Photochromic devices

• US 5,838,483 A
• Filed: 02/13/1997
• Issued: 11/17/1998
• Est. Priority Date: 02/10/1995
• Status: Expired due to Fees

• Current Assignee: Donnelly Corporation (Magna International Incorporated)
• Original Assignee: Donnelly Corporation (Magna International Incorporated)
• Inventors: Agrawal, Anoop, Cronin, John P., Teowee, Gimtong, Allemand, Pierre-Marc, Tonazzi, Juan Carlos Lopez
• Primary Examiner(s): Hellner, Mark
• Application Number:
  US08/798,725
• Time in Patent Office: 642 Days
• Field of Search: 359/241, 359/265, 359/275
• US Class Current: 359/265
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: G02F 1/0126 Opto-optical modulation, i.e. control of one light beam by another light beam, not otherwise provided for in this subclass
• CPC Class Codes: G02F 1/13324 Circuits comprising solar cells
• CPC Class Codes: G02F 1/1533 structural features not otherwise provided for
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor
• CPC Class Codes: H01M 14/005 Photoelectrochemical storage cells light sensitive devices H01G9/20, semiconductors sensitive to light H01L31/00

Abstract

A photochromic device is provided which allows the user to leave the device in a high transmissive state even when exposed to a source of radiation and to control the degree of darkening achieved while exposed to the source of radiation.

Claims

1. A photochromic device comprising (i) a first conducting electrode opposing a second conducting electrode, wherein at least one of said electrodes is transparent, (ii) a radiation sensitive electrode disposed on an opposing surface of said first conducting electrode, (iii) an interconnecting medium containing a redox promoter disposed between said second conducting electrode and said radiation sensitive electrode, (iv) an electrical connection means for electrically connecting said first conducting electrode and said second conducting electrode and at least one of:

(a) a first ion intercalative electrode disposed between said interconnecting medium and said second conducting electrode;

(b) a second ion intercalative electrode disposed between said radiation sensitive electrode and said interconnecting medium; and

(c) a redox active species in said interconnecting medium.

2. The photochromic device according to claim 1, further comprising control means for controlling the electrical connection between the first conducting electrode and the second conducting electrode.

3. The photochromic device according to claim 1, further comprising a first substrate disposed on an outer facing surface of said first conducting electrode and a second substrate disposed on an other outer facing surface of said second conducting electrode, wherein at least one of said substrates is transparent.

4. The photochromic device according to claim 1, wherein said device comprises the first ion intercalative electrode disposed between said interconnecting medium and said conducting electrode.

5. The photochromic device according to claim 1, wherein said device comprises the second ion intercalative electrode disposed between said radiation sensitive electrode and said interconnecting medium.

6. The photochromic device according to claim 1, wherein said device comprises both the first ion intercalative electrode and the second ion intercalative electrode.

7. The photochromic device according to claim 1, wherein said device comprises the redox active species in said interconnecting medium.

8. The photochromic device according to claim 1, wherein said radiation sensitive electrode is a semiconductor.

9. The photochromic device according to claim 1, wherein said radiation sensitive electrode is selected from the group consisting of titanium oxide, zinc oxide, tungsten oxide, nickel oxide, cadmium sulfide, zinc sulfide and mixtures thereof.

10. The photochromic device according to claim 1, wherein said radiative sensitive electrode is a p-n semiconductor or a Schottky junction.

11. The photochromic device according to claim 1, wherein at least one of said ion intercalative electrodes is comprised of an ion intercalatable material selected from the group consisting of tungsten oxide, tungstates, molybdenum oxide, molybdates, titanium oxide, vanadium oxide, vanadates, niobium oxide, polyviologens, polyanilines, polythiophenes, Prussian blue, composites thereof and mixtures thereof.

12. The photochromic device according to claim 1, wherein said first conducting electrode and said second conducting electrode are comprised of indium oxide doped with about 2 to about 20 mole % of tin oxide.

13. The photochromic device according to claim 1, wherein said first conducting electrode and said second conducting electrode are comprised of a fluorine doped tin oxide layer deposited on top of a non-iridescent coated transparent substrate.

14. The photochromic device according to claim 1, wherein said interconnecting medium is a solid or a liquid.

15. The photochromic device according to claim 1, wherein said interconnecting medium contains a dissociable salt selected from the group consisting of lithium, potassium, sodium, rubidium, silver and cesium salts.

16. The photochromic device according to claim 15, wherein said dissociable salt is selected from the group consisting of lithium perchlorate, lithium triflate, lithium iodide, lithium tetrafluoroborate and mixtures thereof.

17. The photochromic device according to claim 16, wherein said liquid interconnecting medium is comprised of said dissociable salt mixed with propylene carbonate, benzyl alcohol or mixtures thereof.

18. The photochromic device according to claim 1, wherein said interconnecting medium contains an organic base.

19. The photochromic device according to claim 18, wherein said organic base is an organic amine.

20. The photochromic device according to claim 19, wherein said organic amine is selected from the group consisting of pyridine, t-butylpyridine, tributylamine, triethanolamine, 3-picoline, 1,8-diazabicyclo 5,4,0!undec-7-ene and mixtures thereof.

21. The photochromic device according to claim 14, wherein said solid interconnecting medium is selected from a thermoplastic or a thermosetting polymer.