UV curable pressure sensitive adhesive composition

• US 5,747,551 A
• Filed: 08/22/1996
• Issued: 05/05/1998
• Est. Priority Date: 12/05/1994
• Status: Expired due to Term

• Current Assignee: Acheson Industries, Inc. (Nouryon BV)
• Original Assignee: Acheson Industries, Inc. (Nouryon BV)
• Inventors: Chasser, Anthony M., Lewandowski, Mark A.
• Primary Examiner(s): Berman, Susan W.
• Application Number:
  US08/704,377
• Time in Patent Office: 621 Days
• Field of Search: 522/95, 522/96, 522/98, 522/79
• US Class Current: 522/95
• CPC Class Codes: C08F 220/10 Esters
• CPC Class Codes: C08F 290/147 Polyurethanes; Polyureas
• CPC Class Codes: C08G 2170/40 Compositions for pressure-sensitive adhesives
• CPC Class Codes: C08L 2666/08 Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof
• CPC Class Codes: C09J 175/16 having terminal carbon-to-carbon unsaturated bonds
• CPC Class Codes: C09J 4/00 Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
• CPC Class Codes: C09J 4/06 Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00

Abstract

A new UV curable pressure sensitive adhesive composition, which comprises in weight percent: about 0.1% to about 15% of a photoinitiator agent, about 10% to about 80% of a polyurethane resin with a pendent acrylate functionality, zero to about 70% by of an acrylate monomer, about 0.1% to about 25% by weight of a an acrylated polybutadiene component, and zero to about 50% by weight of a tackifier agent.

Claims

1. A method comprising the steps of:

applying a UV curable pressure sensitive adhesive composition, comprising in weight percent;

(a) about 0.5% to about 10% photoinitiator agent,

(b) about 20% to about 50% of a polyurethane resin with a pendent acrylate functionality, and having a molecular weight (M_N) within the range of about 500 to about 2.000.000,

(c) about 10% to about 55% of an acrylate monomer, having a molecular weight within the range of about 50 to about 5.000,

(d) about 1/2% to about 10% of acrylated polybutadiene material having a molecular weight (M_N) within the range of about 4000 to about 6000, and

(e) about 0.1% to about 35% of a tackifier agent, to a substrate surface,

subjecting said adhesive composition to ultraviolet radiation,

positioning an object in contact with said adhesive composition to adhere said object in position on said substrate surface.

2. The method of claim 1 wherein,

said polyurethane resin has a molecular weight (M_N) within the range of about 1,000 to about 500,000,

said acrylate monomer has a molecular weight within the range of about 100 to about 2,000.

3. The method of claim 2 wherein,

(a) said photoinitiator agent is present from about 1.0% to about 6%,

(b) said polyurethane resin is present from about 20% to about 45%,

(c) said acrylate monomer is present from about 15% to about 50%,

(d) said polybutadiene material is present from about 1% to about 5%,

(e) said tackifier agent is present from about 5% to about 25%.

4. The method of claim 3 wherein,

said polyurethane resin has a molecular weight (M_N) within the range of about 2,000 to about 30,000,

said acrylate monomer has a molecular weight within the range of about 120 to about 500.

5. The method of claim 2 wherein,

said photoinitiator agent is a free radical photoinitiator type,

said acrylate monomer is selected from at least one member of the group consisting of a methacrylate monomer, an ethyl acrylate monomer, an isobornyl acrylate monomer, a cyclohexyl acrylate monomer, a butyl acrylate monomer, a propyl acrylate monomer, a pentyl acrylate monomer, a hexyl acrylate monomer, and a glycidyl acrylate monomer.

6. The method of claim 5 wherein,

there is also included a minor amount of optional additive materials such as pigments, rheology modifiers, flow aids, antioxidants, or a bubble release agent.

7. The method of claim 5 wherein,

there is also included a minor amount of optional additive materials such as pigments, rheology modifiers, flow aids, antioxidants, or a bubble release agent, and

said tackifier agent is selected from at least one member of the group consisting of rosins, rosin esters, tall oil rosins, and pentaerythritol ester.