Catalytic manufacture of vinyl fluoride

• US 5,880,315 A
• Filed: 11/04/1997
• Issued: 03/09/1999
• Est. Priority Date: 11/21/1996
• Status: Expired due to Fees

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.), Voith Sulzer Papiermaschinen GmbH
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Rao, V.N. Mallikarjuna, Subramanian, Munirpallam A.
• Primary Examiner(s): SIEGEL, ALAN M
• Application Number:
  US08/964,445
• Time in Patent Office: 490 Days
• Field of Search: 570/157, 570/158
• US Class Current: 570/157
• CPC Class Codes: B01J 27/125 with scandium, yttrium, aluminium, gallium, indium or thallium
• CPC Class Codes: B01J 27/138 with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
• CPC Class Codes: C07C 17/25 by splitting-off hydrogen halides from halogenated hydrocarbons
• CPC Class Codes: C07C 21/18 containing fluorine
• CPC Class Codes: Y02P 20/582 Recycling of unreacted starting or intermediate materials

Abstract

A process for the manufacture of vinyl fluoride (i.e., CH₂ ═CHF, VF or 1141) from 1,1-difluoroethane (i.e., CH₃ CHF₂, F152a or HFC-152a) is disclosed which involves contacting the 1,1-difluoroethane at an elevated temperature (200° C.-400° C.) with a multiphase catalyst composition consisting essentially of (a) fluorides of at least one divalent metal selected from magnesium and zinc, and (b) fluorides of trivalent aluminum, in which phases of the divalent fluorides are homogeneously dispersed with phases of the trivalent fluorides.

Claims

1. A process for the manufacture of vinyl fluoride from 1,1-difluoroethane which comprises contacting said 1,1-difluoroethane at an elevated temperature with a catalyst containing at least one divalent Group II metal compound, characterized by:

contacting said 1,1-difluoroethane at a temperature of from about 200°

C. to 400°

C. with a multiphase catalyst composition consisting essentially of (a) fluorides of at least one divalent metal selected from magnesium and zinc, and (b) fluorides of trivalent aluminum;

wherein phases of said divalent fluorides are homogeneously dispersed with phases of said trivalent fluorides.

2. The process of claim 1 wherein the catalyst is prepared by heating a single phase fluoride composition of the formula MAlF₅ (H₂ O)₂ or the formula NH₄ MAlF₆ (H₂ O) where M is at least one divalent element selected from the group consisting of Zn and Mg, to a temperature sufficient to substantially remove H₂ O, and NH₄ F when NH₄⁺ is present, in said single phase fluoride composition.

3. The process of claim 1 wherein the catalyst is a magnesium fluoride/aluminum fluoride composition where the ratio of Mg:

Al is about 1;

1.

4. The process of claim 1 wherein the catalyst is a zinc fluoride/aluminum fluoride composition where the ratio of Zn:

Al is about 1;

1.

5. The process of claim 1 wherein the catalyst is a magnesium fluoride/zinc fluoride/aluminum fluoride composition where the ratio of (Zn+Mg):

Al is about 1;

1.

6. The process of claim 1 wherein the temperature is from 250°

C. to 350°

C.

7. The process of claim 1 wherein the temperature is from 250°

C. to 325°

C.

8. The process of claim 1 wherein a contact time is employed which is sufficient to provide a dehydrofluorination of 1,1-difluoroethane equal to at least 80% of the equilibrium value for conversion of 1,1-difluoroethane to vinyl fluoride at the temperature employed.