Spray dried polymer for catalyst support

• US 6,013,594 A
• Filed: 04/29/1998
• Issued: 01/11/2000
• Est. Priority Date: 03/17/1994
• Status: Expired due to Fees

• Current Assignee: Exxon Chemical Patents Inc. (Exxon Mobil Corporation)
• Original Assignee: Exxon Chemical Patents Inc. (Exxon Mobil Corporation)
• Inventors: Yang, Henry Wu-Hsian, Speca, Anthony Nicholas
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): PASTERCZYK, JAMES W
• Application Number:
  US09/071,294
• Time in Patent Office: 622 Days
• Field of Search: 502/159, 502/109, 502/402, 502/439, 526/124.2, 526/160
• US Class Current: 502/103
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 4/027 Polymers
• CPC Class Codes: Y10S 526/901 Monomer polymerized in vapor state in presence of transition metal containing catalyst
• CPC Class Codes: Y10S 526/943 Polymerization with metallocene catalysts

Abstract

This invention relates to catalyst supports made by spray drying an emulsion polymerized latex and the novel supported catalysts utilizing these supports. This invention further relates to a method for forming supported catalysts by spray drying a latex of microparticles containing catalyst or catalyst components. The polymizerable monomers used in the latex are e.g. styrenes, vinyl benzenes, vinyl cyclohexane and vinyl cyclohexene and can form homo- or copolymers which may be crosslinked. The catalysts supported include metallocenes as well as Ziegler-Natta catalysts. Processes of polymerizing olefins using such catalysts are also described.

Claims

1. A supported olefin polymerization catalyst or catalyst component comprising a porous polymeric support of spray dried emulsion polymerized latex and an olefin polymerization catalyst, wherein said polymeric support is an agglomerate of polymer microparticles having an average diameter of 0.005 to 5.0 micrometers.

2. The supported catalyst or catalyst component of claim 1 wherein the polymer microparticles are homopolymers or copolymers of styrene.

3. The supported catalyst or catalyst component of claim 1 wherein the polymer microparticles are polymers of one or more of styrene, alpha-methylstyrene, methylstyrene, paramethylstyerene, divinylbenzene, vinyl cyclohexane and vinyl cyclohexane.

4. The supported catalyst or catalyst component of claim 2 wherein the polymers are cross-linked with up to 25 weight percent of a cross-linkable comonomer, based on the weight of copolymer.

5. The supported catalyst or catalyst component of claim 3 wherein the polymers are cross-linked with up to 25 weight percent of a cross-linkable comonomer, based on the weight of copolymer.

6. The supported catalyst of claim 1 wherein said olefin polymerization catalyst comprises a cyclopentadienyl Group 4 transition metal compound and an alumoxane or a non-coordinating anion.

7. The supported catalyst of claim 1 wherein said olefin polymerization catalyst comprises a group 4, 5, or 6 transition metal compound and an organoaluminum or MgCl₂ compound.

8. A process for polymerizing olefins comprising contacting olefin monomer and the supported catalyst or supported catalyst component of claim 1 in gas phase, slurry phase, or high pressure in a polymerization zone under polymerization conditions.

9. A process for polymerizing olefins comprising contacting olefin monomer and the supported catalyst or supported catalyst component of claim 2 in gas phase, slurry phase, or high pressure in a polymerization zone under polymerization conditions.

10. A process for polymerizing olefins comprising contacting olefin monomer and the supported catalyst or supported catalyst component of claim 6 in gas phase, slurry phase, or high pressure in a polymerization zone under polymerization conditions.