Electrochromic rearview mirror incorporating a third surface metal reflector

• US 5,818,625 A
• Filed: 04/02/1997
• Issued: 10/06/1998
• Est. Priority Date: 04/02/1997
• Status: Expired due to Term

• Current Assignee: Gentex Corporation
• Original Assignee: Gentex Corporation
• Inventors: Forgette, Jeffrey A., Tonar, William L., Bauer, Frederick T., Byker, Harlan J.
• Primary Examiner(s): Epps, Georgia V.
• Assistant Examiner(s): BEY, DAWN MARIE
• Application Number:
  US08/832,587
• Time in Patent Office: 552 Days
• Field of Search: 359/267, 359/273
• US Class Current: 359/267
• CPC Class Codes: B60Q 1/2665 on rear-view mirrors lighting devices for vehicle interior on or for rear-view mirrors B60Q3/258
• CPC Class Codes: B60R 1/088 using a cell of electrically changeable optical characteristic, e.g. liquid-crystal or electrochromic mirrors
• CPC Class Codes: G02F 1/1506 caused by electrodeposition, e.g. electrolytic deposition of an inorganic material on or close to an electrode
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: G02F 1/157 Structural association of cells with optical devices, e.g. reflectors or illuminating devices
• CPC Class Codes: G02F 2001/1502 complementary cell
• CPC Class Codes: G02F 2001/15145 the electrochromic layer comprises a mixture of anodic and cathodic compounds
• CPC Class Codes: G02F 2201/34 reflector
• CPC Class Codes: G02F 2203/02 reflective
• CPC Class Codes: H10K 50/87 Arrangements for heating or cooling

Abstract

An electrochromic variable reflectance mirror for a vehicle includes a reflector/electrode on the third surface of the mirror. This reflector/electrode forms an integral electrode in contact with the electrochromic media, and may be a single layer of a highly reflective material or may comprise a series of coatings. When a series of coatings is used for the reflector/electrode, there should be a base coating which bonds to the glass surface and resists any adverse interaction, e.g., corrosive action, with the constituents comprising the electrochromic media, an optional intermediate layer (or layers) which bonds well to the base coating and resists any adverse interaction with the electrochromic media, and at least one highly reflective layer which directly contacts the electrochromic media and which is chosen primarily for its high reflectance, stable behavior as an electrode, resistance to adverse interaction with the materials of the electrochromic media, resistance to atmospheric corrosion, resistance to electrical contact corrosion, the ability to adhere to the base or intermediate layer(s) (if present) and to the epoxy seal, and ease of cleaning. If a base layer is deposited it preferably covers the entire third surface; however, when this is done the highly reflective layer may optionally only coat the central portion of the third surface and not the perimeter edge portion. The third surface reflector/electrode provides of improved electrical interconnection techniques used to impart a voltage drive potential to a transparent conductor on the mirror'"'"'s second surface.

Claims

1. An electrochromic variable reflectance mirror for automotive vehicles, comprising front and rear spaced elements, each having front and rear surfaces, said rear surface of said front element having a layer of transparent conductive material disposed thereon, said front surface of said rear element having a reflector/electrode including at least a layer of highly reflective silver alloy, where said front and rear spaced elements are sealably bonded together in a spaced-apart relationship to define a chamber, where said chamber contains at least one solution-phase electrochromic material in contact with said reflector/electrode, and where said reflector/electrode is effective to reflect light through said medium and said front element when said light reaches said reflector/electrode after passing through said front element and said at least one electrochromic material.

2. The mirror according to claim 1, where the silver alloy is a combination of silver and an element selected from the group consisting essentially of gold, platinum, rhodium, and palladium.

3. The mirror according to claim 1, where said reflector/electrode comprises a plurality of layers.

4. The mirror according to claim 3, where said reflector/electrode further includes a base layer disposed beneath said highly reflective alloy.

5. The mirror according to claim 4, where said base layer comprises a material selected from the group consisting essentially of:

chromium;

chromium-molybdenum-nickel alloys;

nickel-iron-chromium alloys;

stainless steel; and

titanium.

6. The mirror according to claim 5, where said reflector/electrode further includes at least one intermediate layer disposed between said highly reflective alloy and said base layer, where said intermediate layer comprises a material selected from the group consisting essentially of:

molybdenum;

rhodium;

stainless steel; and

titanium.

7. The mirror according to claim 6, where said reflector/electrode further includes at least one flash over-layer disposed over said highly reflective layer, where said flash over-layer comprises a material selected from the group consisting essentially of:

rhodium, molybdenum, and platinum.

8. The mirror according to claim 1, where said layer of transparent conductive material has a sheet resistance ranging from about 0.1 ohms per square to about 40 ohms per square.

9. The mirror according to claim 8, where the sheet resistance of said transparent conductor ranges from about 0.5 ohms per square to about 15 ohms per square.

25. The mirror according to any of claims 1, 16 and 20, where said reflector/electrode is removed in a peripheral portion.

26. The mirror according to claim 25, where said reflector/electrode is removed by a technique selected from the group consisting of etching, mechanical scraping and sandblasting.

10. An electrochromic variable reflectance mirror for automotive vehicles, comprising front and rear spaced elements, each having front and rear surfaces, said rear surface of said front element having a layer of transparent conductive material disposed thereon, said front surface of said rear element having a reflector/electrode including at least a layer of highly reflective material and a flash over-coat layer, where said front and rear spaced elements are sealably bonded together in a spaced-apart relationship to define a chamber, where said chamber contains at least one solution-phase electrochromic material in contact with said flash layer, and where said reflector/electrode is effective to reflect light through said medium and said front element when said light reaches said reflector/electrode after passing through said front element and said at least one electrochromic material.

11. The mirror according to claim 10, where said highly reflective material is a material selected from the group consisting of silver and silver alloys, where the silver alloy is a combination of silver and an element selected from the group consisting essentially of gold, platinum, rhodium, and palladium.

12. The mirror according to claim 11, where said reflector/electrode further includes a base layer disposed beneath said highly reflective alloy.

13. The mirror according to claim 12, where said base layer comprises a material selected from the group consisting essentially of:

chromium;

chromium-molybdenum-nickel alloys;

nickel-iron-chromium alloys;

stainless steel; and

titanium.

14. The mirror according to claim 11, where said reflector/electrode further includes at least one intermediate layer disposed between said highly reflective alloy and said base layer, where said intermediate layer comprises a material selected from the group consisting essentially of:

molybdenum;

rhodium;

stainless steel; and

titanium.

15. The mirror according to claim 10 where said flash over-layer comprises a material selected from the group consisting essentially of:

rhodium, molybdenum, and platinum.

16. An electrochromic variable reflectance mirror for automotive vehicles, comprising front and rear spaced elements, each having front and rear surfaces, said rear surface of said front element having a layer of transparent conductive material disposed thereon, said front surface of said rear element having a reflector/electrode comprising a base layer covering the entire portion of said front surface of said rear element and at least one additional layer covering an inner portion of said front surface of said rear element, said at least one additional layer including a layer of a highly reflective material, where said front and rear spaced elements are sealably bonded together in a spaced-apart relationship to define a chamber, where said chamber contains at least one solution-phase electrochromic material in contact with said reflector/electrode, and where said reflector/electrode is effective to reflect light through said medium and said front element when said light reaches said reflector/electrode after passing through said front element and said at least one electrochromic material.

17. The mirror according to claim 16, where said highly reflective material is a material selected from the group consisting of silver and silver alloys, where the silver alloy is a combination of silver and an element selected from the group consisting essentially of gold, platinum, rhodium, and palladium.

18. The mirror according to claim 16, where said base layer comprises a material selected from the group consisting essentially of:

chromium;

chromium-molybdenum-nickel alloys;

nickel-iron-chromium alloys;

stainless steel; and

titanium.

19. The mirror according to claim 16, where said reflector/electrode further includes at least one intermediate layer disposed between said highly reflective alloy and said base layer, where said intermediate layer comprises a material selected from the group consisting essentially of:

molybdenum;

rhodium;

stainless steel;

titanium; and

alloys and combinations thereof.

20. The mirror according to claim 19, where said intermediate layer covers the entire surface of said front surface of said rear element.

21. The mirror according to claim 19, where said intermediate layer covers the inner portion of said front surface of said rear element.

22. The mirror according to claim 16, where said reflector/electrode further includes at least one flash over-layer disposed over said highly reflective layer, where said flash over-layer comprises a material selected from the group consisting essentially of:

rhodium, molybdenum, and platinum.

23. The mirror according to claim 16, where said layer of transparent conductive material has a sheet resistance ranging from about 0.1 ohms per square to about 40 ohms per square.

24. The mirror according to claim 16, where the sheet resistance of said transparent conductor ranges from about 0.5 ohms per square to about 15 ohms per square.

27. An electrochromic variable reflectance mirror for automotive vehicles, comprising front and rear spaced elements, each having front and rear surfaces, said rear surface of said front element having a layer of transparent conductive material disposed thereon, said front surface of said rear element having at least one layer of a reflector/electrode comprising a highly reflective material covering an inner portion of said front surface of said rear element and extending to a small area of an edge thereof, a conductive material disposed on a peripheral portion of said front surface of said rear element separated from said reflector/electrode by an area devoid of reflector/electrode and conductive material, said front and rear spaced elements being bonded together in a spaced-apart relationship to define a chamber by a seal member disposed on said conductive material, where said mirror further includes means for providing electrical interconnection between said conductive material and said transparent conductive material, where said chamber contains at least one solution-phase electrochromic material in contact with said reflector/electrode, and where said reflector/electrode is effective to reflect light through said medium and said front element when said light reaches said reflector/electrode after passing through said front element and said at least one electrochromic material.

28. The mirror according to claim 27, where said interconnection means comprises conductive particles disposed in said seal member.

29. The mirror according to claim 28, where said conductive particles are silver.

30. The mirror according to claim 28, where said conductive particles are beads coated with a conductive material.

31. The mirror according to claim 30, where said conductive beads are coated with one of gold, silver and copper, and are used as spacers.

32. The mirror according to claim 28, where said interconnection means comprises a conductive interconnection material disposed on the outer edge of said seal member.

33. The mirror according to claim 27, where a non-conductive material is disposed on said portion of the front surface of said rear element devoid of said conductive material.

34. An electrochromic variable reflectance mirror for automotive vehicles, comprising front and rear spaced elements, each having front and rear surfaces, said rear surface of said front element having a layer of transparent conductive material disposed thereon, said front surface of said rear element having a cured first portion of a peripheral seal member covered by a reflector/electrode comprising a highly reflective material, where said cured first portion of said seal member is removed to a predetermined thickness such that said reflector/electrode is separated into an inner portion covering an inner portion of said front surface of said rear element and extending to a small area of an edge thereof, and an outer portion separated from said inner portion by said cured first portion of a seal member, where said outer portion of said reflector/electrode is not in electrical contact with said inner portion, said front and rear spaced elements being bonded together, in a spaced-apart relationship to define a chamber, by a second portion of said seal member disposed on said cured first portion of said seal member, where said mirror further includes means for providing electrical interconnection between said outer portion of said reflector/electrode and said transparent conductive material, where said chamber contains at least one solution-phase electrochromic material in contact with said reflector/electrode, and where said reflector/electrode is effective to reflect light through said medium and said front element when said light reaches said reflector/electrode after passing through said front element and said at least one electrochromic material.

35. The mirror according to claim 34, where said interconnection means comprises a conductive interconnection material disposed on the outer edge of said seal member.

36. The mirror according to claim 35, where said conductive interconnection material comprises a material selected from a conductive epoxy and a conductive paint.