Low silicone hair conditioning shampoo and non-silicone hair conditioning/style control shampoo

• US 5,726,137 A
• Filed: 09/27/1996
• Issued: 03/10/1998
• Est. Priority Date: 06/21/1989
• Status: Expired due to Fees

• Current Assignee: Colgate-Palmolive Company
• Original Assignee: Colgate-Palmolive Company
• Inventors: Robbins, Clarence R., Patel, Amrit
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): Delcotto, Gregory R.
• Application Number:
  US08/714,928
• Time in Patent Office: 529 Days
• Field of Search: 510/122, 510/124, 510/125, 510/127, 510/137, 510/158, 510/159, 424/70.11, 424/70.12, 424/70.21, 424/70.24, 424/70.27, 514/881
• US Class Current: 510/122
• CPC Class Codes: A61K 2800/596 Mixtures of surface active compounds
• CPC Class Codes: A61K 8/31 Hydrocarbons
• CPC Class Codes: A61K 8/342 Alcohols having more than seven atoms in an unbroken chain
• CPC Class Codes: A61K 8/39 Derivatives containing from 2 to 10 oxyalkylene groups
• CPC Class Codes: A61K 8/416 Quaternary ammonium compounds A61K8/35 takes precedence
• CPC Class Codes: A61K 8/44 Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
• CPC Class Codes: A61K 8/463 containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
• CPC Class Codes: A61K 8/73 Polysaccharides
• CPC Class Codes: A61K 8/731 Cellulose; Quaternized cellulose derivatives
• CPC Class Codes: A61K 8/817 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
• CPC Class Codes: A61K 8/891 saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
• CPC Class Codes: A61Q 19/10 Washing or bathing preparations
• CPC Class Codes: A61Q 5/02 Preparations for cleaning the hair
• CPC Class Codes: A61Q 5/06 Preparations for styling the hair, e.g. by temporary shaping or colouring
• CPC Class Codes: A61Q 5/12 Preparations containing hair conditioners
• CPC Class Codes: C11D 3/0089 Pearlescent compositions; Opacifying agents

Abstract

A mild, non-irriatating hair conditioning shampoo is disclosed comprising an aqueous dispersion of a water-insoluble lipid phase, an anionic hair cleansing surfactant, an amphoteric surfactant present at a level of at least about 0.75 parts by weight per part by weight of said anionic surfactant, at least one hair conditioning, film forming, polycationic polymer soluble in the aqueous dispersion and 0-6% by weight, based on the weight of the shampoo, of a water-insoluble, non-volatile hair conditioning silicone, the water-insoluble lipid phase comprising at least one lipid soluble, emulsifiable, monocationic, quaternary ammonium compound or amine solubilized in a water-insoluble long chain lipid compound, the weight ratio of monocationic compound to the lipid compound in the lipid phase being in the range of from about 5:1 to about 1:10 and the molar ratio of anionic surfactant to water-insoluble cationic compound is greater than 2:1. The shampoo having no silicone possesses a high degree of style control properties. The shampoo containing silicone has a high degree of hair conditioning properties.

Claims

1. A hair conditioning shampoo composition comprising, by weight, an aqueous dispersion of:

a) about 1% to about 16% of a water-insoluble lipid phase comprising a long chain aliphatic alcohol having an average of from about 24 to about 50 carbon atoms and from 0 to about 40 ethoxy units;

b) at least about 0.7% of a water-insoluble, monocationic conditioner compound dissolved in said lipid phase, said monocationic compound being selected from the group consisting of an alkyl amine having a pKa of at least 7.5 selected from the group consisting of distearylamine, distearyl methylamine, behenylamine, behenylmethylamine, behenyldimethylamine, dicetylamine, dicetylmethylamine and tricetylamine;

c) about 3% to about 25% of a water-soluble, anionic, hair cleansing organic surfactant;

d) an amphoteric betaine or sulfobetaine surfactant containing a C₈ -C₁₈ alkyl or C₈ -C₁₈ alkanolamido C₂ -C₃ alkylene group in its molecular structure, present in said dispersion at a level of at least 0.75 to 1.25 parts by weight per one part by weight of said anionic surfactant;

e) from 0 to about 6% of a water-insoluble, non-volatile silicone hair conditioning agent; and

f) 0.2% to 3% of at least one hair conditioning, water-soluble, film-forming polycationic polymer;

the weight ratio of said monocationic conditioner compound to said lipid compound in said lipid phase being in the range of from about 5;

1 to about 1;

10 and the molar ratio of anionic surfactant to water-insoluble, monocationic compound being in the range of 2;

1 to 50;

1.

2. The shampoo according to claim 1 containing no silicone hair conditioning agent and possessing a high degree of hair conditioning and hair damage repair properties.

3. The shampoo according to claim 1 containing from about 0.2 to about 6% by weight, based on the weight of the shampoo, of said silicone and possessing a high degree of style control properties.

4. The shampoo of claim 1 wherein said anionic surfactant is an alkyl sulfate, alkyl ether sulfate, alkyl ether sulfonate, sulfate ester of an alkylphenoxy polyoxyethylene ethanol, alpha-olefin sulfonate, beta-alkoxy alkene sulfonate, alkyl arylsulfonate, sulfated monoglyceride, fatty acid amino polyoxyethylene sulfate or a combination thereof.

5. The shampoo of claim 1 wherein said anionic surfactant is ammonium lauryl sulfate.

6. The shampoo of claim 1 wherein said anionic surfactant is sodium decethsulfate.

7. The shampoo of claim 1 wherein said anionic surfactant is a mixture of ammonium lauryl sulfate and sodiumdecethsulfate.

8. The shampoo of claim 1 wherein said anionic surfactant is sodium laurethsulfate.

9. The shampoo of claim 1 wherein said lipid phase is said long chain aliphatic alcohol having an average of from about 24 to about 50 carbon atoms.

10. The shampoo of claim 1 wherein said hair conditioning monocatronic compound comprises from about 0.7% to about 3% by weight of said shampoo.

11. The shampoo of claim 4 wherein said amphoteric surfactant is cocoamidopropyl betaine.

12. The shampoo of claim 1 additionally containing a hydrotrope selected from the group consisting of sodium cumene sulfonate, sodium xylene sulfonate, sodium benzene sulfonate and sodium hexyl sulfate.

13. The shampoo of claim 1 wherein said water soluble cationic polymer comprises a salt of hydroxyethyl cellulose reacted with a trimethyl ammonium substituted epoxide.

14. The shampoo of claim 1 wherein said water soluble cationic polymer comprises a copolymer of acrylamide and dimethyldiallylammonium chloride.

15. The shampoo of claim 2 wherein said anionic surfactant is selected from the group consisting of a C₈ -C₁₈ alkyl sulfate, a C₈ -C₁₈ alkyl ether ethenoxy sulfate containing 1-12 ethenoxy groups and mixtures thereof and is present in an amount of 7% to 14% by weight:

said amphoteric surfactant is said betaine; and

said water-insoluble lipid phase is present in an amount of 4% to 10% by weight.

16. The shampoo of claim 15 wherein said polycationic polymer is selected from the group consisting of a salt of hydroxyethyl cellulose reacted with a trimethyl ammonium substituted epoxide, a copolymer of acrylamide and dimethyldiallylammonium chloride and mixtures thereof.

17. The shampoo of claim 16 wherein said lipid phase comprises a mixture of said long chain alcohol and isostearyl alcohol ethoxylate.

18. The shampoo of claim 1 wherein said lipid phase includes an ethoxylated isostearyl alcohol.