Glass article having a solar control coating

• US 5,780,149 A
• Filed: 09/13/1996
• Issued: 07/14/1998
• Est. Priority Date: 09/13/1996
• Status: Expired due to Fees

• Current Assignee: Libbey-Owens-Ford Co. (Eaton Corporation PLC.)
• Original Assignee: Libbey-Owens-Ford Co. (Eaton Corporation PLC.)
• Inventors: Strickler, David A., McCurdy, Richard J.
• Primary Examiner(s): TURNER, ARCHENE A
• Application Number:
  US08/713,785
• Time in Patent Office: 669 Days
• Field of Search: 428/336, 428/212, 428/697, 428/699, 428/701, 428/702, 428/428, 428/432, 428/216, 359/359, 359/361, 359/580, 359/581, 359/582, 359/586, 359/588, 359/589
• US Class Current: 428/336
• CPC Class Codes: B32B 17/06 comprising glass as the main or only constituent of a layer, next to another layer of a specific material
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 17/3435 comprising a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 17/3441 comprising carbon, a carbide or oxycarbide
• CPC Class Codes: G02B 5/282 reflecting for infrared and transparent for visible light, e.g. heat reflectors, laser protection
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/265 1 mil or less

Abstract

A glass article having a solar control coating is disclosed for use in producing heat reducing glass for architectural windows. The coated article includes a glass substrate, an iridescence-suppressing interlayer deposited on and adhering to the surface of the glass substrate. At least a first transparent coating deposited on and adhering to the surface of the iridescence-suppressing coating and at least a second transparent coating deposited on and adhering to the surface of the first transparent coating. The first transparent coating and the second transparent coating have a difference in refractive indices in the near infrared region greater than a difference in the refractive indices in the visible region. The use of the article in architectural glazing results in a glazing that rejects solar energy in the near infrared region while permitting the transmittance of a high degree of visible light.

Claims

1. A coated glass article comprising:

(a) a glass substrate, having a surface;

(b) an iridescence-suppressing interlayer deposited on and adhering to the surface of the glass substrate;

(c) a first transparent coating deposited on and adhering to the iridescence-suppressing interlayer; and

(d) a second transparent coating deposited on and adhering to said first transparent coating, said first transparent coating and said second transparent coating having a difference in refractive indices in the near infrared region greater than a difference in refractive indices in the visible region, wherein the coatings, including the interlayer, are such as to provide, when applied to a clear nominal 3 mm glass substrate, a glass article having a visible light transmittance (Illuminant C) of at least 10 percentage points higher than a solar heat transmittance integrated with an air mass 1.5.

2. The coated glass article of claim 1, wherein the coatings including the interlayer are such as to provide a neutral color in transmittance and reflectance when applied to a clear glass substrate.

3. The coated glass article of claim 2, wherein said article exhibits a color saturation of less than 12 units, as defined by CIELAB color scale coordinates.

4. The coated glass article of claim 1, wherein said coated glass article has a visible light transmittance (Illuminant C) of at least 60% on a clear glass substrate at a nominal 3 mm thickness.

5. The coated glass article of claim 1, wherein said glass substrate is a clear float glass ribbon.

6. The coated glass article of claim 1, wherein said first transparent coating is selected from the group consisting of indium oxide doped with tin, indium oxide doped with fluorine, tin oxide doped with fluorine, tin oxide doped with antimony, zinc oxide doped with aluminum, zinc oxide doped with fluorine, zinc oxide doped with boron, cadmium stannate, zinc stannate, tungsten oxide, tungsten oxide doped with fluorine, titanium nitride, and vanadium nitride.

7. The coated glass article of claim 1, wherein said first transparent coating has a carrier density greater than about 5×

10²⁰ per cubic centimeter.

8. The coated glass article of claim 1, wherein said second transparent coating is selected from the group consisting of tin oxide, titanium oxide, aluminum oxide, indium oxide, zinc oxide, and a metal oxide mixed with silica.

9. The coated glass article of claim 1, wherein said interlayer has a refractive index in the visible region defined as about the square root of the multiple of the refractive indices in the visible region of said glass and said first transparent coating, said interlayer having a total optical thickness of about 1/4 wavelength of a 500 nanometer design wavelength.

10. The coated glass article of claim 1, wherein said interlayer further comprises two component layers including,

(a) a first component layer of relatively high index refractive index material deposited on and adhering to the glass substrate;

(b) a second component layer of a relatively low refractive index material deposited on and adhering to the first component layer, wherein each component layer has a thickness such that the combined interlayer forms an iridescence suppressing means with a total optical thickness of about 1/6th to about 1/12th of a 500 nanometer design wavelength.

11. The coated glass article of claim 1, further comprising an intermediate coating deposited on and adhering to said iridescence-suppressing interlayer, said intermediate coating having a refractive index in the near infrared greater than the refractive index in the near infrared of the first transparent coating.

23. The coated glass article of claim 4, wherein said intermediate coating and said second transparent coating are selected from the group consisting of tin oxide, titanium oxide, aluminum oxide, indium oxide, zinc oxide, and a metal oxide mixed with silica.

24. An insulated glass unit for architectural windows, comprising a coated glass article as defined in claim 1.

25. The insulated glass unit of claim 24, wherein said insulated glass unit has a neutral color in transmittance and reflectance.

26. The insulated glass unit of claim 24, wherein said insulated glass unit has a shading co-efficient no greater than 0.65.

27. The insulated glass unit of claim 24, wherein said insulated glass unit has a U value of less than 0.5.

12. A coated glass article comprising:

(a) a glass substrate, having a surface;

(b) an iridescence-suppressing interlayer deposited on and adhering to the surface of the glass substrate;

(c) an indium oxide coating doped with tin deposited on and adhering to said iridescence-suppressing interlayer; and

(d) a tin oxide coating deposited on and adhering to said indium oxide coating doped with tin, said indium oxide coating doped with tin and said tin oxide coating having a difference in refractive indices in the near infrared region greater than a difference in refractive indices in the visible region, wherein the coatings, including the interlayer, are such as to provide, when applied to a clear nominal 3-mm glass substrate, a glass article having a visible light transmittance (Illuminant C) of at least 10 percentage points higher than a solar heat transmittance integrated with an air mass 1.5.

13. The coated glass article of claim 12, wherein said coated glass article has an emittance less than or equal to about 0.2.

14. The coated glass article of claim 12, wherein said iridescence-suppressing interlayer includes a tin oxide coating deposited on and adhering to the surface of the glass substrate, and a silicon oxide coating deposited on and adhering to the tin oxide coating.

15. The coated glass article of claim 12, wherein said interlayer has a refractive index in the visible region defined as about the square root of the multiple of the refractive indices in the visible region of said glass and said first transparent coating, said interlayer having a total optical thickness of about 1/4 wavelength of a 500 nanometer design wavelength.

16. The coated glass article of claim 12, wherein said interlayer further comprises two component layers including,

(1) a first component layer of relatively high index refractive index material deposited on and adhering to the glass substrate;

(2) a second component layer of a relatively low refractive index material deposited on and adhering to the first component layer, wherein each component layer has a thickness such that the combined interlayer forms an iridescence suppressing means with a total optical thickness of about 1/6th to about 1/12th of a 500 nanometer design wavelength.

17. The coated glass article of claim 12, wherein the coatings including the interlayer are such as to provide a neutral color in transmittance and reflectance on a clear glass substrate at a nominal 3 mm thickness.

18. The coated glass article of claim 17, wherein said article exhibits a color saturation of less than 12, as defined by CIELAB color scale coordinates.

19. The coated glass article of claim 12, wherein said coated glass article has a visible light transmittance (Illuminant C) of at least 60% on a clear glass substrate at a nominal 3 mm thickness.

20. The coated glass article of claim 12, wherein said indium oxide coating doped with tin has a carrier density greater than 5×

10²⁰ per cubic centimeter.

21. A coated glass article comprising:

(a) a glass substrate, having a surface;

(b) an iridescence-suppressing interlayer deposited on and adhering to the surface of the glass substrate;

(c) an intermediate coating deposited on and adhering to the iridescence-suppressing interlayer;

(d) at least one first transparent coating deposited on and adhering to the intermediate layer interlayer; and

(e) at least one second transparent coating deposited on and adhering to said first transparent coating, said intermediate coating and said first transparent coating having a difference in refractive indexes in the near infrared region greater than a difference in refractive indexes in the visible region, said first transparent coating and said second transparent coating having a difference in refractive indices in the near infrared region greater than a difference in refractive indices in the visible region, wherein the coatings, including the interlayer, are such as to provide, when applied to a clear nominal 3 mm glass substrate, a glass article having a visible light transmittance (Illuminant C) of at least 10 percentage points higher than a solar heat transmittance integrated with an air mass 1.5.

22. The coated glass article of claim 21, wherein said first transparent coating is selected from the group consisting of indium oxide doped with tin, indium oxide doped with fluorine, tin oxide doped with fluorine, tin oxide doped with antimony, zinc oxide doped with aluminum, zinc oxide doped with fluorine, zinc oxide doped with boron, cadmium stannate, zinc stannate, tungsten oxide, tungsten oxide doped with fluorine, titanium nitride, and vanadium nitride.