Electrochemical capacitor

• US 5,963,417 A
• Filed: 11/08/1996
• Issued: 10/05/1999
• Est. Priority Date: 11/09/1995
• Status: Expired due to Term

• Current Assignee: Battelle Energy Alliance LLC (Battelle Memorial Institute), Wisconsin Alumni Research Foundation (University of Wisconsin System)
• Original Assignee: Lockheed Martin Postal Technologies Inc (Opex Corporation), Wisconsin Alumni Research Foundation (University of Wisconsin System)
• Inventors: Liu, Kuo-Chuan, Anderson, Marc A., Mohr, Charles M.
• Primary Examiner(s): Kincaid, Kristine
• Assistant Examiner(s): Dinkins, Anthony
• Application Number:
  US08/748,558
• Time in Patent Office: 1,061 Days
• Field of Search: 361/502-504, 361/508-509, 361/512, 361/516, 361/523-525, 361/528-529, 361/532, 29/25.03, 252/62.2, 429/40, 429/44, 429/46, 429/128-129, 429/188, 429/209, 429/218
• US Class Current: 361/503
• CPC Class Codes: H01G 9/042 characterised by the material H01G11/22 takes precedence
• CPC Class Codes: H01G 9/048 characterised by their structure H01G11/22 takes precedence
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors
• CPC Class Codes: Y02T 10/70 Energy storage systems for electromobility, e.g. batteries

Abstract

An inexpensive porous metal oxide material having high surface area, good conductivity and high specific capacitance is advantageously used in an electrochemical capacitor. The materials are formed in a sol-gel process which affords control over the properties of the resultant metal oxide materials.

Claims

1. An electrochemical capacitor comprising an anode and a cathode, the anode and the cathode comprising:

an electrode substrate;

a porous coating on the substrate, the coating comprising a metal oxide and having a surface area of greater than 30 m² /g, a porosity in the range of 10 to 80%, a mean grain size between 2 and 100 nm, and a mean pore size of between 0.5 and 20 nm; and

an electrolyte in contact with the coating,

wherein the metal oxide comprises an anion and a cation in a non-stoichiometric ratio.

2. An electrochemical capacitor as claimed in claim 1 wherein the coating is selected from a group consisting of a single metal oxide, a mixed metal oxide, a doped metal oxide, and a metal oxide/metal composite.

3. An electrochemical capacitor as claimed in claim 1 wherein the metal oxide is selected from a group consisting of nickel oxide, silica, titania, aluminum oxide, iron oxide, molybdenum oxide, manganese oxide, ruthenium oxide, rhodium oxide, iridium oxide, osmium oxide, chromium oxide, rhenium oxide, vanadium oxide and tungsten oxide.

4. An electrochemical capacitor as claimed in claim 1 wherein the metal oxide is nickel oxide.

5. An electrochemical capacitor as claimed in claim 1 wherein the electrolyte comprises an intercalating ion.

6. An electrochemical capacitor as claimed in claim 5 wherein the intercalating ion is lithium.

7. An electrochemical capacitor as claimed in claim 1 comprising a separator in contact with the porous coating.

8. An electrochemical capacitor as claimed in claim 7 wherein the separator comprises a material selected from the group consisting of a non-conducting polymer and a metal oxide insulating film.

9. An electrochemical capacitor as claimed in claim 1 having a specific electrochemical capacitance between 10 and 2000 F/g.

10. An electrochemical capacitor as claimed in claim 1 having a conductivity between 10^-5 per ohm-cm and 10⁴ per ohm-cm.

11. An electrochemical capacitor formed according to a process comprising the steps of:

coating onto a pair of electrode substrates a sol comprising metal oxide colloidal particles of between 2 and 100 nm in diameter;

drying the sol onto the substrates to form a xerogel;

firing the xerogel in an atmosphere at a temperature that does not destroy the porous microstructure of the xerogel, for a time sufficient to yield on the substrates a porous metal oxide material that comprises an anion and a cation in a non-stoichiometric ratio, the material having a surface area of greater than 30 m² /g, a porosity in the range of 10 to 80%, a mean grain size between 2 and 100 nm, and a mean pore size of between 0.5 and 20 nm, to form a pair of electrodes; and

immersing the electrodes into an electrolyte.

12. An electrochemical capacitor as claimed in claim 11 wherein the atmosphere comprises a gas selected from the group consisting of an oxidizing gas, a reducing gas and an inert gas.

13. An electrochemical capacitor as claimed in claim 11 wherein the firing temperature is between 200 and 1000°

C.

14. An electrochemical capacitor as claimed in claim 11 wherein the electrolyte is selected from a group consisting of a non-aqueous electrolyte and an aqueous electrolyte.

15. An electrochemical capacitor as claimed in claim 11 wherein the electrolyte comprises an intercalating ion.

16. An electrochemical capacitor as claimed in claim 15 wherein the intercalating ion is lithium.

17. An electrode comprising:

an electrode substrate;

a porous coating on the substrate, the coating comprising a metal oxide that comprises an anion and a cation in a non-stoichiometric ratio, the coating having a surface area of greater than 50 m² /g, a porosity in the range of 10 to 80%, and a mean pore size of between 0.5 and 20 nm.

18. An electrode as claimed in claim 17 wherein the substrate is selected from a group consisting of a foil, a foam, and gauze.

19. An electrode as claimed in claim 17 wherein the substrate comprises a material selected from the group consisting of aluminum, nickel, and a conductive polymer.

20. An electrode as claimed in claim 17 wherein the metal oxide comprises nickel oxide.

21. An electrochemical capacitor consisting of:

a pair of electrode substrates;

a porous coating on the substrates, the coating comprising a metal oxide that comprises an anion and a cation in a non-stoichiometric ratio, the coating having a surface area of greater than 30 m² /g, a porosity in the range of 10 to 80%, a mean grain size between 2 and 100 nm, and a mean pore size of between 0.5 and 20 nm; and

an electrolyte in contact with the coating.