Ink jet print head containing a radiation curable resin layer

• US 5,907,333 A
• Filed: 03/28/1997
• Issued: 05/25/1999
• Est. Priority Date: 03/28/1997
• Status: Expired due to Term

• Current Assignee: Funai Electric Co., Ltd.
• Original Assignee: Lexmark International Incorporated (Ninestar Corporation)
• Inventors: Patil, Girish Shivaji, Spivey, Paul Timothy, Williams, Gary Raymond
• Primary Examiner(s): Fuller, Benjamin R.
• Assistant Examiner(s): ANNICK, CHRISTINA FRANCIS
• Application Number:
  US08/827,564
• Time in Patent Office: 788 Days
• Field of Search: 347/65, 347/64, 347/63, 347/20, 156/310, 156/335, 156/292
• US Class Current: 347/20
• CPC Class Codes: B41J 2/1603 of the front shooter type
• CPC Class Codes: B41J 2/1607 Production of print heads with piezoelectric elements B41J2/1606, B41J2/162 take precedence
• CPC Class Codes: B41J 2/1623 bonding and adhesion
• CPC Class Codes: B41J 2/1631 photolithography
• CPC Class Codes: B41J 2/1645 thin film formation by spincoating
• CPC Class Codes: B41J 2202/03 Specific materials used
• CPC Class Codes: C08G 59/68 characterised by the catalysts used
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• CPC Class Codes: G03F 7/038 Macromolecular compounds which are rendered insoluble or differentially wettable G03F7/075 takes precedence; macromolecular azides G03F7/012; macromolecular diazonium compounds G03F7/021

Abstract

This invention relates to an ink jet print head having ink passage ways formed in a radiation cured resin layer which is attached to a substrate. The passageways are connected in fluid flow communication to an ink discharging outlet provided by an orifice plate. In order to form the passage ways in the resin layer, a resin composition is exposed to a radiation source in a predetermined pattern to cure certain regions of resin layer while other regions which provide the passage ways remain uncured. The uncured regions are removed from the resin layer leaving the desired passage ways. The resin composition to be used for forming the radiation curable layers is a resin composition comprising: a first multifunctional epoxy compound; a second multifunctional compound; a photoinitiator; and a non-photoreactive solvent.

Claims

1. An ink jet print head comprising a polymeric nozzle plate having an inner layer of phenolic butyral, ink passage ways connected to nozzles of said nozzle plate, and a predominately silicon containing substrate, said passage ways being formed by subjecting a layer of a radiation curable resin composition coated on said substrate to exposure of radiation in a pattern to cure said composition in said pattern to thereby form a cured region of said resin composition, said cured region thereby being bonded on one side of said cured region to said predominately silicon containing substrate, and removing the uncured resin composition region from said layer, said radiation curable resin composition comprising:

(A) about 10 to 20 weight percent of a difunctional first epoxy compound;

(B) less than about 4.5% by weight of a multifunctional second crosslinking epoxy compound;

(C) about 1 to about 10 weight percent of a photoinitiator capable of generating a cation; and

(D) about 20 to about 90 weight percent of a nonphotoreactive solvent, wherein the weight percents are based on the total weight of the resin composition;

said cured region being bonded opposite said substrate directly to said layer of phenolic butyral of said nozzle plate.

2. The ink jet print head according to claim 1 wherein the molecular weight of the first epoxy compound is from about 100 to about 100,000.

3. The ink jet print head according to claim 1 wherein the first epoxy compound is a diglycidyl ether of Bisphenol A.

4. The ink jet print head according to claim 1 wherein the photoinitiator is an aromatic complex salt photoinitiator is selected from the group consisting of onium salts of a Group VA element, onium salts of a Group VIA element, aromatic halonium salts, and combinations thereof.

5. The ink jet print head according to claim 1 wherein the resin composition further comprises up to about 35 weight percent of an acrylate or methacrylate polymer.

6. The ink jet print head according to claim 5 wherein the acrylate or methacrylate polymer is selected from the group consisting of copolymers of methylmethacrylate/n-butylmethacrylate, methylmethacrylate/n-butylmethacrylate/hydroxyethylmethacrylate, methylmethacrylate/-styrene/n-butylacrylate/hydroxyethylacrylate, styrene/hydroxyethylacrylate, and n-butylacrylate/hydroxyethylacrylate/vinyl acetate.