Pesticidal composition to noxious organisms

• US 5,866,514 A
• Filed: 07/10/1996
• Issued: 02/02/1999
• Est. Priority Date: 07/11/1995
• Status: Expired due to Fees

• Current Assignee: Nippon Petrochemicals Co., Ltd. (ENEOS Holdings, Inc.)
• Original Assignee: Nippon Petrochemicals Co., Ltd. (ENEOS Holdings, Inc.)
• Inventors: Shouko, Toshikatsu, Sugisawa, Kunio, Togami, Yasuo
• Primary Examiner(s): Hubinson, Allen J.
• Application Number:
  US08/676,662
• Time in Patent Office: 937 Days
• Field of Search: 514/86, 514/89, 514/136, 514/147, 514/479, 514/481, 514/748, 514/112, 514/132, 514/148, 504/347, 504/116
• US Class Current: 504/347
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/02 containing liquids as carriers, diluents or solvents
• CPC Class Codes: A01N 25/12 Powders or granules A01N25/26 takes precedence
• CPC Class Codes: A01N 27/00 Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
• CPC Class Codes: A01N 33/18 Nitro compounds
• CPC Class Codes: A01N 37/34 Nitriles
• CPC Class Codes: A01N 57/14 containing aromatic radicals
• CPC Class Codes: A01N 57/16 containing heterocyclic radicals

Abstract

A pesticidal composition to noxious organisms which comprises a diarylalkane and an active component effective for killing or repelling noxious organisms and the diarylalkane is at least one member selected from the group consisting of butyl diphenylmethane, butyl-1,1-diphenylethane and butyl-1,2-diphenylethane. The used diarylalkane has a high dissolving power to the effective component, a high boiling point and a high flash point with low unpleasant smell and does not deteriorate the effective component in the pesticidal composition.

Claims

1. A pesticidal composition which comprises an active component which kills or repels noxious organisms and a diarylalkane as represented by the following formula I!¹ ##STR2## wherein R₁ is a bivalent radical which is formed from methane or ethane, each of R₂ and R₃ is a hydrogen atom or an alkyl group having 3 or 4 carbon atoms, R₄ is an alkyl group having 3 or 4 carbon atoms, and the groups R₂, R₃ and R₄ can be the same or different ones, and wherein said diarylalkane is present in said composition in an amount of from about 0.01 to about 500 parts by weight based on 1 part by weight of said active component, and said composition is substantially free of noxious odor.

2. The pesticidal composition as claimed in claim 1, wherein said diarylalkane is one member selected from the group consisting of butyl diphenylmethane, butyl-1,1-diphenylethane, and butyl-1,2-diphenyl-ethane.

3. The pesticidal composition as claimed in claim 1, wherein said diarylalkane is a mixture of 20 to 80 wt. % of butyl diphenylmethane, 5 to 50 wt. % of butyl-1,1-diphenylethane and 5 to 50 wt. % of butyl-1,2-diphenylethane.

4. The pesticidal composition as claimed in claim 1, wherein said diarylalkane contains more than 80 wt. % of butyl.

5. A pesticidal composition as claimed in claim 1 wherein said diarylalkane comprises at least one member selected from the group consisting of propyl diphenylmethane, propyl-1,1-diphenylethane, propyl-1,2-diphenylethane, butyl diphenylmethane, butyl-1,1-diphenylethane, butyl-1,2-diphenylethane, dipropyl diphenylmethane, dipropyl-1,1 -diphenylethane, dipropyl-1,2-diphenylethane, dibutyl diphenylmethane, dibutyl-1,1 -diphenylethane and dibutyl-1,2-diphenylethane.

6. A pesticidal composition as claimed in claim 1, wherein said composition comprises a solid composition and said diarylalkane is present in said composition in an amount of from about 0.1 to about 10 parts by weight based on 1 part by weight of said active component.

7. A pesticidal composition as claimed in claim 1, wherein said composition comprises a suspension composition and said diarylalkane is present in said composition in an amount of from about 0.1 to about 10 parts by weight based on 1 part by weight of said active component.

8. A pesticidal composition as claimed in claim 1, wherein said composition comprises a liquid and said diarylalkane is present in said composition in an amount of from about 0.1 to about 500 parts by weight based on 1 part by weight of said active component.

9. A pesticidal composition as claimed in claim 1, wherein said active component comprises at least one component selected from the group consisting of insectides and industrial microbicides.

10. A pesticidal composition as claimed in claim 1, wherein said active component comprises at least one component selected from the group consisting of organic phosphorus components, carbamate components, organic chlorine compound components, phenoxide components, benzoic acid components, phenol components, urea components, dinitroaniline components, nitrile components, S-triazine components and diazine components.

11. A pesticidal composition as claimed in claim 1, wherein said diarylalkane has a flash point of 152°

C. or higher.

12. A pesticidal composition as claimed in claim 1, wherein said active component comprises at least one component selected from the group consisting of O,O-dimethyl-O-(3-methyl-4-nitrophenyl) thiophosphate, ethyl-p-nitrophenyl-phenylphosphorothionate, diethyl-(2,4-dichlorophenyl) thiophosphate, dimethyl-4-methylthio-m-tolylphosphorothionate, O,O-diethyl-O-(2-isopropyl-4-methyl-6-pyrimidinyl) phosphorothioate, O-ethyl-diphenyldithio phosphate, S-benzyl-ethyl-phenylphosphonothiolate, tetrachlorovinphos, phoxim, O,O-dimethyl-O-(2,2-dichlorovinyl) phosphate, 1-naphthyl-N-methylcarbamate, 2-ethylthio-methyl) phenyl-methylcarbamate, 2-butylphenyl-N-methylcarbamate, O,O-diethyl-O-3,5,6-trichloro-2-pyridyl phosphorothioate, tetrachloroisophthalonitrile, 4,5,6,7-tetrachlorophthalide, N-tetrachloroethylthiotetrahydrophtalimide, chlorobenzylate, O,O-diethyl phthalimid methyldithiophosphate, etofenprox, tripropyl cyanate, sodium-2,4-dichlorophenoxyacetate, sodium (4-chloro-tolyl)oxy!acetate, dimethyl-tetrachloroterephthalate, sodium pentachloro phenoxide, diphenyl ethers of 2,4-dichlorophenyl-p-nitrophenyl ether, p-nitrophenyl-2,4,6-trichlorophenyl ether, p-nitrophenyl-m-tolylether, 3'"'"',4'"'"'-dichloropropionanilide, 3-(3,4-dichlorophenyl)-1,1-dimethyl urea, 3 -(3,4-dichlorophenyl)- 1-methyl urea, α

, α

, α

-trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine, N-butyl-N-ethyl-α

, α

, α

-trifluoro-2,6-dinitro-p-toluidine, N-(1-ethylpropyl)-3 ,4-dimethyl-2,6-dinitroaniline, 4-cyano-2,6-diiodophenyloctoate, 2,6-dichlorothiobenzamide, 2-chloro-4,6-bis(ethylamino)- 1,3,5-triazine, 2-ethylamino-4-propylamino-6-methylthio- 1,3,5-triazine, 3 -(0-tolyloxy) pyridazine, 5-bromo-3 -butyl-6-methyluracil, and 5-amino-4-chloro-2-phenyl-3 (2H)-pyridazinone.