Thick film compositions for making medical electrodes

• US 5,928,571 A
• Filed: 08/10/1998
• Issued: 07/27/1999
• Est. Priority Date: 08/29/1997
• Status: Expired due to Term

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Chan, Man-Sheung
• Primary Examiner(s): KOPEC, MARK T
• Application Number:
  US09/131,435
• Time in Patent Office: 351 Days
• Field of Search: 252/514, 252/520.3, 252/521.5, 106/1.19, 106/1.14
• US Class Current: 252/514
• CPC Class Codes: A61N 1/0436 Material of the electrode
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon

Abstract

The invention is directed to a conductive composition for iontophoretic electrodes comprising, based on solids: (a) 20-90% wt finely divided particles of silver, carbon, graphite and mixtures thereof; (b) 0-75% wt. finely divided particles of silver chloride; (c) 0.25-10% wt. hydrophilic polymer; and (d) 2-15% wt. hydrophobic thermoplastic polymer having a glass transition temperature (Tg) >40° C. The invention is also directed to compositions wherein the binder comprises 5-15% wt. copolymer of hydrophilic and hydrophobic monomers.

Claims

1. A conductive composition for iontophoretic electrodes comprising, based on solids:

(a) 20-90% wt. silver particles;

(b) 0-75% wt. of silver chloride particles; and

(c) 5-15% wt. of a copolymer of hydrophilic and hydrophobic monomers wherein said hydrophilic monomer is selected from the group consisting of vinyl pyrrolidone, vinyl alcohol, vinyl methyl ether, hydroxyalkyl acrylate, hydroxyalkyl methacrylate, acrylamide and methacrylamide, and wherein said hydrophobic monomer is selected from the group consisting of vinyl chloride, vinylidene chloride, vinyl acetate, acrylonitrile, alkyl acrylate, alkyl methacrylate and styrene.

2. The composition of claim 1 further comprising organic vehicle.

3. The composition in claim 1 wherein the silver particles are in the range of 1-25 microns.

4. The composition in claim 1 wherein the silver chloride particles are in the range of 0.1-15 microns.

5. The composition in claim 1 further comprising conductive fillers selective from the group consisting of carbon and graphite.

6. The composition in claim 2 wherein the organic vehicle is selected from the group consisting of alkyl ketones, aromatic ketones, glycol alkyl ethers and their acetates, dibasic esters, n-methylpyrrolidone, butyrolactone, and aromatic solvents.

7. The composition of claim 1 wherein silver to silver chloride ratio is in the range of 100/0 to 80/20 by weight for iontophoretic anode.

8. The composition of claim 1 wherein silver to silver chloride ratio is in the range of 15/85 to 35/65 by weight for iontophoretic cathode.

9. The composition of claim 1 wherein the silver to silver chloride ratio by weight is in the range of 70/30 to 65/35.