Method for producing bright stainless steel

• US 5,830,291 A
• Filed: 10/08/1996
• Issued: 11/03/1998
• Est. Priority Date: 04/19/1996
• Status: Expired due to Term

• Current Assignee: Jewel Acquisition, LLC
• Original Assignee: J&L Specialty Steel, Inc. (Allegheny Technologies Incorporated)
• Inventors: Senzarin-Kulik, Kelley L., Denoi, Anthony J., McGuire, Michael F.
• Primary Examiner(s): Yee, Deborah
• Application Number:
  US08/726,841
• Time in Patent Office: 756 Days
• Field of Search: 148/610, 148/606
• US Class Current: 148/610
• CPC Class Codes: C21D 8/0205 of ferrous alloys
• CPC Class Codes: C21D 8/0236 Cold rolling
• CPC Class Codes: C21D 8/0278 involving a particular surface treatment C21D8/0294 takes precedence
• CPC Class Codes: C23G 1/086 solutions containing HF

Abstract

A method for producing bright stainless steel whereby a hot mill band having a dull oxide-free surface is first formed. The hot mill band is cold reduced to form a full hard coil having a shiny surface. The coil is subjected to continuous annealing at a temperature of 1500°-1950° F. in an oxygen-containing atmosphere sufficient to form a protective FeCr₂ O₃ scale. The annealed coil is subjected to a mild non-etching pickling process to remove the black scale. The coil is then rolled on a temper mill having specially finished rolls to impart a surface pattern that replicates an abrasively polished surface.

Claims

1. A method for producing bright stainless steel comprising:

a) forming a hot mill band having a dull oxide free surface;

b) cold reducing the hot mill band to form a full hard coil having a shiny surface;

c) subjecting said full hard coil to a continuous anneal at a temperature of 1500°

-1950°

F. in an oxygen containing atmosphere sufficient to form a protective FeCr₂ O₃ scale;

d) subjecting said annealed coil to a mild non-etching pickling process to remove the scale; and

e) rolling said annealed coil on a temper mill having specially finished rolls configured to impart a surface pattern that replicates an abrasively polished surface.

2. The method of claim 1 wherein the mild non-etching pickling process includes air cooling the annealed coil to an intermediate temperature where it is subjected to a molten salt treatment and then air cooling to ambient temperature where the coil is subjected to a mild acid pickle.

3. The method of claim 2 wherein the intermediate temperature is between 800°

F. and 1000°

F.

5. The method of claim 3 including a mild acid bath and maintaining an iron content of the nitric acid bath at or below 1%.

6. The method of claim 1 wherein the surface pattern following temper rolling is defined by an arithmetic roughness on the order of 2 to 50 micro inch and an 85°

transverse surface gloss of 40 to 90%.

7. The method of claim 1 wherein the stainless steel is of the austenitic type and the annealing temperature is 1800°

to 1950°

F.

8. The method of claim 1 wherein the stainless steel is of the ferritic type and the composition includes ferrite stabilizers.

9. The method of claim 8 wherein the ferrite stabilizers include at least Ti.

10. The method of claim 1 wherein the atmosphere has an oxygen partial pressure of at least 0.1%.

11. The method claim of 10 wherein the oxygen partial pressure is at least 2%.

12. The method of claim 1 wherein the air/fuel ratio used for combustion is at least 9.2 to 1.

13. The method of claim 1 wherein said coil is subject to a temper pass on a smooth roll prior to the specially finished roll pass.

4. A method for producing bright stainless steel comprising:

a) forming a hot mill band having a dull oxide free surface;

b) cold reducing the hot mill band to form a full hard coil having a shiny surface;

c) subjecting said full hard coil to a continuous anneal at a temperature of 1500°

-1950°

F. in an oxygen containing atmosphere sufficient to form a protective FeCr₂ O₃ scale;

d) subjecting said annealed coil to a mild non-etching pickling process to remove the scale, wherein the mild non-etching pickling process includes air cooling the annealed coil to an intermediate temperature between 800°

F. and 1000°

F. where it is subjected to a molten salt treatment and then air cooling to ambient temperature where the coil is subjected to a mild acid pickle, and wherein the mild acid pickle includes subjecting said annealed coil to at least one of a nitric acid bath and rinse, a sulfuric acid bath and rinse with hydrofluoric concentration of 0.5% or less on either acid bath; and

e) rolling said annealed coil on a temper mill having specially finished rolls configured to impart a surface pattern that replicates an abrasively polished surface.

14. A method for producing bright stainless steel from a cold reduced, full hard coil, comprising the steps of:

subjecting the full hard coil to a continuous anneal at a temperature of 1500°

-1950°

F. in an oxygen containing atmosphere to form an FeCr₂ O₃ containing scale on the annealed coil;

pickling the annealed coil with a mild non-etching pickling process to remove the scale, wherein the pickling process includes treating the annealed coil with an acid bath including at least one of nitric and sulfuric acid, the acid bath having a hydrofluoric acid content of less than 0.5%; and

rolling the descaled coil on a temper mill having specially finished rolls such that a surface pattern is imparted to the rolled coil which replicates an abrasively polished surface.

15. The method as claimed in claim 14, wherein the steel is an austenitic steel and the annealing temperature is 1800°

-1950°

F.

16. The method as claimed in claim 15, wherein the atmosphere has an oxygen partial pressure of at least two percent.

17. The method as claimed in claim 14, wherein the steel is ferritic steel having at least one ferrite stabilizer selected from the group consisting of Ti, Nb, Ta and Zr and the annealing temperature is 1700°

-1950°

F.

18. The method as claimed in claim 14, including:

cooling the annealed coil to an intermediate temperature;

subjecting the annealed coil to a molten salt treatment; and

cooling the annealed coil to ambient temperature.