Conductive wire coating

• US 5,786,086 A
• Filed: 01/02/1996
• Issued: 07/28/1998
• Est. Priority Date: 01/02/1996
• Status: Expired due to Fees

• Current Assignee: Arizona Chemical Company LLC
• Original Assignee: Union Carbide Corporation (Dow, Inc.)
• Inventors: Frihart, Charles Richard, Kliwinski, Joseph
• Primary Examiner(s): Ryan, Patrick
• Assistant Examiner(s): GRAY, JILL M
• Application Number:
  US08/581,782
• Time in Patent Office: 938 Days
• Field of Search: 427/117, 427/120, 427/372.2, 427/384, 427/553, 427/388.5, 428/379, 428/375, 428/383, 525/435, 525/420.5, 525/426, 522/164, 174/110 SR, 174/110 N
• US Class Current: 428/379
• CPC Class Codes: H01B 13/065 Insulating conductors with lacquers or enamels
• CPC Class Codes: H01B 3/303 Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups H01B3/38 or H01B3/302
• CPC Class Codes: H01B 3/44 vinyl resins; acrylic resins silicones H01B3/46
• CPC Class Codes: Y10T 428/2933 Coated or with bond, impregnation or core
• CPC Class Codes: Y10T 428/294 including metal or compound thereof [excluding glass, ceramic and asbestos]
• CPC Class Codes: Y10T 428/2947 Synthetic resin or polymer in plural coatings, each of different type

Abstract

A conductive wire coated with an improved electrical insulation and methods for the preparation of same. The methods involve coating a conductive wire with an insulating material that comprises a curable acrylate-modified aminoamide resin. The insulated conductive wires possess highly desirable properties, including, for example, desirable dielectric strength, heat-resistance, flexibility, mechanical properties and/or uniformity.

Claims

1. A method for electrically insulating a conductive wire comprising:

(a) coating a conductive wire with an insulating material which comprises a substantially solvent-free curable acrylate-modified aminoamide resin; and

(b) curing said resin to provide the insulated wire with a smooth and tack-free surface.

2. A method according to claim 1 wherein said resin comprises a Michael addition reaction product of a polyamide and a polyol ester having a multiplicity of acrylate ester groups.

3. A method according to claim 2 wherein said Michael addition reaction further comprises reacting with said polyol ester a mono- or disubstituted amine-containing reactive diluent of about 10 to about 44 carbon atoms.

4. A method according to claim 3 wherein said reactive diluent is selected from the group consisting of stearylamine, tallowamine, distearylamine, ditallowamine, dihydrogenated tallowamine, tallowaminopropylamine and dimer diamine.

5. A method according to claim 2 wherein said polyamide is derived from dimer acid.

6. A method according to claim 5 wherein said polyamide is derived from dimer acid, a linear dibasic acid and a linear, branched or cyclic aliphatic amine.

7. A method according to claim 2 wherein said polyol ester is selected from the group consisting of trimethylolethane triacrylate, trimethylolpropane triacrylate, ethoxylated trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, pentaerythritol trimethacrylate and pentaerythritol tetramethacrylate.

8. A method according to claim 2 wherein said polyamide has a softening point above about 50°

C.

9. A method according to claim 8 wherein said polyamide has a softening point from about 75°

C. to about 200°

C.

10. A method according to claim 9 wherein said polyamide has a softening point from about 95°

C. to about 150°

C.

11. A method according to claim 1 wherein said curing comprises photocuring.

12. A method according to claim 11 wherein said photocuring comprises UV curing.

13. A method according to claim 1 wherein step (a) comprises coating said wire with a thin coating of insulating material.

14. An electrically insulated conductive wire prepared according to claim 1.

15. A method for the preparation of an electrically insulated conductive wire having a smooth and tack-free surface, wherein the method comprises:

(a) providing a conductive wire; and

(b) coating said conductive wire with an insulating material which comprises a substantially solvent-free curable acrylate-modified aminoamide resin.

16. A method according to claim 15 wherein said acrylate-modified aminoamide resin comprises a Michael addition reaction product of a polyamide and a polyol ester having a multiplicity of acrylate ester groups.

17. A method according to claim 16 wherein said Michael addition reaction further comprises a mono- or disubstituted amine-containing reactive diluent of about 10 to about 44 carbon atoms.

18. A method according to claim 16 wherein said polyamide has a softening point above about 50°

C.

19. A method according to claim 18 wherein said polyamide has a softening point from about 75°

C. to about 200°

C.

20. A method according to claim 19 wherein said polyamide has a softening point from about 95°

C. to about 150°

C.

21. An electrically insulated conductive wire prepared by the process of claim 15.

22. A method for the preparation of an electrically insulated conductive wire according to claim 15 wherein step (b) comprises:

(i) coating said wire with said curable acrylate-modified aminoamide resin; and

(ii) curing said resin.

23. A method according to claim 22 wherein said coating step (i) is conducted neat.

24. A method according to claim 22 wherein said curing step (ii) comprises photocuring.

25. A method according to claim 24 wherein said photocuring comprises UV curing.

26. An electrically insulated conductive wire prepared by the process of claim 22.

27. An electrically insulated conductive wire prepared according to claim 15.

28. An electrically insulated conductive wire comprising a conductive wire covered with an insulating material which comprises a substantially solvent-free acrylate-modified aminoamide resin, wherein the surface of the insulated wire is smooth and tack-free.

29. A wire according to claim 28 wherein said resin comprises a Michael addition reaction product of a polyamide with a polyol ester having a multiplicity of acrylate ester groups.

30. A wire according to claim 29 wherein said Michael addition reaction further comprises a mono- or disubstituted amine-containing reactive diluent of about 10 to about 44 carbon atoms.

31. A wire according to claim 29 wherein said polyamide has a softening point above about 50°

C.

32. A wire according to claim 31 wherein said polyamide has a softening point from about 75°

C. to about 200°

C.

33. A wire according to claim 32 wherein said polyamide has a softening point from about 95°

C. to about 150°

C.

34. A wire according to claim 28 which is an electrically insulated magnet wire.

35. A wire according to claim 28 wherein said coating comprises a high dielectric strength.

36. A wire according to claim 28 wherein said coating is substantially heat-resistant.

37. An electrically insulated conductive wire according to claim 28 wherein said insulating material is coated on said wire in a thickness of no greater than about 20% of the diameter of the uncovered conductive wire.