance than the electrolyte that can be used to indicate the condition of the cell which different visual appearance is observable to the user comprising a substrate and wherein said electrode is disposed on said substrate.

11. The cell tester device of claim 10 wherein the conductive layer is printed on the electrolyte or the electrolyte gel is printed on the conductive layer.

15. The cell tester device of claim 10 wherein the substrate is a plastic film.

21. The cell tester device of claim 10, wherein the electrode is printed on the substrate.

22. The cell tester of claim 21, wherein the substrate is incorporated into a label for an electrochemical cell.

23. The cell tester of claim 22, wherein the label is adhered to a housing of the electrochemical cell.

24. The cell tester of claim 23, wherein the label comprises one or more layers, and the substrate, electrode, conductive layer, and electrolyte are disposed on or within one or more of the layers of the label.

13. A cell tester device for an electrochemical cell having a first terminal and a second terminal of opposite polarity;

said device comprising a first electrically conductive electrode adapted to contact the first terminal of the cell;

an electrically conductive layer spaced apart from said electrode and adapted to contact the second terminal of the cell; and

an immobilized metal ion electrolyte disposed between and in contact with the electrode and the conductive layer, said electrolyte comprising a solution of at least one salt of at least one metal which can be cathodically deposited from the solution of one of its simple or complex ions at least at the interface of the electrode and the electrolyte and the deposited metal ion having a different color than the electrolyte so that when the electrode makes contact with the first terminal of the cell and the conductive layer makes contact with the second terminal of the cell, the metal ion in the electrolyte will be reduced to provide a deposit at said interface that has a different visual appearance than the electrolyte that can be used to indicate the condition of the cell which different visual appearance is observable to the user at least one of the electrode and conductive layer being an elongated member that functions as a variable resistance component for the cell tester device so that the electrical resistance can be varied for the cell tester device depending on the amount of resistance placed in the circuit when the cell tester device is connected to an electrochemical cell.

20. The cell tester device of claim 13 wherein the electrode contains indium-tin oxide, the conductive layer is carbon and the gel electrolyte contains LiBr.

14. A cell tester device for an electrochemical cell having a first terminal and a second terminal of opposite polarity;

said device comprising a first electrically conductive electrode adapted to contact the first terminal of the cell;

an electrically conductive layer spaced apart from said electrode and adapted to contact the second terminal of the cell; and

an immobilized metal ion electrolyte disposed between and in contact with the electrode and the conductive layer, said electrolyte comprising a solution of at least one salt of at least one metal which can be cathodically deposited from the solution of one of its simple or complex ions at least at the interface of the electrode and the electrolyte and the deposited metal ion having a different color than the electrolyte so that when the electrode makes contact with the first terminal of the cell and the conductive layer makes contact with the second terminal of the cell, the metal ion in the electrolyte will be reduced to provide a deposit at said interface that has a different visual appearance than the electrolyte that can be used to indicate the condition of the cell which different visual appearance is observable to the user and wherein said conductive layer functions as the variable resistance component.