Clear cosmetic stick comprising dibenzylidene alditol

• US 5,705,171 A
• Filed: 07/10/1996
• Issued: 01/06/1998
• Est. Priority Date: 03/02/1995
• Status: Expired due to Term

• Current Assignee: Dial Corporation (Henkel AG & Co KGaA)
• Original Assignee: Gillette Company (The Procter & Gamble Company)
• Inventors: Vu, Tuan M., Iovanni, Carl F., Sane, Jayant N.
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): HOWARD, SHARON LEE
• Application Number:
  US08/695,839
• Time in Patent Office: 545 Days
• Field of Search: 424/65, 424/66, 424/68
• US Class Current: 424/401
• CPC Class Codes: A61K 2800/262 Transparent; Translucent
• CPC Class Codes: A61K 2800/51 Chelating agents
• CPC Class Codes: A61K 2800/5422 nonionic
• CPC Class Codes: A61K 8/0229 Sticks
• CPC Class Codes: A61K 8/042 Gels
• CPC Class Codes: A61K 8/26 Aluminium; Compounds thereof
• CPC Class Codes: A61K 8/28 Zirconium; Compounds thereof
• CPC Class Codes: A61K 8/345 containing more than one hydroxy group
• CPC Class Codes: A61K 8/44 Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
• CPC Class Codes: A61K 8/498 having 6-membered rings or their condensed derivatives, e.g. coumarin
• CPC Class Codes: A61K 8/731 Cellulose; Quaternized cellulose derivatives
• CPC Class Codes: A61Q 15/00 Anti-perspirants or body deodorants deodorisation of air A61L9/00

Abstract

A clear gel cosmetic stick includes a liquid vehicle, a dibenzylidene alditol as a gelling agent, an antiperspirant salt dissolved in the liquid vehicle, and a chelating agent. The cosmetic stick comprises in percent by weight about 40% to about 95% of the liquid vehicle, from about 0.1% to about 5% of the dibenzylidene alditol, from about 0.5% to about 25% of the antiperspirant salt, and from about 0.05% to about 3% of the chelating agent. The cosmetic stick is preferably substantially free of alkaline gelling agent stabilizers such as NaOH and KOH.

Claims

1. A clear gel cosmetic stick comprising a liquid vehicle, a gelling agent comprising dibenzylidene alditol, an antiperspirant salt dissolved in said liquid vehicle, and a chelating agent.

2. The cosmetic stick of claim 1 wherein said liquid vehicle comprises a polyhydric alcohol having from 3 to 6 carbon atoms and from 2 to 6 hydroxyl groups.

3. The cosmetic stick of claim 2 wherein said antiperspirant salt comprises aluminum chlorohydrate or aluminum zirconium chlorohydrate.

4. The cosmetic stick of claim 3 wherein said antiperspirant salt is partially neutralized with alkaline glycinate.

5. The cosmetic stick of claim 3 or 4 wherein said dibenzylidene alditol comprises dibenzylidene sorbitol.

6. The cosmetic stick of claim 5 wherein said chelating agent is selected from the group consisting of tetrasodium ethylenediaminetetraacetate, trisodium ethylenediaminetetraacetate, hydroxyethylethylenediaminetriacetate, diethylenetriaminepentaacetate, nitrilotriacetate, ethanoldiglycine disodium salt, ethylenediaminetetraacetate or trisodium etheylenediaminetetraacetate, diethanolglycine sodium salt, and 1,3-propylenediaminetetraacetic acid.

7. The cosmetic stick of claim 5 wherein said chelating agent is tetrasodium ethylenediaminetetraacetate or trisodium ethylenediaminetetraacetate.

8. The cosmetic stick of claim 7 wherein said polyhydric alcohol comprises propylene glycol.

9. The cosmetic stick of claim 1 wherein said chelating agent is selected from the group consisting of tetrasodium ethylenediaminetetraacetate, trisodium ethylenediaminetetraacetate, hydroxyethylethylenediaminetriacetate, diethylenetriaminepentaacetate, nitrilotriacetate, ethanoldiglycine disodium salt, diethanolglycine sodium salt, and 1,3-propylenediaminetetraacetic acid.

10. The cosmetic stick of claim 1 wherein said chelating agent is tetrasodium ethylenediaminetetraacetate or trisodium ethylenediaminetetraacetate.

11. The cosmetic stick of claim 1 which comprises in percent by weight about 40% to about 95% of said liquid vehicle, from about 0.1% to about 5% of said dibenzylidene alditol, from about 0.5% to about 25% of said antiperspirant salt, and from about 0.05% to about 3% of said chelating agent.

12. The cosmetic stick of claim 1 which comprises in percent by weight about 50% to about 92% of said liquid vehicle, from about 0.5% to about 1.5% of said dibenzylidene alditol, from about 1% to about 22% of said antiperspirant salt, and from about 0.1% to about 2% of said chelating agent.

13. The cosmetic stick of claim 12 which further comprises a hydroxyalkyl cellulose.

14. The cosmetic stick of claim 13 which comprises from about 0.08% to about 1% of hydroxypropyl cellulose by weight.

15. The cosmetic stick of claim 12 wherein said liquid vehicle comprises a polyhydric alcohol having from 3 to 6 carbon atoms and from 2 to 6 hydroxyl groups.

16. The cosmetic stick of claim 15 wherein said antiperspirant salt comprises aluminum chlorohydrate or aluminum zirconium chlorohydrate.

17. The cosmetic stick of claim 16 wherein said antiperspirant salt is partially neutralized with alkaline glycinate.

18. The cosmetic stick of claim 16 or 17 wherein said dibenzylidene alditol comprises dibenzylidene sorbitol.

19. The cosmetic stick of claim 18 wherein said chelating agent is tetrasodium ethylenediaminetetraacetate or trisodium ethylenediaminetatraacetate.

20. The cosmetic stick of claim 19 which comprises from about 0.08% to about 1% of hydroxypropyl cellulose by weight.

21. The cosmetic stick of claim 20 wherein said polyhydric alcohol comprises propylene glycol.

22. The cosmetic stick of claim 17 which has a pH of about 4.8 to about 5.5.

23. The cosmetic stick of claim 22 which is substantially free of sodium hydroxide and potassium hydroxide.

24. The cosmetic stick of claim 23 wherein said chelating agent is tetrasodium ethylenediaminetetraacetate or trisodium ethylenediaminetetraacetate.

25. The cosmetic stick of claim 24 which further comprises from about 0.08% to about 1% of hydroxypropyl cellulose by weight.

26. The cosmetic stick of claim 25 which further comprises from about 0.1% to about 2% of an emollient by weight.

27. The cosmetic stick of claim 26 wherein said cosmetic stick is an antiperspirant that comprises from about 8% to about 22% of said antiperspirant salt by weight.

28. The cosmetic stick of claim 26 wherein said cosmetic stick is a deodorant that comprises from about 1% to about 6% of said antiperspirant salt by weight.

29. The cosmetic stick of claim 1, 24 or 26 wherein said cosmetic stick has a turbidity of less than about 100 NTU.

30. The cosmetic stick of claim 1, 24 or 26 wherein said cosmetic stick is sufficiently clear to enable an observer to read without difficulty lettering of size 0.1 to 0.6 on a visual acuity chart.

31. The cosmetic stick of claim 29 which has a hardness of about 60 to about 150.

32. The cosmetic stick of claim 31 which has a color of 0 to 1 on the yellow scale.

33. The cosmetic stick of claim 32 which is substantially odor free.

34. The cosmetic stick of claim 33 which is stable with respect to clarity, color and odor when stored at 45°

C. for 3 months.

35. A clear gel cosmetic stick comprising in percent by weight about 50% to about 92% of a liquid vehicle comprising a polyhydric alcohol having from 3 to 6 carbon atoms and from 2 to 6 hydroxyl groups, about 0.5% to about 1.5% of dibenzylidene sorbitol, about 1% to about 22% of an antiperspirant salt selected from aluminum chlorohydrate and aluminum zirconium chlorohydrate, said antiperspirant salt being solubilized in said vehicle and partially neutralized with alkaline glycinate, about 0.08% to about 1% of hydroxyalkyl cellulose, and about 0.1% to about 2% of a chelating agent selected from tetrasodium ethylenediaminetetraacetate and trisodium ethylenediaminetetraacetate, wherein said stick has a pH of about 4.8 to about 5.5, a turbidity of less than about 100 NTU, and a hardness of about 60 to about 150.

36. A clear gel antiperspirant stick comprising in percent by weight about 50% to about 92% of a liquid vehicle comprising a polyhydric alcohol having from 3 to 6 carbon atoms and from 2 to 6 hydroxyl groups, said liquid vehicle being substantially free of monohydric alcohol, about 0.5% to about 1.5% of dibenzylidene sorbitol, about 8% to about 22% of an antiperspirant salt, said antiperspirant salt being solubilized in said vehicle, about 0.05% to about 3% of a chelating agent, and about 0.08% to about 1% of hydroxyalkyl cellulose, wherein said stick has a pH greater than 4.4, a turbidity of less than about 100 NTU, and is substantially free of sodium hydroxide and potassium hydroxide.

37. The antiperspirant stick of claim 36 comprising about 0.1% to about 2% of a chelating agent selected from tetrasodium ethylenediaminetetraacetate and trisodium ethylenediaminetetraacetate.