Method for remote detection of volatile taggant

• US 6,025,200 A
• Filed: 12/21/1996
• Issued: 02/15/2000
• Est. Priority Date: 05/24/2000
• Status: Expired due to Term

• Current Assignee: Copilot Ventures Fund III LLC
• Original Assignee: TRACER DETECTION TECHNOLOGY CORPORATION
• Inventors: Kaish, Norman, Fraser, Jay, Otugen, Volkan, Popovic, Svetozar
• Primary Examiner(s): ALEXANDER, LYLE
• Application Number:
  US08/771,608
• Time in Patent Office: 1,151 Days
• Field of Search: 436/56, 436/164, 436/805, 436/902, 436/27, 436/816, 422/83, 422/90, 73/23.2, 73/23.36
• US Class Current: 436/56
• CPC Class Codes: G01N 2021/1793 Remote sensing
• CPC Class Codes: G01N 21/643 non-biological material
• CPC Class Codes: G01N 33/0057 for warfare agents or explosives properties of explosives G01N33/227
• CPC Class Codes: G01N 33/225 Gaseous fuels, e.g. natural gas
• CPC Class Codes: Y10S 436/816 Alkaloids, amphetamines, and barbiturates
• CPC Class Codes: Y10T 436/13 Tracers or tags

Abstract

A method of tagging and detecting objects is disclosed which comprises the steps of: (a) applying a volatile taggant to the object; and (b) subsequently detecting the presence of the taggant by the absorption, transmittance, reflectance, photon emission or fluorescence of the taggant and therefore a proximity of the tagged object. The present invention therefore provides optical sensing means which do not require physical separation of differing compounds for discrimination thereof.

Claims

1. A method of detecting the presence or proximity of an object, comprising the steps of:

(a) applying a volatile tracer to the object as a taggant; and

(b) subsequently detecting the presence of said taggant by the absorption, transmittance, reflectance, photon emission or fluorescence spectral characteristics of the taggant, to determine the presence or proximity of the object.

2. The method defined in claim 1, further comprising the step of illuminating a space to be sensed for the presence of taggant, wherein the illumination is cooperative with the detection, further comprising the steps of synchronizing the illumination with the detection and processing a detected signal based on said synchronization for increased detection sensitivity.

3. The method defined in claim 1, wherein said applying step comprises the step of subjecting the object to a PFT vapor.

4. The method defined in claim 1, wherein said applying step comprises the steps of:

(a) encapsulating a taggant in a plurality of microcapsules; and

(b) applying said microcapsules with said encapsulated taggant to the object.

5. The method defined in claim 1, wherein the object comprises illicit drugs, and the taggant comprises a Perfluorocarbon Tracer (PFT), applied to a container of illicit drug related material, such that said PFT is released from said container over a period of time as a vapor taggant.

6. The method defined in claim 1, wherein an illumination source is provided for detecting the absorption, transmittance, reflectance, photon emission or fluorescence spectral characteristics of the taggant, the illumination source being cooperative with the detector.

7. The method defined in claim 1, wherein the detecting step comprises detecting a fluorescent emission from a taggant excited by a pulsed illumination source, the detecting step further comprising the step of determining a background signal from the object when the illumination source is not pulsing and compensating detection for the background signal.

8. The method defined in claim 1, further comprising the step of illuminating a space to be sensed for the presence of taggant, wherein the illumination is cooperative with the detection, further comprising the steps of synchronizing the illumination with the detection and processing a detected signal based on said synchronization for increased detection sensitivity.

9. The method defined in claim 1, wherein the taggant exhibits UV fluorescent characteristics.

10. The method defined in claim 1, wherein the taggant is microencapsulated and selectively released in response to one or more stimuli selected from the group consisting of light, specific illumination, heat, pressure, touch, humidity, pH, and receptor binding.

11. The method defined in claim 1, wherein said applying step comprises the steps of:

(a) dissolving a taggant composition in a liquid carrier; and

(b) applying said liquid carrier with said dissolved composition to the object.

12. The method defined in claim 11, wherein said liquid carrier is an oil.

14. The method defined in claim 11, wherein said carrier is a substantially clear liquid.

15. The method defined in claim 1, wherein the absorption, transmittance, reflectance, photon emission or fluorescence of the taggant is detected after laser illumination.

16. The method defined in claim 15, wherein the laser is an ultraviolet laser.

17. The method defined in claim 15, wherein the illuminator is a pulsed, high energy laser which provides stimulation at the wavelength at which the taggant is most sensitive and which produces absorption, transmittance, reflectance, photon emission or fluorescence at a wavelength to which the sensor is sensitive.

18. The method defined in claim 15, wherein the laser is an ultraviolet laser.

19. The method defined in claim 15, wherein the illuminator is a pulsed, high energy laser which provides stimulation at the wavelength at which the taggant is most sensitive and which produces absorption, transmittance, reflectance, photon emission or fluorescence at a wavelength to which the sensor is sensitive.

20. The method defined in claim 1, wherein the object comprises a drug.

21. The method defined in claim 20, wherein said applying step comprises the steps of:

(b) dissolving a taggant in a liquid carrier; and

(c) treating a precursor required in the manufacture of the drug with the liquid carrier with the dissolved taggant.

22. The method defined in claim 20, wherein the object comprises a drug outside legal channels of distribution.

23. The method defined in claim 22, wherein said treating step comprises the step of spraying crops which are used in the manufacture of drugs with a liquid carrier with the dissolved taggant.

24. The method defined in claim 22, wherein said treating step comprises the step of applying a taggant to a chemical composition which is used as a precursor in the manufacture of a drug.

25. The method defined in claim 1, further comprising the step of illuminating a space to be sensed for the presence of taggant.

26. The method defined in claim 25, wherein said light is in the ultraviolet, visible or infrared sections of the electromagnetic spectrum, or in a combination of two or all of those sections.

27. The method defined in claim 25, wherein the illumination is in the ultraviolet, visible or infrared sections of the electromagnetic spectrum, or in a combination of two or all of those sections.

28. The method defined in claim 25, wherein said step of illuminating comprises directing a laser toward the space.

29. The method defined in claim 28, wherein said laser is an ultraviolet laser.

30. The method defined in claim 28, wherein said laser is an ultraviolet laser.

31. The method defined in claim 1, wherein the absorption, transmittance, reflectance, photon emission or fluorescence spectral characteristics of the taggant are detected by a detector after illumination by an illuminator, the illuminator and the detector being spatially separated.

32. The method defined in claim 31 wherein the illuminator is located in a flying object.

33. The method defined in claim 31, wherein the detector is located in a flying object.

34. The method defined in claim 31 wherein the illuminator is located in a flying object.

35. The method defined in claim 31, wherein the detector is located in a flying object.

36. The method defined in claim 35, wherein the detector is either in geostationary orbit or low earth orbit.

37. The method defined in claim 35, wherein the absorption, transmittance, reflectance, photon emission or fluorescence is within at least one of the bands of atmospheric transmission in which a detector can receive electromagnetic signals from the ground.

38. The method defined in claim 37, wherein the band is the MWIR band at about 3.1 μ

m or the visible band above 0.4 μ

m.

39. The method defined in claim 31, wherein the illuminator is cooperative with the detector, the illuminator being triggered when the object of interest is within a field of view of the detector.

13. The method defined in clam 11, wherein said object is a document and said carrier is an oil.

40. A method for detecting a volatile taggant having spectral characteristics within a sample space, comprising:

(a) illuminating the sample space;

(b) detecting a spectral characteristic of energy from the sample space;

(c) comparing the spectral characteristic to a predetermined spectral characteristic pattern; and

(d) outputting a signal relating to a result of said comparing.

41. The method according to claim 40, further comprising the steps of:

(a) detecting an electron capture characteristic of a sample from the sample space;

(b) comparing the electron capture characteristic to a predetermined electron capture characteristic pattern; and

(c) outputting a signal relating to a result of said comparing.