Switchable cholesteric filter and luminaire having such a filter

• US 5,762,823 A
• Filed: 06/14/1996
• Issued: 06/09/1998
• Est. Priority Date: 09/08/1993
• Status: Expired due to Fees

• Current Assignee: US Philips Corporation (Koninklijke Philips N.V.)
• Original Assignee: US Philips Corporation (Koninklijke Philips N.V.)
• Inventors: Hikmet, Rifat A. M.
• Primary Examiner(s): KELLY, CYNTHIA HARRIS
• Application Number:
  US08/668,428
• Time in Patent Office: 725 Days
• Field of Search: 252/299.01, 349/13
• US Class Current: 252/299.01
• CPC Class Codes: C09K 19/38 Polymers
• CPC Class Codes: C09K 19/542 Macromolecular compounds
• CPC Class Codes: F21V 9/14 for producing polarised light
• CPC Class Codes: G02F 1/0063 Optical properties, e.g. absorption, reflection or birefringence materials for non-linear optics G02F1/355
• CPC Class Codes: G02F 1/13345 Network or three-dimensional gels
• CPC Class Codes: G02F 1/13718 based on a change of the texture state of a cholesteric liquid crystal

Abstract

The invention relates to a switchable cholesteric filter. Said filter comprises an optically active layer which is situated between two substrates which are both provided with an electrode for applying an electric field. The optically active layer comprises a liquid-crystalline material which is in the cholesteric phase. In accordance with the invention, the optically active layer comprises a three-dimensional polymer network which consists of the polymerization product of maximally 2 wt. % of monomers with at least two polymerizable groups and maximally 30 wt. % of liquid-crystalline monomers with one polymerizable group, and the rest of the optically active layer consists predominantly of a mixture of chiral and achiral liquid-crystalline molecules. An optically active layer of this composition can be switched in a simple and reproducible manner by means of an electric field. The invention also relates to a luminaire comprising such a switchable cholesteric filter.

Claims

1. A switchable cholesteric filter, which can be switched between a stable colored state and a non-stable transparent state, comprising an optically active layer which is situated between two substrates which are both provided with an electrode layer for applying an electric field, said optically active layer containing a liquid crystalline material which is in the cholesteric phase and which comprises a three-dimensional polymer network which consists of the polymerisation product of maximally 2 wt. % of monomers comprising at least two polymerisable groups and maximally 30 wt. % of liquid crystalline monomers comprising one polymerisable group, the rest of the optically active layer consisting predominantly of a mixture of at least one chiral and achiral liquid crystalline molecules, said network being dissolved in said mixture of liquid crystalline molecules.

2. A switchable cholesteric filter as claimed in claim 1, characterized in that the monomers with at least two polymerizable groups also comprise a liquid-crystalline group.

3. A switchable cholesteric filter as claimed in claim 1, characterized in that (meth)acrylate groups are used as the polymerizable groups of the monomers.

4. In a luminaire comprising a connection for a light source, a cholesteric filter, and means for switching the cholesteric filter, characterized in that said cholesteric filter is a switchable cholesteric filter as claimed in claim 1.

5. A switchable cholesteric filter as claimed in claim 1, characterized in that the optically active layer has a quantity of approximately 0.1-1 wt. % of said monomers with at least two polymerizable groups.

6. A switchable cholesteric filter as claimed in claim 1, characterized in that the optically active layer has a quantity of approximately 15-25 wt. % of said monomers with one polymerizable group.

7. A luminaire as claimed in claim 4, further comprising a light source and reflecting means for reflecting light through the switchable cholesteric filter.