Production of high purity water using reverse osmosis

• US 5,766,479 A
• Filed: 08/07/1995
• Issued: 06/16/1998
• Est. Priority Date: 08/07/1995
• Status: Expired due to Fees

• Current Assignee: Zenon Environmental Incorporated
• Original Assignee: Zenon Environmental Incorporated
• Inventors: Collentro, William V., Collentro, Andrew W.
• Primary Examiner(s): Drodge, Joseph W.
• Application Number:
  US08/512,109
• Time in Patent Office: 1,044 Days
• Field of Search: 210/634, 210/641, 210/651, 210/652, 210/259, 210/195.2, 210/638, 210/806, 210/900
• US Class Current: 210/639
• CPC Class Codes: B01D 2311/04 Specific process operations in the feed stream; Feed pretreatment
• CPC Class Codes: B01D 2311/18 pH control
• CPC Class Codes: B01D 2311/2649 Filtration
• CPC Class Codes: B01D 2317/025 Permeate series
• CPC Class Codes: B01D 61/026 comprising multiple reverse osmosis steps
• CPC Class Codes: B01D 61/029 Multistep processes comprising different kinds of membrane processes selected from reverse osmosis, hyperfiltration or nanofiltration
• CPC Class Codes: B01D 61/04 Feed pretreatment
• CPC Class Codes: C02F 1/441 by reverse osmosis
• CPC Class Codes: C02F 1/442 by nanofiltration
• CPC Class Codes: Y10S 210/90 Ultra pure water, e.g. conductivity water

Abstract

A process for purifying water by removing dissolved materials therefrom, the process capable of producing purified water having a resistivity in the range of 2 to 10 megohm-cm. The process comprises providing a water feed stream to be purified and adjusting the pH of the water feed stream to a basic water solution to drive the equilibrium of a first weakly ionized material to become ionized in the basic solution. The basic water solution is introduced to a high pressure side of a first reverse osmosis membrane module and water is passed through the first reverse osmosis membrane to provide a first retentate having ions therein from the first weakly ionized material concentrated therein and a first permeate depleted in ions from the first weakly ionized material. The pH of the first permeate is adjusted to an acidic water solution to drive the equilibrium of a second weakly ionized material to become ionized in an acidic solution. The acidic water solution is transferred to the high pressure side of a second reverse osmosis membrane and the acidic water solution is purified by passing at least a portion thereof through the second reverse osmosis membrane to provide a second retentate containing ions of the second weakly ionized material ionized in the acidic solution and provide a second permeate depleted in the ions from the second weakly ionized material, the second permeate having a resistivity in the range of 1 to greater than 10 megohm-cm.

Claims

1. A process for purifying water by removing dissolved materials therefrom, the process capable of producing purified water having a resistivity in the range of 4 to 10 megohm-cm or greater, comprising the steps of:

(a) providing a water feed stream to be purified;

(b) adjusting the pH of the water feed stream to a basic water solution having a pH in the range of 7.5 to 10.5 in order for a first weakly ionized material comprised of carbon dioxide to become ionized in a basic solution;

(c) introducing said basic water solution to a high pressure side of a first reverse osmosis membrane;

(d) passing water through said first reverse osmosis membrane to provide a first retentate having ions therein from said first weakly ionized material concentrated therein and a first permeate depleted of ions from said first weakly ionized material;

(e) adjusting the pH of said first permeate to an acidic water solution in order for a second weakly ionized material comprised of ammonia to become ionized in an acidic solution;

(f) transferring said acidic water solution to the high pressure side of a second reverse osmosis membrane; and

(h) further purifying said acidic water solution by passing at least a portion thereof through said second reverse osmosis membrane to provide a second retentate containing ions of said second weakly ionized material ionized in said acidic solution and a second permeate, the second permeate having high resistivity.

2. The process in accordance with claim 1 including adjusting the pH of the first permeate to a pH in the range of 5 to 7.

3. The process in accordance with claim 1 including adjusting the pH of the first permeate to a pH in the range of 5.5 to 6.5.

4. The process in accordance with claim 1 including adjusting the pH of the water feed stream by adding a hydroxide material.

5. The process in accordance with claim 1 including subjecting said water feed stream to a nanofiltration step prior to adjusting the pH of said water feed stream.

6. The process in accordance with claim 1 including adding sulfuric acid to said first permeate for purposes of adjusting said pH to provide said acidic solution.

7. The process in accordance with claim 1 including the step of adding said first permeate to the high pressure side of a hydrophobic membrane to provide a carbon dioxide and/or ammonia depleted retentate.

8. The process in accordance with claim 7 including adjusting the pH of said first permeate to an acidic condition prior to the step of adding said first permeate to the high pressure side of said hydrophobic membrane.

9. The process in accordance with claim 1 wherein said basic water solution has a pH in the range of 8 to 9.5.

10. A process for purifying water by removing dissolved materials therefrom, the process capable of producing purified water having a resistivity in the range of 4 to 10 megohm-cm or greater, comprising the steps of:

(a) providing a water feed stream to be purified;

(b) adjusting the pH of the water feed stream to a basic water solution in order for a first weakly ionized material comprised of carbon dioxide to become ionized in a basic solution;

(c) introducing said basic water solution to a high pressure side of a first reverse osmosis membrane;

(d) passing water through said first reverse osmosis membrane to provide a first retentate having ions therein from said first weakly ionized material concentrated therein and a first permeate depleted of ions from said first weakly ionized material;

(e) adjusting the pH of said first permeate to an acidic water solution having a pH in the range of 5 to 7 in order for a second weakly ionized material comprised of ammonia to become ionized in an acidic solution;

(f) transferring said acidic water solution to the high pressure side of a second reverse osmosis membrane; and

(h) further purifying said acidic water solution by passing at least a portion thereof through said second reverse osmosis membrane to provide a second retentate containing ions of said second weakly ionized material ionized in said acidic solution and a second permeate, the second permeate having high resistivity.

11. The process in accordance with claim 10 wherein the pH of the acidic water solution is 5.5 to 6.5.

12. A process for purifying water by removing dissolved materials therefrom, the process capable of producing purified water having a resistivity in the range of 4 to 10 megohm-cm or greater, comprising the steps of:

(a) providing a water feed stream to be purified;

(b) adjusting the pH of the water feed stream to a basic water solution having a pH in the range of 8 to 9.5 in order for a first weakly ionized material comprised of carbon dioxide to become ionized in a basic solution;

(c) introducing said basic water solution to a high pressure side of a first reverse osmosis membrane;

(d) passing water through said first reverse osmosis membrane to provide a first retentate having ions therein from said first weakly ionized material concentrated therein and a first permeate depleted of ions from said first weakly ionized material;

(e) adjusting the pH of said first permeate to an acidic water solution having a pH in the range of 5.0 to 7 in order for a second weakly ionized material comprised of ammonia to become ionized in an acidic solution;

(f) transferring said acidic water solution to the high pressure side of a second reverse osmosis membrane; and

(h) further purifying said acidic water solution by passing at least a portion thereof through said second reverse osmosis membrane to provide a second retentate containing ions of said second weakly ionized material ionized in said acidic solution and a second permeate, the second permeate having high resistivity.

13. In a process for purifying a water feed stream by removing dissolved materials therefrom, including weakly ionized material using reverse osmosis membranes, the process capable of producing purified water having a resistivity in the range of 4 to 10 megohm-cm, the improvement wherein:

(a) the water feed stream is provided as a basic water solution in order for a first weakly ionized material comprised of carbon dioxide to become ionized in a basic solution;

(b) introducing said basic water solution to a high pressure side of a first reverse osmosis membrane;

(c) passing water through said first reverse osmosis membrane to provide a first retentate having ions therein from said first weakly ionized material concentrated therein and a first permeate depleted of ions from said first weakly ionized material;

(d) adjusting the pH of said first permeate to an acidic water solution in order for a second weakly ionized material comprised of ammonia to become ionized in an acidic solution;

(e) transferring said acidic water solution to the high pressure side of a second reverse osmosis membrane; and

(f) further purifying said acidic water solution by passing at least a portion thereof through said second reverse osmosis membrane to provide a second retentate containing ions of said second weakly ionized material ionized in said acidic solution and a second permeate, the second permeate having high resistivity.

14. The process in accordance with claim 13 including adjusting the pH of the water feed stream to a pH in the range of 7.5 to 10.5.

15. The process in accordance with claim 13 including adjusting the pH of the water feed stream to a pH in the range of 8 to 9.5.

16. The process in accordance with claim 13 including adjusting the pH of the first permeate to a pH in the range of 5 to 7.

17. The process in accordance with claim 13 including adjusting the pH of the first permeate to a pH in the range of 5.5 to 6.5.

18. In a process for purifing a water feed stream by removing dissolved materials therefrom, including weakly ionized material using reverse osmosis membranes, the process capable of producing purified water having a resistivity in the range of 4 to 10 megohm-cm, the improvement wherein:

(a) the water feed stream is provided as a basic water solution in the range of 8 to 9.5 in order for a first weakly ionized material comprised of carbon dioxide to become ionized in a basic solution;

(b) introducing said basic water solution to a high pressure side of a first reverse osmosis membrane;

(c) passing water through said first reverse osmosis membrane to provide a first retentate having ions therein from said first weakly ionized material concentrated therein and a first permeate depleted of ions from said first weakly ionized material;

(d) adjusting the pH of said first permeate to an acidic water solution having a pH in the range of 5 to 7 in order for a second weakly ionized material comprised of ammonia to become ionized in an acidic solution;

(e) transferring said acidic water solution to the high pressure side of a second reverse osmosis membrane; and

(f) further purifying said acidic water solution by passing at least a portion thereof through said second reverse osmosis membrane to provide a second retentate containing ions of said second weakly ionized material ionized in said acidic solution and a second permeate, the second permeate having high resistivity.