Thickened peracid compositions

• US 5,962,392 A
• Filed: 06/23/1997
• Issued: 10/05/1999
• Est. Priority Date: 12/21/1994
• Status: Expired due to Term

• Current Assignee: Solvay Interox Limited
• Original Assignee: Solvay Interox Limited
• Inventors: Ellis, Enid Margaret, Revell, Christopher
• Primary Examiner(s): Lovering, Richard D.
• Assistant Examiner(s): Metzmaier, Daniel S.
• Application Number:
  US08/860,228
• Time in Patent Office: 834 Days
• Field of Search: 252/186.23, 252/186.26, 252/186.42, 510/310, 510/372, 510/373, 510/191, 510/218, 510/238, 510/503, 514/557, 134/3, 422/28
• US Class Current: 510/372
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/30 characterised by the surfactants
• CPC Class Codes: A01N 31/02 Acyclic compounds
• CPC Class Codes: A01N 37/16 containing the group; Thio analogues thereof
• CPC Class Codes: C11D 17/003 Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
• CPC Class Codes: C11D 3/3947 Liquid compositions

Abstract

Thickened aqueous compositions comprising soluble peracids, particularly peracetic acid are provided. The compositions are thickened by the use of one or more aliphatic alcohol ethoxylates having the general formula: R¹ R² CH--(OCH₂ CH₂)_n --OH in which R¹ and R² are each either hydrogen or linear or branched alkyl such that R¹ plus R² has a total of from 7 to 22 carbon atoms, and n is selected in the range of 1 to 15, such that the number ratio of carbon atoms in R¹ plus R² :n is greater than or equal to 3:1; and a co-surfactant selected from the group consisting of anionic surfactants, amine oxides, amphoteric surfactants and quaternary ammonium compounds.

Claims

1. A thickened aqueous composition comprising 0.01 to 40% w/w of a water-soluble peracid in solution together with a thickener wherein the thickener comprises:

(a) an aliphatic alcohol ethoxylate having the formula;

space="preserve" listing-type="equation">R.sup.1 R.sup.2 CH--(OCH.sub.2 CH.sub.2).sub.n --OH

in which R¹ and R² are hydrogen or linear or branched alkyl,

in which n is an integer of at least 1,

in which, when neither R¹ nor R² is a hydrogen atom, R¹ and R² have in total from 10 to 18 carbon atoms, and the number ratio of carbon atoms in R¹ plus R² ;

n is in the range of from 4;

1 to 7;

1, and

in which when either R¹ or R² is a hydrogen atom, the total number of carbon atoms is from 7 to 16 carbon atoms and the number ratio of carbon atoms in R¹ plus R² ;

n is in the range of from 4;

1 to 9;

1; and

(b) an amine oxide co-surfactant in an amount sufficient to increase the viscosity of the composition, said ethoxylate (a) being present in an amount of from 2.5 to 15% w/w, said co-surfactant (b) being present in an amount of from 0.1 to 5% w/w, and the weight ratio of said ethoxylate (a) to said co-surfactant (b) being from 2;

1 to 20;

1.

2. A composition according to claim 1 wherein, in the formula, either R¹ or R² is a hydrogen atom and the number ratio of carbon atoms in R¹ plus R² :

n is in the range of from 5;

1 to 8;

1.

3. A composition according to claim 2, wherein the total number of carbon atoms is from 9 to 16 carbon atoms.

4. A composition according to claim 1, wherein the water soluble peracid comprises peracetic acid.

5. A composition according to claim 1, or 4 wherein the pH of the thickened composition is 2.0 or more.

6. A composition according to claim 5, wherein the pH of the thickened composition is in the range of from 2.3 to 4.

7. A composition according to claim 1 or 4, wherein the weight ratio of alcohol ethoxylate (a) to co-surfactant (b) is in the range of from 4:

1 to 15;

1.

8. A composition according to claim 1 or 4, wherein the weight ratio of alcohol ethoxylate (a) to co-surfactant (b) is from 6:

1 to 12;

1.

9. A composition according to claim 1, or 4 wherein the co-surfactant (b) is selected from amine oxides comprising a C10 to C18 alkyl group.

10. A composition according to claim 9, wherein the co-surfactant (b) comprises cocodi(hydroxyethyl)amine oxide.

11. A composition according to claim 1 or 4 wherein the viscosity is greater than 30 cPs.

12. A composition according to claim 1 or 4 wherein the solution further comprises a carboxylic acid which corresponds to the peracid and wherein the total amount of peracid plus corresponding carboxylic acid in the peracid composition is less than 30% w/w.

13. A composition according to claim 12 wherein the total amount of peracid plus corresponding carboxylic acid in the peracid composition is less than 16% w/w.

14. A composition according to claim 1 or 4 wherein the concentration of peracid is from 0.05 to 5% w/w.

15. A composition according to claim 14, wherein the concentration of peracid is from 0.1 to 2% w/w.

16. A composition according to claim 1 or 4 wherein the peracid solution is substantially free from mineral acid.

17. A method for disinfecting and/or cleaning a hard surface comprising contacting the hard surface with a composition according to claim 1 or 4.

18. A process for thickening an aqueous peracid solution, containing from 0.01 to 40% w/w of a water-soluble peracid, said process comprising introducing into said solution:

(a) an aliphatic alcohol ethoxylate having the formula;

space="preserve" listing-type="equation">R.sup.1 R.sup.2 CH--(OCH.sub.2 CH.sub.2).sub.n --OH

in which R¹ and R² are hydrogen or linear or branched alkyl,

in which n is an integer of at least 1,

in which, when neither R¹ nor R² is a hydrogen atom, R¹ and R² have in total from 10 to 18 carbon atoms, and the number ratio of carbon atoms in R¹ plus R² ;

n is in the range of from 4;

1 to 7;

1, and

in which when either R¹ or R² is a hydrogen atom, the total number of carbon atoms is from 7 to 16 carbon atoms and the number ratio of carbon atoms in R¹ plus R² ;

n is in the range of from 4;

1 to 9;

1; and

(b) an amine oxide co-surfactant in an amount sufficient to increase the viscosity of the compositions, said ethoxylate being present in an amount of from 2.5 to 15% w/w, said co-surfactant being present in an amount of from 0.1 to 5% w/w, and the weight ratio of said ethoxylate (a) to said co-surfactant (b) being from 2;

1 to 20;

1.

19. A process according to claim 18, wherein the aliphatic alcohol ethoxylate and co-surfactant are pre-mixed prior to the addition of the peracid solution.

20. A process according to claim 18, wherein, in the formula, either R¹ or R² is a hydrogen atom and the number ratio of carbon atoms in R¹ plus R² :

n is in the range of from 5;

1 to 8;

1.

21. A process according to claim 20, wherein the total number of carbon atoms is from 9 to 16 carbon atoms.

22. A process according to claim 18, wherein the water soluble peracid comprises peracetic acid.

23. A process according to claim 18 or 22, wherein the pH of the thickened composition is 2.0 or more.

24. A process according to claim 23, wherein pH of the thickened composition is in the range of from 2.3 to 4.

25. A process according to claim 18 or 22, wherein the weight ratio of hydrophobic alcohol ethoxylate (a) to co-surfactant (b) is in the range of from 4:

1 to 15;

1.

26. A process according to claim 18 or 22, wherein the weight ratio of hydrophobic alcohol ethoxylate (a) to co-surfactant (b) is from 6:

1 to 12;

1.

27. A process according to claim 18 or 22, wherein the co-surfactant (b) is selected from amine oxides comprising a C10 to C18 alkyl group.

28. A process according to claim 18 or 22, wherein the co-surfactant (b) comprises cocodi(hydroxyethyl)amine oxide.

29. A process according to claim 18 or 22, wherein the solution further comprises a carboxylic acid which corresponds to the peracid, and wherein the total amount of peracid plus corresponding carboxylic acid in the peracid composition is less than 30% w/w.

30. A process according to claim 29 wherein the total amount of peracid plus corresponding carboxylic acid in the peracid composition is less than 16% w/w.

31. A process according to claim 18 or 22, wherein the concentration of peracid is from 0.05 to 5% w/w.

32. A process according to claim 18 or 22, wherein the concentration of peracid is from 0.1 to 2% w/w.

33. A process according to claim 18 or 22, wherein the peracid solution is substantially free from mineral acid.