Electrochromic devices and methods

• US 5,724,177 A
• Filed: 05/02/1995
• Issued: 03/03/1998
• Est. Priority Date: 09/04/1991
• Status: Expired due to Term

• Current Assignee: Sage Electrochromics, Inc (Compagnie de Saint-Gobain SA)
• Original Assignee: Sun Active Glass Electrochromics Incorporated
• Inventors: Van Dine, John E., Ellis, Frank B. Jr., Parkhe, V. D.
• Primary Examiner(s): Nelms, David C.
• Assistant Examiner(s): Lester, Evelyn A.
• Application Number:
  US08/434,159
• Time in Patent Office: 1,036 Days
• Field of Search: 359/265, 359/266, 359/273, 359/274, 359/275
• US Class Current: 359/273
• CPC Class Codes: G02F 1/133502 Antiglare, refractive index matching layers
• CPC Class Codes: G02F 1/13439 characterised by their electrical, optical, physical properties; materials therefor; method of making
• CPC Class Codes: G02F 1/1525 characterised by a particular ion transporting layer, e.g. electrolyte
• CPC Class Codes: G02F 1/1533 structural features not otherwise provided for
• CPC Class Codes: G02F 1/157 Structural association of cells with optical devices, e.g. reflectors or illuminating devices
• CPC Class Codes: G02F 2001/1536 additional, e.g. protective, layer inside the cell
• CPC Class Codes: G02F 2202/20 LiNbO3, LiTaO3

Abstract

Electrochromic devices are disclosed which may be used for large surface area applications. The devices utilize optical tuning to minimize optical interference between layers of the structure and to maximize uniform optical transparency. Optical tuning also enables transparent conductive oxide layers to be replaced by thin conductive metal layers, thereby reducing the overall thickness of these devices and facilitating the manufacturing process.

Claims

1. An electrochromic device, comprising

an electrochromic structure including an elelectrochromic mate an electrochromic material, a counterelectrode and transporting means for transporting ions between said electrode and said counterelectrode,

conductive means including at least two electrically conductive layers sandwiching said electrochromic structure for applying an electric potential across said electrochromic structure, at least one of said electrically conductive layers including a layer of an electrically conductive oxide,

a substrate and a superstrate together cooperating to sandwich said electrochromic structure and said electrically conductive layers, and

enhancing means for enhancing the transmission of radiation through said electrically conductive layers, said enhancing means including at least one optically transparent layer including silicon dioxide in surface contact with said substrate and at least one other optically transparent layer including silicon dioxide in surface contact with said superstrate.

2. The electrochromic device as claimed in claim 1, wherein said at least one optically transparent layer is interposed between said substrate and said one of said electrically conductive layers, and said at least one other optically transparent layer is interposed between said superstrate and another of said electrically conductive layers.

3. The electrochromic device as claimed in claim 1, wherein said one of said electrically conductive layers between said electrochromic structure and said substrate includes a transparent oxide and said at least one optically transparent layer is interposed between said substrate and said one of said electrically conductive layers in surface contact with said transparent oxide.

4. An electrochromic combination, comprising

a substrate, and

an electrochromic device arranged on said substrate, said electrochromic device including an electrochromic structure having an electrode formed from an electrochromic material, a counterelectrode, lithium ions and transporting means for transporting said lithium ions between said electrode and said counterelectrode, conductive means including at least two electrically conductive layers sandwiching said electrochromic structure for applying an electric potential across said electrochromic structure, at least one of said electrically conductive layers between said electrochromic structure and said substrate including a transparent conductive oxide and excluding a metal layer, and enhancing means for enhancing the transmission of radiation through said at least one of said electrically conductive layers, said enhancing means including at least one optically transparent layer in surface contact with said substrate.

5. The electrochromic combination as claimed in claim 4, wherein said at least one optically transparent layer is interposed between said substrate and said at least one of said electrically conductive layers.

14. The electrochromic combination as claimed in claim 4, further comprising a superstrate cooperating with said substrate to sandwich said electrochromic device.

6. An electrochromic combination, comprising

a substrate,

an electrochromic device arranged on said substrate, said electrochromic device including an electrochromic structure having an electrode formed from an electrochromic material, a counterelectrode and transporting means for transporting ions between said electrode and said counterelectrode, conductive means including at least two electrically conductive layers sandwiching said electrochromic structure for applying an electric potential across said electrochromic structure, at least one of said electrically conductive layers between said electrochromic structure and said substrate including a transparent conductive oxide and excluding a metal layer, and enhancing means for enhancing the transmission of radiation through said at least one of said electrically conductive layers, said enhancing means including at least one optically transparent layer including silicon dioxide in surface contact with said substrate, and

a superstrate cooperating with said substrate to sandwich said electrochromic device.

7. An electrochromic combination, comprising

a substrate, and

an electrochromic device arranged on said substrate, said electrochromic device including an electrochromic structure having an electrode formed from an electrochromic material, a counterelectrode, lithium ions and transporting means for transporting said lithium ions between said electrode and said counterelectrode, conductive means including at least two electrically conductive layers sandwiching said electrochromic structure for applying an electric potential across said electrochromic structure, and enhancing means for enhancing the transmission of radiation through said electrically conductive layers, said enhancing means including at least two optically transparent layers sandwiching said electrochromic structure and said electrically conductive layers, one of said optically transparent layers being in surface contact with said substrate.

8. The electrochromic combination as claimed in claim 7, wherein said at least two optically transparent layers have an index of refraction greater than about 1.5.

9. The electrochromic combination as claimed in claim 7, wherein said one of said optically transparent layers is interposed between said substrate and said one of said electrically conductive layers.

15. The electrochromic combination as claimed in claim 7, further comprising a superstrate cooperating with said substrate to sandwich said electrochromic device.

10. An electrochromic combination, comprising

a substrate,

an electrochromic device arranged on said substrate, said electrochromic device including an electrochromic structure having an electrode formed from an electrochromic material, a counterelectrode and transporting means for transporting ions between said electrode and said counterelectrode, conductive means including at least two electrically conductive layers sandwiching said electrochromic structure for applying an electric potential across said electrochromic structure, and enhancing means for enhancing the transmission of radiation through said electrically conductive layers, said enhancing means including at least two optically transparent layers sandwiching said electrochromic structure and said electrically conductive layers, one of said optically transparent layers being in surface contact with said substrate, at least one of said optically transparent layers including silicon dioxide, and

a superstrate cooperating with said substrate to sandwich said electrochromic device.

11. The electrochromic combination as claimed in claim 10, wherein said one of said optically transparent layers is interposed between said substrate and said one of said electrically conductive layers, and another one of said optically transparent layers is interposed between said superstrate and another of said electrically conductive layers.

12. An electrochromic combination, comprising

a substrate, and

an electrochromic device arranged on said substrate, said electrochromic device including an electrochromic structure having an electrode formed from an electrochromic material, a counterelectrode, lithium ions and transporting means for transporting said lithium ions between said electrode and said counterelectrode, conductive means including at least two electrically conductive layers sandwiching said electrochromic structure for applying an electric potential across said electrochromic structure, at least one of said electrically conductive layers between said electrochromic structure and said substrate including a transparent oxide, and enhancing means for enhancing the transmission of radiation through said at least one of said electrically conductive layers, said enhancing means including at least one optically transparent layer interposed between said substrate and said at least one of said electrically conductive layers in surface contact with said transparent oxide.

16. The electrochromic combination as claimed in claim 12, further comprising a superstrate cooperating with said substrate to sandwich said electrochromic device.

13. An electrochromic combination, comprising

a substrate,

an electrochromic device arranged on said substrate, said electrochromic device including an electrochromic structure having an electrode formed from an electrochromic material, a counterelectrode and transporting means for transporting ions between said electrode and said counterelectrode, conductive means including at least two electrically conductive layers sandwiching said electrochromic structure for applying an electric potential across said electrochromic structure, at least one of said electrically conductive layers between said electrochromic structure and said substrate including a transparent oxide, and enhancing means for enhancing the transmission of radiation through said at least one of said electrically conductive layers, said enhancing means including at least one optically transparent layer including silicon dioxide interposed between said substrate and said at least one of said electrically conductive layers in surface contact with said transparent oxide, and

a superstrate cooperating with said substrate to sandwich said electrochromic device.

17. An electrochromic combination, comprising

a substrate, and

an electrochromic device arranged on said substrate, said electrochromic device including an electrochromic structure having an electrode formed from an electrochromic material, a counterelectrode and transporting means consisting of only a single layer for transporting ions between said electrode and said counterelectrode, conductive means including at least two electrically conductive layers sandwiching said electrochromic structure for applying an electric potential across said electrochromic structure, at least one of said electrically conductive layers between said electrochromic structure and said substrate including a transparent conductive oxide and excluding a metal layer, and enhancing means for enhancing the transmission of radiation through said at least one of said electrically conductive layers, said enhancing means including at least one optically transparent layer including silicon dioxide in surface contact with said substrate.

18. An electrochromic combination, comprising

a substrate, and

an electrochromic device arranged on said substrate, said electrochromic device including an electrochromic structure having an electrode formed from an electrochromic material, a counterelectrode and transporting means consisting of only a single layer for transporting ions between said electrode and said counterelectrode, conductive means including at least two electrically conductive layers sandwiching said electrochromic structure for applying an electric potential across said electrochromic structure, and enhancing means for enhancing the transmission of radiation through said electrically conductive layers, said enhancing means including at least two optically transparent layers sandwiching said electrochromic structure and said electrically conductive layers, one of said optically transparent layers being in surface contact with said substrate, at least one of said optically transparent layers including silicon dioxide.

19. An electrochromic combination, comprising

a substrate, and

an electrochromic device arranged on said substrate, said electrochromic device including an electrochromic structure having an electrode formed from an electrochromic material, a counterelectrode and transporting means consisting of only a single layer for transporting ions between said electrode and said counterelectrode, conductive means including at least two electrically conductive layers sandwiching said electrochromic structure for applying an electric potential across said electrochromic structure, at least one of said electrically conductive layers between said electrochromic structure and said substrate including a transparent oxide, and enhancing means for enhancing the transmission of radiation through said at least one of said electrically conductive layers, said enhancing means including at least one optically transparent layer including silicon dioxide interposed between said substrate and said at least one of said electrically conductive layers in surface contact with said transparent oxide.