Reduction of haze in transparent coatings

• US 5,744,215 A
• Filed: 01/04/1996
• Issued: 04/28/1998
• Est. Priority Date: 01/04/1996
• Status: Expired due to Term

• Current Assignee: Vitro Flat Glass LLC (Compagnie De Saint-Gobain)
• Original Assignee: PPG Industries Incorporated (Nouryon BV)
• Inventors: Neuman, George A.
• Primary Examiner(s): WATKINS III, WILLIAM P
• Application Number:
  US08/582,795
• Time in Patent Office: 845 Days
• Field of Search: 428/156, 428/141, 428/172, 428/432, 428/702, 428/701, 428/913, 428/161, 428/173, 427/126.3, 427/109, 427/167, 427/166, 427/255.3
• US Class Current: 428/141
• CPC Class Codes: C03C 17/00 Surface treatment of glass, not in the form of fibres or filaments, by coating optical coatings of optical elements G02B1/10
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 2217/24 Doped oxides
• CPC Class Codes: C03C 2217/241 with halides
• CPC Class Codes: C03C 2217/94 Transparent conductive oxide layers [TCO] being part of a multilayer coating
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10T 428/24355 Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
• CPC Class Codes: Y10T 428/24479 including variation in thickness
• CPC Class Codes: Y10T 428/24521 with component conforming to contour of nonplanar surface
• CPC Class Codes: Y10T 428/24612 Composite web or sheet
• CPC Class Codes: Y10T 428/2462 with partial filling of valleys on outer surface

Abstract

Surface haze resulting from a rough surface of a substrate e.g. a fluorine doped tin oxide coated glass piece is reduced by coating the rough surface with a smooth surface coating of sufficient thickness to smooth out the rough surface e.g. coating the tin oxide layer with a silica film having a thickness of about 100 to 2000 Angstroms.

Claims

1. An article having reduced surface haze comprising:

a substrate having a coating layer over a major surface of the substrate, the coating layer having a major surface facing away from the substrate defined as a first major surface and an opposite major surface facing the substrate, the first major surface having valleys and peaks wherein light beams incident on the first major surface are reflected from the first major surface as first surface reflected light beams whereby the first major surface of the coating layer has a level of surface haze, and

a haze reducing film deposited on the first major surface of the coating layer wherein the haze reducing film is a crystalline coating film deposited by a technique selected from the group consisting of pyrolytic coating and sputter coating, the haze reducing film while being deposited on the first major surface contacts the first major surface filling in the valleys of the first major surface, the film as deposited has a major surface facing away from the first major surface of the coating layer defined as a second major surface, the second major surface having valleys and peaks with the distance between the valleys and peaks of the second major surface being less than the distance between the valleys and peaks of the surface of the first major surface wherein the light beams incident on the second major surface are reflected from the second major surface as second surface reflected light beams wherein the second surface reflected light beams are less diffused than the first surface reflected light beams such that the level of surface haze of the second major surface is less than the level of surface haze of the first major surface to provide the article having reduced surface haze.

2. The article according to claim 1 wherein the substrate is a glass piece and the light beams incident on the first major surface pass through the substrate and exit as first surface transmitted light beams and the light beams incident on the second major surface pass through the article as second surface transmitted light beams wherein the second surface transmitted light beams are less diffuse than the first surface transmitted light beams.

3. The article according to claim 1 wherein the haze reducing film has a thickness of about 1 to 3 times the distance between the average depth of the valleys and the average height of the peaks of the first major surface.

4. The article according to claim 1 wherein the haze reducing film has a thickness of about 3 to 10 times the distance between the average depth of the valleys and the average height of the peaks of the first major surface.

5. The article according to claim 1 wherein the coating layer is a polycrystalline coating layer.

6. The article according to claim 1 wherein the coating layer is a crystalline coating layer.

7. The article according to claim 2 wherein the coating layer is a tin oxide coating.

8. The article according to claim 1 wherein index of refraction of the haze reducing film is approximately equal to the index of refraction of the coating layer.

17. The coated article according to claim 2 wherein the haze reducing film is a mixed oxide.

18. The coated article according to claim 17 wherein the mixed oxide is tin oxide and silicon oxide.

19. The article according to claim 1 wherein the value of emissivity of the substrate is similar to value of the emissivity of the article.

20. The article according to claim 1 wherein the coating layer includes a film of silica on the substrate and a film of tin oxide on the film of silica.

9. An article having reduced surface haze comprising:

a substrate having a coating layer over a major surface of the substrate, the coating layer having a major surface facing away from the substrate defined as a first major surface and an opposite major surface facing the substrate, the first major surface having valleys and peaks wherein light beams incident on the first major surface are reflected from the first major surface as first surface reflected light beams whereby the first major surface of the coating layer has a level of surface haze, and

a haze reducing film deposited on the first major surface of the coating layer by a technique selected from the group consisting of pyrolytic coating and sputter coating wherein index of refraction of the haze reducing film is different than the index of refraction of the coating layer, the haze reducing film while being deposited on the first major surface contacts the first major surface filling in the valleys of the first major surface, the film as deposited has a major surface facing away from the first major surface of the coating layer defined as a second major surface, the second major surface having valleys and peaks with the distance between the valleys and peaks of the second major surface being less than the distance between the valleys and peaks of the surface of the first major surface wherein the light beams incident on the second major surface are reflected from the second major surface as second surface reflected light beams wherein the second surface reflected light beams are less diffused than the first surface reflected light beams such that the level of surface haze of the second major surface is less than the level of surface haze of the first major surface to provide the article having reduced surface haze.

10. The article according to claim 9 wherein the haze reducing film is a silica film.

11. The article according to claim 10 wherein the coating layer is tin oxide.

12. The article according to claim 11 wherein the tin oxide layer is a fluorine doped tin oxide layer.

13. The article according to claim 12 wherein the coating layer has a thickness between 500 to 10,000 Angstroms.

14. The article according to claim 12 wherein the tin oxide is pyrolytically deposited and the distance between the average depth of the valleys and the average height of the peaks is equal to about 5 to 25 percent of the tin oxide layer thickness.

15. The article according to claim 14 wherein the thickness of the tin oxide coating layer is in the range of about 1,000 to 5,000 Angstroms.

16. The coated article according to claim 10 wherein the thickness of the silica film is in the range of about 100 to 2000 Angstroms.

21. The article according to claim 9 wherein the haze reducing film is a crystalline layer.